\(Đặt:n_{CuO}=a\left(mol\right);n_{PbO}=b\left(mol\right)\left(a,b>0\right)\\ n_{H_2O}=\dfrac{1,35}{18}=0,075\left(mol\right)\\ CuO+H_2\underrightarrow{^{to}}Cu+H_2O\\ PbO+H_2\underrightarrow{^{to}}Pb+H_2O\\ \Rightarrow\left\{{}\begin{matrix}80a+223b=8,145\\a+b=0,075\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,06\\b=0,015\end{matrix}\right.\\ \Rightarrow\%m_{CuO}=\dfrac{0,06.80}{8,145}.100\approx58,932\%\\ \Rightarrow\%_{PbO}\approx41,068\%\)

\(CuO+CO\rightarrow Cu+CO_2\)

..x..........x.........................

\(PbO+CO\rightarrow Pb+CO_2\)

..y........y........................

- Theo bài ra ta có hệ : \(\left\{{}\begin{matrix}80x+223y=3,83\\x+y=0,03\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}x=0,02\\y=0,01\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=1,6\\m_{PbO}=2,23\end{matrix}\right.\) ( g )

b, \(n_K=n_{CO_2}=x+y=0,03\left(mol\right)\)

\(\Rightarrow V=0,672\left(l\right)\)

c, \(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)

........................0,03........0,03.............

\(\Rightarrow m_{kt}=3\left(g\right)\) 

Đặt \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{PbO}=y\left(mol\right)\end{matrix}\right.\)

\(m_{CuO}+m_{PbO}=3,83\\ \Rightarrow80x+223y=3,83\left(1\right)\)

\(PTHH:CuO+CO\underrightarrow{t^o}Cu+CO_2\uparrow\\ \left(mol\right)......x\rightarrow..x....x.....x\\ PTHH:PbO+CO\underrightarrow{t^o}Pb+CO_2\uparrow\\ \left(mol\right)......y\rightarrow..y....y.....y\\ n_{CO}=\dfrac{0,84}{28}=0,03\\ \Rightarrow x+y=0,03\left(2\right)\)

Từ (1) và (2) ta có hpt \(\left\{{}\begin{matrix}80x+223y=3,83\\x+y=0,03\end{matrix}\right.\)

Giải hpt ta được \(\left\{{}\begin{matrix}x=0,02\\y=0,01\end{matrix}\right.\)

\(a,\left\{{}\begin{matrix}m_{CuO}=80.0,02=1,6\left(g\right)\\m_{PbO}=3,83-1,6=2,23\left(g\right)\end{matrix}\right.\)

\(b,V_{CO_2}=\left(x+y\right).22,4=\left(0,02+0,01\right).22,4=0,672\left(l\right)\)

\(c,n_{CO_2}=x+y=0,02+0,01=0,03\left(mol\right)\\ PTHH:Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3\downarrow+H_2O\\ \left(mol\right)................0,03\rightarrow0,03\\ m_{CaCO_3}=0,03.100=3\left(g\right)\)

nCO = 0.84/28 = 0.03 (mol)

Đặt nCuO= x (mol)

nPbO = y (mol)

Bảo Toàn e : 

2x +2y = 0.06 (1)

Và : 80x + 223y =3.83(2)

Từ (1) và (2) 

=> x = 0.02 ; y = 0.01 

=> m PbO = 223 . 0,01 = 2.23 (g)

m CuO = 3,83 - 2,23 = 1.6 (g)

b. Bảo toàn nguyên tố C

=> n CO2 = 0.03 × 22.4 = 0.672 (l)

c. Bảo toàn nguyên tố C : 

m CaCO3 = 100 × 0.03 = 3 (g) 

\(n_{Pb}=\dfrac{2,07}{207}=0,01mol\)

\(n_{Cu}=\dfrac{1,6}{64}=0,025mol\)

\(PbO+H_2\rightarrow\left(t^o\right)Pb+H_2O\)

0,01    0,01            0,01            ( mol )

\(CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\)

0,025  0,025        0,025            ( mol )

\(m_{hh}=m_{PbO}+m_{CuO}=\left(0,01.223\right)+\left(0,025.80\right)=4,23g\)

\(V_{H_2}=\left(0,01+0,025\right).22,4=0,784l\)

\(n_{Pb}=\dfrac{2,07}{207}=0,01\left(mol\right)\\ n_{Cu}=\dfrac{1,6}{64}=0,025\left(mol\right)\\ PTHH:PbO+H_2\underrightarrow{t^o}Pb+H_2O\\ Mol:0,01\leftarrow0,01\leftarrow0,01\\ CuO+H_2\underrightarrow{t^o}Cu+H_2O\\ Mol:0,025\leftarrow0,025\leftarrow0,025\)

\(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=0,025.80=2\left(g\right)\\m_{PbO}=0,01.223=2,23\left(g\right)\end{matrix}\right.\Rightarrow m_{oxit}=2+2,23=4,23\left(g\right)\\ V_{H_2}=\left(0,01+0,025\right).22,4=0,784\left(l\right)\)

PTHH:CuO+COto→Cu+CO2(1)(1)

PbO+COto→Pb+CO2(2)

Theo(1) nCuO=nCu=1,664=0,025(mol)

mCuO=0,025.80=2g

Theo(2) nPbO=nPb=\(\dfrac{2,07}{207}\)=0,01mol

mPbO=0,01.223=2,23g

b) Theo(1) và (2): ΣnCO=nCu+nPb=0,025+0,01=0,035mol

ΣVCO=0,035.22,4=0,784lit

Gọi $n_{CuO} = a;  n_{PbO} = b$

Ta có : 

$80a + 223b = 15,15(1)$
$CuO + CO \xrightarrow{t^o} Cu + CO_2$
$PbO + CO \xrightarrow{t^o} Pb + CO_2$
$CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O$

Theo PTHH :

$n_{CO_2} = a + b = \dfrac{10}{100} = 0,1(2)$
Từ (1)(2) suy ra a = b = 0,05

Vậy :

$m_{CuO} = 0,05.80 = 4(gam)$
$m_{PbO} = 0,05.223 = 11,15(gam)$

Theo gt ta có: $n_{CO_2}=n_{CaCO_3}=0,1(mol)$

Gọi số mol $CuO$ và $PbO$ lần lượt là a;b

$\Rightarrow 80a+223b=15,15$

$CuO+CO\rightarrow Cu+CO_2$

$PbO+CO\rightarrow Pb+CO_2$

$\Rightarrow a+b=0,1$

Giải hệ ta được $a=b=0,05$

$\Rightarrow m_{kl}=13,55(g)$

\(Fe_2O_3+3H_2\rightarrow\left(t^o\right)2Fe+3H_2O\\ CuO+H_2\rightarrow\left(t^o\right)Cu+H_2O\\ Đặt:n_{Fe_2O_3}=a\left(mol\right);n_{CuO}=b\left(mol\right)\left(a,b>0\right)\\ m_{hhoxit}=k\left(g\right)\\ \Rightarrow\left(1\right)160a+80b=k\\ \left(2\right)112a+64b=0,72k\\ \Rightarrow6,4a=12,8b\\ \Leftrightarrow\dfrac{a}{b}=\dfrac{12,8}{6,4}=\dfrac{2}{1}\\ \Rightarrow\%m_{Fe_2O_3}=\dfrac{160.2}{160.2+80.1}.100=80\%\\ \Rightarrow\%m_{CuO}=20\%\)

hư

gọi n cuo = a (mol)

n fe2o3 = b (mol)

PTHH     Cuo + h2 ---> cu + h2o

mol           a          a         a

PTHH    Fe2O3 + 3H2 ----> 2Fe + 3H2O

mol         b               3b            2b

Ta có 64a + 112b = 12 (1)

nh2 (đktc) = 2,24 : 22,4 = 0,1 (mol)

PTHH : Fe + 2HCl ----> FeCl2 + H2

mol        2b                                  2b

=> 2b = 0,1 (mol) (2)

Từ (1) và (2) => a = 0,1 (mol) và b = 0,2 (mol)

m hỗn hợp oxit = 0,1 . 80 + 0,2 . 160 = 8 + 32 = 40 (g)

%CuO = 8 . 100 : 40 = 20%

%Fe2O3 = 100 - 20 = 80 %

b) Vh2 (đktc) = (0,1 + 3.0,2) . 22,4 = 15,68 (g)