\(CuO+CO\rightarrow Cu+CO_2\)
..x..........x.........................
\(PbO+CO\rightarrow Pb+CO_2\)
..y........y........................
- Theo bài ra ta có hệ : \(\left\{{}\begin{matrix}80x+223y=3,83\\x+y=0,03\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}x=0,02\\y=0,01\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=1,6\\m_{PbO}=2,23\end{matrix}\right.\) ( g )
b, \(n_K=n_{CO_2}=x+y=0,03\left(mol\right)\)
\(\Rightarrow V=0,672\left(l\right)\)
c, \(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)
........................0,03........0,03.............
\(\Rightarrow m_{kt}=3\left(g\right)\)
Đặt \(\left\{{}\begin{matrix}n_{CuO}=x\left(mol\right)\\n_{PbO}=y\left(mol\right)\end{matrix}\right.\)
\(m_{CuO}+m_{PbO}=3,83\\ \Rightarrow80x+223y=3,83\left(1\right)\)
\(PTHH:CuO+CO\underrightarrow{t^o}Cu+CO_2\uparrow\\ \left(mol\right)......x\rightarrow..x....x.....x\\ PTHH:PbO+CO\underrightarrow{t^o}Pb+CO_2\uparrow\\ \left(mol\right)......y\rightarrow..y....y.....y\\ n_{CO}=\dfrac{0,84}{28}=0,03\\ \Rightarrow x+y=0,03\left(2\right)\)
Từ (1) và (2) ta có hpt \(\left\{{}\begin{matrix}80x+223y=3,83\\x+y=0,03\end{matrix}\right.\)
Giải hpt ta được \(\left\{{}\begin{matrix}x=0,02\\y=0,01\end{matrix}\right.\)
\(a,\left\{{}\begin{matrix}m_{CuO}=80.0,02=1,6\left(g\right)\\m_{PbO}=3,83-1,6=2,23\left(g\right)\end{matrix}\right.\)
\(b,V_{CO_2}=\left(x+y\right).22,4=\left(0,02+0,01\right).22,4=0,672\left(l\right)\)
\(c,n_{CO_2}=x+y=0,02+0,01=0,03\left(mol\right)\\ PTHH:Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3\downarrow+H_2O\\ \left(mol\right)................0,03\rightarrow0,03\\ m_{CaCO_3}=0,03.100=3\left(g\right)\)
nCO = 0.84/28 = 0.03 (mol)
Đặt nCuO= x (mol)
nPbO = y (mol)
Bảo Toàn e :
2x +2y = 0.06 (1)
Và : 80x + 223y =3.83(2)
Từ (1) và (2)
=> x = 0.02 ; y = 0.01
=> m PbO = 223 . 0,01 = 2.23 (g)
m CuO = 3,83 - 2,23 = 1.6 (g)
b. Bảo toàn nguyên tố C
=> n CO2 = 0.03 × 22.4 = 0.672 (l)
c. Bảo toàn nguyên tố C :
m CaCO3 = 100 × 0.03 = 3 (g)
Gọi \(\left\{{}\begin{matrix}n_{CuO}=x\\n_{PbO}=y\end{matrix}\right.\left(x,y>0\right)\)
n\(_{CO}\)= 0,84 : 28 = 0,03 (mol)
CuO + CO \(\xrightarrow[]{t^0}\) Cu + CO\(_2\)
x x x x (mol)
PbO + CO \(\xrightarrow[]{t^0}\) Pb + CO\(_2\)
y y y y (mol)
Theo bài ra ta có hệ phương trình:\(\left\{{}\begin{matrix}80x+223y=3,83\\x+y=0,03\end{matrix}\right.\)
⇔\(\left\{{}\begin{matrix}x=0,02\left(mol\right)\\y=0,01\left(mol\right)\end{matrix}\right.\)
a)%CuO = \(\dfrac{80.0,02}{3,83}.100\%\)= 41,78%
%PbO = 100% - 41,78% = 58,22%
b)\(n_{CO_2}\)= x + y = 0,02 + 0,01 = 0,03 (mol)
\(V_{CO_2}\)= 0,03 . 22,4 = 0,672 (l)
c)
CO\(_2\) + Ca(OH)\(_2\) → CaCO\(_3\) + H\(_2\)O
0,03 0,03 (mol)
\(m_{kt}\)= 0,03 . 100 = 3 (g)