\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)

PTHH:

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

0,2                      0,2          0,3 

\(V_{H_2}=n.22,4=6,72\left(l\right)\)

\(m_{AlCl_3}=n.M=0,2.133,5=26,7\left(g\right)\)

a) \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

b) \(n_{Al}=\dfrac{m}{M}=\dfrac{5,4}{27}=0,2\left(mol\right)\) ;    \(n_{HCl}=\dfrac{m}{M}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

 \(2Al\)    \(+\)   \(6HCl\)    →    \(2AlCl_3\)  \(+\)  \(3H_2\)

Tỉ lệ:   \(\dfrac{0,2}{2}>\dfrac{0,5}{6}\)                                          ⇒  Al dư, tính theo HCl

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

           \(0,5\)    →   \(\dfrac{1}{6}\)    →   \(0,25\)       ( mol )

\(V_{H_2}=n.22,4=0,25.22,4=5,6\left(l\right)\)

c) \(m_{AlCl_3}=n.M=\dfrac{1}{6}.\left(27+35,5.3\right)=22,25\left(g\right)\)

a, \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)

\(n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\)

PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,3}{1}\), ta được H₂SO₄ dư.

Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{Fe}=0,2\left(mol\right)\Rightarrow n_{H_2SO_4\left(dư\right)}=0,3-0,2=0,1\left(mol\right)\)

\(\Rightarrow m_{Fe}=0,1.98=9,8\left(g\right)\)

b, \(n_{H_2}=n_{Fe}=0,2\left(mol\right)\Rightarrow n_{H_2}=0,2.22,4=4,48\left(l\right)\)

c, \(n_{CuO}=\dfrac{24}{80}=0,3\left(mol\right)\)

PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)

Xét tỉ lệ: \(\dfrac{0,3}{1}>\dfrac{0,2}{1}\), ta được CuO dư.

Theo PT: \(n_{Cu}=n_{H_2}=0,2\left(mol\right)\Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\)

PTHH: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\uparrow\)

Ta có: \(\left\{{}\begin{matrix}n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{49}{98}=0,5\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Axit còn dư

\(\Rightarrow\left\{{}\begin{matrix}n_{H_2}=0,2\left(mol\right)\\n_{H_2SO_4\left(dư\right)}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,2\cdot22,4=4,48\left(l\right)\\m_{H_2SO_4\left(dư\right)}=0,3\cdot98=29,4\left(g\right)\end{matrix}\right.\)

nH2SO4=0,5(mol)

nZn=0,2(mol)

a) PTHH: Zn + H2SO4 -> ZnSO4 + H2

ta có: 0,5/1 > 0,2/1

=> Zn hết, H2SO4 dư, tính theo nZn

b) m(H2SO4 dư)= (0,5-0,2).98=29,4(g)

c) nH2= nZn=0,2(mol)

=>V(H2,đktc)=0,2.22,4=4,48(l)

\(a,PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ b,n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\\ n_{HCl}=2\cdot0,15=0,3\left(mol\right)\)

Vì \(\dfrac{n_{Zn}}{1}>\dfrac{n_{HCl}}{2}\) nên sau p/ứ Zn dư

\(\Rightarrow n_{Zn}=\dfrac{1}{2}n_{HCl}=0,15\left(mol\right)\\ \Rightarrow m_{Zn}=0,15\cdot65=9,75\\ \Rightarrow m_{Zn\left(dư\right)}=13-9,75=3,25\left(g\right)\\ c,n_{H_2}=n_{Zn}=0,15\left(mol\right)\\ \Rightarrow V_{H_2}=0,15\cdot22,4=3,36\left(l\right)\)

\(\left(a\right)2Al+3H_2O\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ \left(b\right)n_{H_2}=\dfrac{13,44}{22,4}=0,6mol\\ n_{Al}=\dfrac{0,6.2}{3}=0,4mol\\ m_{Al}=0,4.27=10,8g\\ \left(c\right)n_{O_2}=\dfrac{4,8}{32}=0,15mol\\ 4Al+3O_2\underrightarrow{t^0}2Al_2O_3\\ \Rightarrow\dfrac{0,4}{4}>\dfrac{0,15}{3}\Rightarrow Al.dư\\ n_{Al_2O_3}=\dfrac{0,15.2}{3}=0,1mol\\ m_{oxit}=m_{Al_2O_3}=0,1.102=10,2g\)

a: \(2Al+3H_2SO_4\rightarrow1Al_2\left(SO_4\right)_3+3H_2\uparrow\)

    0,4           0,6                0,2             0,6

b: \(n_{H_2}=\dfrac{13.44}{22.4}=0.6\left(mol\right)\)

=>\(n_{Al}=0.4\left(mol\right)\)

\(m_{Al}=0.4\cdot27=10.8\left(g\right)\)

c: \(4Al+3O_2\rightarrow2Al_2O_3\)

0,4                      0,2

\(m_{Al_2O_3}=0.2\left(27\cdot2+16\cdot3\right)=0.2\cdot102=20.4\left(g\right)\)

\(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

PTHH ;

2Al + 3H2SO4 --> Al2(SO4)3 + 3H2↑

  0,4           0,6               0,2           0,6

4Al + 3O2 ---> 2Al2O3

0,2       0,15          0,1 

\(n_{O_2}=\dfrac{4,8}{32}=0,15\left(mol\right)\)

\(\dfrac{0,4}{4}>\dfrac{0,15}{3}\)

--> Tính theo oxi

\(b,m_{Al}=0,4.27=10,8\left(g\right)\)

\(c,m_{Al_2O_3}=0,1.102=10,2\left(g\right)\)

\(a) Zn + H_2SO_4 \to ZnSO_4 + H_2\\ b) n_{Zn} = \dfrac{13}{65} = 0,2 < n_{H_2SO_4} = \dfrac{49}{98} = 0,5 \to H_2SO_4\ dư\\ c) n_{H_2}= n_{Zn} = 0,2(mol)\\ V_{H_2} = 0,2.22,4= 4,48(lít)\\ d) CuO + H_2 \xrightarrow{t^o} Cu + H_2O\\ n_{Cu} = n_{H_2}= 0,2(mol)\\ m_{Cu} = 0,2.64= 12,8(gam)\)

     a)PTHH(1): Zn+H2SO4 →ZnSO4+H2

     b)  theo gt: 0,21 < 0,51⇒H2SO4dư 0,21 < 0,51⇒H2SO4dư , tính số mol các chất theo Zn

ta có theo PTHH: nH2SO4= nZn=0,2(mol)

⇒ nH2SO4dư=0,5−0,2=0,3(mol)

⇒ mH2SO4dư=0,3⋅98=29,4(g)

 Do tỉ lệ phương trình là 1:1:1:1

=>  nH2 = nZn = 0,2 mol

=>  VH2= n.22,4= 0,2.22,4= 4,48 (l)

c) PTHH(2) : Cuo + H2  Cu + H2O

Theo PTHH (1)  và tích chất bắc cầu ta được

=>  nH2 = nCu = 0,2 mol

=>  mCu = n.M= 0,2.64= 12,8 (g)

 PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)

Làm gộp các phần còn lại

Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\) \(\Rightarrow\left\{{}\begin{matrix}n_{Al_2\left(SO_4\right)_3}=0,1mol\\n_{H_2SO_4}=n_{H_2}=0,3mol\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{Al_2\left(SO_4\right)_3}=0,1\cdot342=34,2\left(g\right)\\m_{H_2SO_4}=0,3\cdot98=29,4\left(g\right)\end{matrix}\right.\)