a) Fe + 2HCl --> FeCl₂ + H₂

b) m_tăng = m_Fe - m_H2

=> m_H2 = 8,4 - 8,1 = 0,3 (mol)

=> \(n_{H_2}=\dfrac{0,3}{2}=0,15\left(mol\right)\)

=> V_H2 = 0,15.22,4 = 3,36 (l)

c) n_HCl(pư) = 0,3 (mol)

a,\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right);n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\left(mol\right)\)

PTHH: 2Al + 3H₂SO₄ → Al₂(SO₄)₃ + 3H₂

Mol:    0,1         0,15            0,05             0,15

b,Ta có: \(\dfrac{0,1}{2}< \dfrac{0,3}{3}\) ⇒ Al hết, H₂SO₄ dư

\(\Rightarrow m_{H_2SO_4dư}=\left(0,3-0,15\right).98=14,7\left(g\right)\)

c, \(m_{Al_2\left(SO_4\right)_3}=0,05.342=17,1\left(g\right)\)

d, \(V_{H_2}=0,15.22,4=3,36\left(l\right)\)

\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)  
            0,125                            0,125 (mol ) 
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\ \)   
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
 

Bài 18:

Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)

\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.

Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)

\(m_{H_2}=0,125.2=0,25\left(g\right)\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)

Có: m _{dd sau pư} = 8,125 + 100 - 0,25 = 107,875 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)

Bạn tham khảo nhé!

`a)PTHH:`

`Zn + 2HCl -> ZnCl_2 + H_2↑`

`0,125`  `0,25`    `0,125`    `0,125`      `(mol)`

`b)n_[Zn] = [ 8,125 ] / 65 = 0,125 (mol)`

`n_[HCl] = [ [ 18,25 ] / 100 . 100 ] / [ 36,5 ] = 0,5 (mol)`

Ta có: `[ 0,125 ] / 1 < [ 0,5 ] / 2`

    `-> Zn` hết, `HCl` dư

 `=> V_[H_2] = 0,125 . 22,4 = 2,8 (l)`

 `=> m_[H_2] = 0,125 . 2 = 0,25 (g)`

`c)m_\text{dd sau p/ứ} = 8,125 + 100 - 0,25 = 107,875 (g)`

`=> C%_[ZnCl_2] = [ 0,125 . 136 ] / [ 107,875 ] . 100 ~~ 15,76%`

`=> C%_[HCl(dư)] = [ ( 0,5 - 0,25 ) . 36,5 ] / [ 107,875 ] . 100 ~~ 8,46%`

\(\left(a\right)2Al+3H_2O\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ \left(b\right)n_{H_2}=\dfrac{13,44}{22,4}=0,6mol\\ n_{Al}=\dfrac{0,6.2}{3}=0,4mol\\ m_{Al}=0,4.27=10,8g\\ \left(c\right)n_{O_2}=\dfrac{4,8}{32}=0,15mol\\ 4Al+3O_2\underrightarrow{t^0}2Al_2O_3\\ \Rightarrow\dfrac{0,4}{4}>\dfrac{0,15}{3}\Rightarrow Al.dư\\ n_{Al_2O_3}=\dfrac{0,15.2}{3}=0,1mol\\ m_{oxit}=m_{Al_2O_3}=0,1.102=10,2g\)

a: \(2Al+3H_2SO_4\rightarrow1Al_2\left(SO_4\right)_3+3H_2\uparrow\)

    0,4           0,6                0,2             0,6

b: \(n_{H_2}=\dfrac{13.44}{22.4}=0.6\left(mol\right)\)

=>\(n_{Al}=0.4\left(mol\right)\)

\(m_{Al}=0.4\cdot27=10.8\left(g\right)\)

c: \(4Al+3O_2\rightarrow2Al_2O_3\)

0,4                      0,2

\(m_{Al_2O_3}=0.2\left(27\cdot2+16\cdot3\right)=0.2\cdot102=20.4\left(g\right)\)

\(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

PTHH ;

2Al + 3H2SO4 --> Al2(SO4)3 + 3H2↑

  0,4           0,6               0,2           0,6

4Al + 3O2 ---> 2Al2O3

0,2       0,15          0,1 

\(n_{O_2}=\dfrac{4,8}{32}=0,15\left(mol\right)\)

\(\dfrac{0,4}{4}>\dfrac{0,15}{3}\)

--> Tính theo oxi

\(b,m_{Al}=0,4.27=10,8\left(g\right)\)

\(c,m_{Al_2O_3}=0,1.102=10,2\left(g\right)\)

\(nAl=\dfrac{8,1}{27}=0,3\left(mol\right)\)

\(nHCl=\dfrac{21,9}{36,5}=0,6\left(mol\right)\)

PTHH:

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

 2         6             2             3    (mol)

0,2       0,6         0,2          0,3      (mol)

LTL : 0,3 / 2 > 0,6/6

=> Al dư sau pứ , HCl đủ vs pứ

\(mAl_{\left(dư\right)}=\left(0,3-0,2\right).27=2,7\left(g\right)\)

\(mAlCl_3=0,2.98=19,6\left(g\right)\)

\(H_2+CuO\rightarrow Cu+H_2O\)

 1        1           1         1   (mol)

0,3      0,3      0,3      0,3   (mol)

=> \(mCu=0,3.64=19,2\left(g\right)\)

\(n_{Al}=\dfrac{8,1}{27}=0,3\left(mol\right)\\ n_{HCl}=\dfrac{21,9}{36,5}=0,6\left(mol\right)\\ pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\) 
\(LTL:\dfrac{0,3}{2}>\dfrac{0,6}{6}\) 
=> Al dư HCl hết 
theo pthh : \(n_{Al\left(p\text{ư}\right)}=\dfrac{1}{3}n_{HCl}=0,2\left(mol\right)\\ m_{Al\left(d\right)}=\left(0,3-0,2\right).27=2,7\left(g\right)\) 

theo pthh : \(n_{AlCl_3}=\dfrac{1}{3}n_{HCl}=0,1\left(mol\right)\\ m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\) 
theo pthh : \(n_{H_2}=\dfrac{1}{2}n_{HCl}=0,3\left(mol\right)\)
pthh: \(CuO+H_2\underrightarrow{t^o}H_2O+Cu\) 
                     0,3               0,3 
\(m_{Cu}=0,3.64=19,2\)
            

a) \(PTHH:Mg+2HCl\rightarrow MgCl_2+H_2\) 

b) \(n_{Mg}=\dfrac{4,8}{24}=0,2mol\) 

\(n_{HCl}=2.n_{Mg}=0,2.2=0,4mol\)

\(\Rightarrow m_{HCl}=n.M=0,4.36,5=14,6g\)

c) \(n_{H_2}=n_{Mg}=0,2mol\) 

Thể tích khí hidro sinh ra (ở đktc): 

\(V_{H_2}=0,2.24,79=4,958l.\)