a) Gọi \(\left\{{}\begin{matrix}n_{Fe}=a\left(mol\right)\\n_{Zn}=b\left(mol\right)\end{matrix}\right.\) \(\Rightarrow56a+65b=12,1\)  (1)

Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

Bảo toàn electron: \(2n_{Fe}+2n_{Zn}=2n_{H_2}\) \(\Rightarrow2a+2b=0,4\)  (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{0,1\cdot56}{12,1}\cdot100\%\approx46,28\%\\\%m_{Zn}=53,72\%\end{matrix}\right.\)

b)

Bảo toàn nguyên tố: \(\left\{{}\begin{matrix}n_{FeSO_4}=n_{Fe}=n_{Zn}=n_{ZnSO_4}=0,1\left(mol\right)\\n_{H_2SO_4\left(p.ứ\right)}=n_{H_2}=0,2\left(mol\right)\Rightarrow\Sigma n_{H_2SO_4}=0,2\cdot110\%=0,22\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{FeSO_4}=0,1\cdot152=15,2\left(g\right)\\m_{ZnSO_4}=0,1\cdot161=16,1\left(g\right)\\m_{H_2}=0,2\cdot2=0,4\left(g\right)\\m_{H_2SO_4\left(dư\right)}=\left(0,22-0,2\right)\cdot98=1,96\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd}=m_{KL}+m_{ddH_2SO_4}-m_{H_2}=211,7\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeSO_4}=\dfrac{15,2}{211,7}\cdot100\%\approx7,18\%\\C\%_{ZnSO_4}=\dfrac{16,1}{211,7}\cdot100\%\approx7,61\%\\C\%_{H_2SO_4}=\dfrac{1,96}{22,4}\cdot100\%\approx0,93\%\end{matrix}\right.\)

Câu 1:

Gọi số mol Al, Fe là a,b (mol)

=> 27a + 56b = 41,5

\(n_{H_2}=\dfrac{28}{22,4}=1,25\left(mol\right)\)

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

______a-------------------------->1,5a_______(mol)

Fe + 2HCl --> FeCl₂ + H₂

b---------------------------->b_______________(mol)

=> 1,5a + b = 1,25

=> \(\left\{{}\begin{matrix}a=0,5\\b=0,5\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{56.0,5}{41,5}.100\%=67,47\%\\\%m_{Al}=\dfrac{27.0,5}{41,5}.100\%=32,53\%\end{matrix}\right.\)

Câu 1:

Đặt \(n_{Al}=x(mol);n_{Fe}=y(mol)\Rightarrow 27x+56y=41,5(1)\)

\(n_{H_2}=\dfrac{28}{22,4}=1,25(mol)\\ PTHH:2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ Fe+H_2SO_4\to FeSO_4+H_2\\ \Rightarrow 1,5x+y=1,25(2)\\ (1)(2)\Rightarrow x=y=0,5(mol)\\ \Rightarrow \%_{Fe}=\dfrac{0,5.56}{41,5}.100\%\approx 67,5\%\\ \Rightarrow \%_{Al}=100\%-67,5\%=32,5\%\)

Chọn D

Câu 2:

\(PTHH:Mg+2HCl\to MgCl_2+H_2\\ \Rightarrow n_{Mg}=n_{H_2}=\dfrac{5,6}{22,4}=0,25(mol)\\ \Rightarrow \%_{Mg}=\dfrac{0,25.24}{27,6}.100\%=21,74\%\\ \Rightarrow \%_{Ag}=100\%-21,74\%=78,26\%\)

Chọn A

Bài 3 : 

a) $Mg + H_2SO_4 \to MgSO_4 + H_2$
$n_{Mg} = n_{H_2} = \dfrac{3,36}{22,4} = 0,15(mol)$
$\%m_{Mg} = \dfrac{0,15.24}{13,2}.100\% = 27,27\%$
$\%m_{Cu} = 100\% -27,27\% = 72,73\%$

b) $n_{Cu} = \dfrac{13,2 - 0,15.24}{64}= 0,15(mol)$

$\Rightarrow m_{muối} = 0,15.120 + 0,15.160= 42(gam)$

Bài 4 : 

Gọi $n_{Fe} = a(mol) ; n_{Mg} = b(mol)$
$56a + 24b = 18,4(1)$

$Fe + 2HCl \to FeCl_2 + H_2$
$Mg + 2HCl \to MgCl_2 + H_2$

Theo PTHH : $n_{H_2} = a + b = \dfrac{11,2}{22,4} = 0,5(2)$

Từ (1)(2) suy ra a = 0,2 ; b = 0,3

$\%m_{Fe} = \dfrac{0,2.56}{18,4}.100\%  = 60,87\%$

$\%m_{Mg} = 100\% -60,87\% = 39,13\%$

b) $n_{HCl} = 2n_{H_2} = 1(mol)$
$V_{dd\ HCl} = \dfrac{1}{0,8}=  1,25(lít)$

3a) \(Mg+H_2SO_4\rightarrow MgSO_4+H_2\)

\(n_{H_2}=n_{Mg}=0,15\left(mol\right)\)

=> \(\%m_{Mg}=\dfrac{0,15.24}{13,2}.100=27,28\%\)

\(\%m_{Cu}=100-27,28=72,73\%\)

b) \(n_{Cu}=\dfrac{13,2-3,6}{64}=0,15\left(mol\right)\)

Cu + 2H2SO4 → CuSO4 + SO2 + 2H2O

0,15------------------->0,15

Mg + 2H2SO4 → MgSO4 + SO2 + 2H2O

0,15------------------->0,15

\(m_{muối}=0,15.160+0,15.120=42\left(g\right)\)

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Chất không tan là Ag.

=> mAg= 6,25(g)

nH2=0,25(mol)

PTHH: Zn + H2SO4 -> ZnSO4 + H2

-> nZn=nH2= 0,25(mol)

=>mZn= 0,25 . 65=16,25(g)

=> \(\%mAg=\dfrac{6,25}{6,25+16,25}.100\approx27,778\%\\ \Rightarrow\%mZn\approx72,222\%\)

PTHH: 

Zn + H₂SO₄ ---> ZnSO₄ + H₂ (1)

2Al + 3H₂SO₄ ---> Al₂(SO₄)₃ + 3H₂ (2)

Ta có: \(n_{H_2}=\dfrac{1,792}{22,4}=0,08\left(mol\right)\)

Gọi x, y lần lượt là số mol của Zn và Al

a. Theo PT₍₁₎: \(n_{H_2}=n_{Zn}=x\left(mol\right)\)

Theo PT₍₂₎: \(n_{H_2}=\dfrac{3}{2}.n_{Al}=\dfrac{3}{2}y\left(mol\right)\)

=> \(x+\dfrac{3}{2}y=0,8\) (*)

Theo đề, ta có: 65x + 27y = 3,79 (**)

Từ (*) và (**), ta có HPT:

\(\left\{{}\begin{matrix}x+\dfrac{3}{2}y=0,8\\65x+27y=3,79\end{matrix}\right.\)

(Ra số âm, bn xem lại đề nhé.)