a) nFe= 0,25(mol)

PTHH: Fe + H2SO4 -> FeSO4 + H2

0,25______0,25______0,25__0,25(mol)

b) V(H2,đktc)=0,25.22,4=5,6(l)

c) mH2SO4= 0,25.98= 24,5(g)

Lời giải "chi tiết"

PTHH: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\uparrow\)

Ta có: \(n_{Fe}=\dfrac{14}{56}=0,25\left(mol\right)=n_{H_2SO_4}=n_{H_2}\)

\(\Rightarrow\left\{{}\begin{matrix}m_{H_2SO_4}=0,25\cdot98=24,5\left(g\right)\\V_{H_2}=0,25\cdot22,4=5,6\left(l\right)\end{matrix}\right.\)

a,PTHH:

=0,25(mol)

Theo pt: nH2=nFe=0,25(mol)

⇒VH2=0,25.22,4=5,6(l)

c, Theo pt: nH2SO4=nFe=0,25(mol)

⇒mH2SO4=0,25.98=24,5(g)

\(n_{Zn}=\dfrac{m_{Zn}}{M_{Zn}}=\dfrac{19,5}{65}=0,3mol\)

\(Zn+\dfrac{1}{2}O_2\rightarrow\left(t^o\right)ZnO\)

1      1/2                   1       (mol)

0,3     0,15                   0,3        ( mol )

PƯ trên thuộc loại phản ứng hóa hợp

\(m_{ZnO}=n_{ZnO}.M_{ZnO}=0,3.81=24,3g\)

\(V_{O_2}=n_{O_2}.22,4=0,15.22,4=3,36l\)

a. \(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)

PTHH : 2Zn + O₂ -> 2ZnO   ( Phản ứng hóa hợp )

             0,3      0,15      0,3

b. \(m_{ZnO}=0,3.81=24,3\left(g\right)\)

c. \(V_{O_2}=0,15.22,4=3,36\left(l\right)\)

2Zn+O2-to>2ZnO

0,1---0,05----0,1

n Zn=0,1 mol

nO2=0,025 mol

=>VO2=0,05.22,4=1,12l

=>mZnO=0,1.81=8,1g

c)Zn dư

=>m ZnO=0,05.81=4,05g

2Zn+O2-to>2ZnO

0,1---0,05----0,1

n Zn=6,5/65=0,1 mol

n O2=0,8/32=0,025 mol

=>VO2=0,05.22,4=1,12l

=>mZnO=0,1.81=8,1g

c)Zn dư

=>m ZnO=0,05.81=4,05g

.

\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\\a, PTHH:4Al+3O_2\rightarrow\left(t^o\right)2Al_2O_3\\ b,n_{O_2}=\dfrac{3}{4}.n_{Al}=\dfrac{3.0,2}{4}=0,15\left(mol\right)\\ \Rightarrow V_{O_2\left(đktc\right)}=0,15.22,4=3,36\left(l\right)\\ c,2KMnO_4\rightarrow\left(t^o\right)K_2MnO_4+MnO_2+O_2\\ n_{KMnO_4}=2.n_{O_2}=2.0,15=0,3\left(mol\right)\\ \Rightarrow m_{KMnO_4}=158.0,3=47,4\left(g\right)\)

\(n_{C_2H_5OH}=\dfrac{13,8}{46}=0,3mol\)

\(C_2H_5OH+3O_2\rightarrow2CO_2+3H_2O\)

     0,3          0,9          0,6                   ( mol )

\(V_{CO_2}=0,6.22,4=13,44l\)

\(V_{kk}=\left(0,9.22,4\right).5=100,8l\)

C2H5OH+3O2-to>2CO2+3H2O

0,3------------0,9-----------0,6

n C2H5OH=0,3 mol

=>VCO2=0,6.22,4=13,44l

=>VO2=0,9.22,4.5=100,8l

\(n_{C_2H_5OH}=\dfrac{13,8}{46}=0,3mol\)

\(C_2H_5OH+3O_2\underrightarrow{t^o}2CO_2+3H_2O\)

0,3               0,9      0,6

\(V_{CO_2}=0,6\cdot22,4=13,44l\)          

\(V_{O_2}=0,9\cdot22,4=20,16l\)

\(V_{kk}=5V_{O_2}=5\cdot20,16=100,8l\)

Đáp án B

Theo giả thiết, bảo toàn nguyên tố C và bảo toàn electron, ta có :

Bài 4 câu a đề là thể tích H2 nha bạn

a)\(Fe2O3+3H2-->2Fe+3H2O\)

\(n_{Fe2O3}=\frac{12}{160}=0,075\left(mol\right)\)

\(n_{H2}=3n_{Fe2O3}=0,225\left(mol\right)\)

\(V_{H2}=0,225.22,4=5,04\left(l\right)\)

b)\(n_{Fe}=2n_{Fe2O3}=0,15\left(mol\right)\)

\(m_{Fe}=0,15.56=8,4\left(g\right)\)

Bài 6

a)\(Zn+H2SO4-->ZnSO4+H2\)

\(n_{Zn}=\frac{19,5}{65}=0,3\left(mol\right)\)

\(n_{ZnSO4}=n_{Zn}=0,3\left(mol\right)\)

\(m_{ZnSO4}=0,3.162=48,3\left(g\right)\)

b)\(n_{H2}=n_{Zn}=0,3\left(mol\right)\)

\(V_{H2}=0,3.22,4=6,72\left(l\right)\)

a)Fe2O3+3H2−−>2Fe+3H2O

0,075-------0,225---0,15 mol

nFe2O3=12/160=0,075(mol)

VH2=0,225.22,4=5,04(l)

b)

mFe=0,15.56=8,4(g)

Bài 6

a)Zn+H2SO4−−>ZnSO4+H2

0,3----------------------0,3---0,3

nZn=19,5/65=0,3(mol)

mZnSO4=0,3.162=48,3(g)

b)

=>VH2=0,3.22,4=6,72(l)

B5, Pthh: \(Zn+H_2SO_4\rightarrow ZnSO_4+H_2\)

Số mol của 19,5g Zn là:

\(n=\frac{m}{M}=\frac{19,5}{65}=0,3\left(mol\right)\)

KL \(ZnSO_4\) sau phản ứng là:

\(m=n\times M=0,3\times\left(65+32+16\times4\right)=48,3\left(g\right)\)

Thể tích khi \(H_2\)(đktc) là

\(V=n\times22,4=0,3\times22,4=6,72\)

\(n_{Al}=\dfrac{5,4}{27}=0,2mol\)

\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)

0,2      0,15    0,1

\(m_{Al_2O_3}=0,1\cdot102=10,2g\)

\(2KClO_3\underrightarrow{t^o}2KCl+3O_2\)

0,1                            0,15

\(m_{KClO_3}=0,1\cdot122,5=12,25g\)

\(PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)

\(n_{Al}=5,4:27=0,2\left(mol\right)\)

\(\Rightarrow n_{Al_2O_3}=0,2.2:4=0,1\left(mol\right);n_{O_2}=0,2.3:4=0,15\left(mol\right)\)

\(m_{Al_2O_3}=0,1.102=10,2\left(g\right)\)

b)\(PTHH:2KClO_3\underrightarrow{t^o}2KCl+3O_2\)

\(n_{O_2}=0,15\left(mol\right)\)(câu a)

\(\Rightarrow n_{KClO_3}=0,15.2:3=0,1\left(mol\right)\)

\(m_{KClO_3}=0,1.123,5=12,35\left(g\right)\)