\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right);n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\left(mol\right)\\ PTHH:Fe+H_2SO_4\rightarrow FeSO_4+H_2\\ Vì:\dfrac{0,4}{1}>\dfrac{0,25}{1}\Rightarrow Fe.dư\\ n_{H_2}=n_{Fe\left(p.ứ\right)}=n_{H_2SO_4}=0,25\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,25.22,4=5,6\left(l\right)\\ b,n_{Fe\left(dư\right)}=0,4-0,25=0,15\left(g\right)\\ m_{Fe\left(dư\right)}=0,14.56=8,4\left(g\right)\)

a) \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\) => Zn hết, HCl dư

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

          0,2--->0,4-------------->0,2

=> \(V_{H_2}=0,2.22,4=4,48\left(l\right)\)

b) \(n_{HCl\left(dư\right)}=0,5-0,4=0,1\left(mol\right)\)

=> \(m_{HCl\left(dư\right)}=0,1.36,5=3,65\left(g\right)\)

nZn = 19.5/65 = 0.3 (mol) 

Zn + H2SO4 => ZnSO4 + H2 

0.3........................0.3.........0.3

VH2 = 0.3*22.4 = 6.72 (l) 

mZnSO4 = 0.3*161 = 48.3 (g) 

nCuO = 16/80 = 0.2 (mol) 

CuO + H2 -to-> Cu + H2O 

0.2........0.2 

=> H2 dư 

mH2 (dư) = ( 0.3 - 0.2 ) * 2 = 0.2 (g) 

nZn=0,3(mol)

a) PTHH: Zn + H2SO4 -> ZnSO4+ H2

0,3___________________0,3____0,3(mol)

mZnSO4=161.0,3=48,3(g)

b) V(H2,đktc)=0,3.22,4=6,72(l)

c) nCuO=16/80=0,2(mol)

PTHH: CuO + H2 -to-> Cu + H2O

vì: 0,3/1 > 0,2/1

=> H2 dư, CuO hết, tính theo nCuO

=> n(H2,dư)=0,3-0,2=0,1(mol)

=> mH2(dư)=0,1.2=0,2(g)

\(n_{Zn}=\dfrac{13}{65}=0,2mol\)

\(n_{HCl}=\dfrac{18,25}{36,5}=0,5mol\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

0,2       0,5            0          0

0,2       0,4            0,2       0,2

0          0,1            0,2       0,2

Sau phản ứng, axit HCl còn dư và dư \(m=0,1\cdot36,5=3,65g\)

\(m_{ZnCl_2}=0,2\cdot136=27,2g\)

\(V_{H_2}=0,2\cdot22,4=4,48l\)

n_Fe=11,2/56=0,2 mol

n_H2SO4=24,5/98=0,25

PTPƯ: Fe +       H₂SO₄ ---> FeSO₄ +        H₂

              _{0,2 mol ----> 0,2 mol --------------------> 0,2 mol}

Ta có Fe:H₂SO₄=0,2/1<0,25/1 (nên H₂SO₄ dư)

a, m_H2SO4=(0,25-0,2).98=4,9 g

b, V_H2=0,2.22,4=4,48 l

PTHH: \(Fe+H_2SO_{4\left(l\right)}\rightarrow FeSO_4+H_2\uparrow\)

Ta có: \(\left\{{}\begin{matrix}n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\\n_{H_2SO_4}=\dfrac{24,5}{98}=0,25\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Sắt còn dư, Axit p/ứ hết

\(\Rightarrow\left\{{}\begin{matrix}n_{H_2}=0,25\left(mol\right)\\n_{Fe\left(dư\right)}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,25\cdot22,4=5,6\left(l\right)\\m_{Fe\left(dư\right)}=0,15\cdot56=8,4\left(g\right)\end{matrix}\right.\)

a) \(Pt:Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

\(n_{Fe}=\dfrac{22,4}{56}=0,4mol\)

\(n_{H_2SO_4}=\dfrac{24,5}{98}=0,25mol\)

Lập tỉ lệ

\(n_{Fe}:n_{H_2SO_4}=\dfrac{0,4}{1}:\dfrac{0,25}{1}=0,4:0,25\)

Do 0,4>0,25 

=> Fe dư

Theo pt: \(n_{H_2}=n_{H_2SO_4}=0,25mol\)

=> \(V_{H_2}=0,25.22,4=5,6lít\)

b) Fe là chất dư sau phản ứng

\(n_{Fe}dư=0,4-0,25=0,15mol\)

\(m_{Fe}dư=0,15.56=8,4g\)

\(a) Fe + H_2SO_4 \to FeSO_4 + H_2\\ n_{Fe} = \dfrac{22,4}{56} = 0,4 > n_{H_2SO_4} = \dfrac{24,5}{98} = 0,25(mol) \to Fe\ dư\\ n_{H_2} = n_{H_2SO_4} = 0,25(mol)\\ V_{H_2} = 0,25.22,4 = 5,6(lít)\\ b) n_{Fe\ pư} = n_{H_2SO_4} = 0,25(mol)\\ \Rightarrow m_{Fe\ dư} = 22,4 - 0,25.56 = 8,4(gam)\)

\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right);n_{HCl}=\dfrac{21,9}{36,5}=0,6\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ Vì:\dfrac{0,4}{1}>\dfrac{0,6}{2}\Rightarrow Zn.dư\\ n_{H_2}=n_{Zn\left(p.ứ\right)}=\dfrac{0,6}{2}=0,3\left(mol\right)\\ a,V_{H_2\left(đktc\right)}=0,3.22,4=6,72\left(l\right)\\ b,n_{Zn\left(dư\right)}=0,4-0,3=0,1\left(mol\right)\Rightarrow m_{Zn\left(dư\right)}=0,1.65=6,5\left(g\right)\)

`n_(Zn)=m/M=(26)/65=0,4(mol)`

`n_(HCl)=m/M=(21,9)/36,5=0,6(mol)`

`PTHH:Zn+2HCl->ZnCl_2 +H_2`

tỉ lệ:      1 ;     2    :  1          :     1

n(mol)   0,3<----0,6---->0,3----->0,3

\(\dfrac{n_{Zn}}{1}>\dfrac{n_{HCl}}{2}\left(\dfrac{0,4}{1}>\dfrac{0,6}{2}\right)\)

`=>` `Zn` dư, `HCl` hết, tính theo `HCl`

`V_(H_2)=n*22,4=0,3*22,4=6,72(l)`

`n_(Zn(dư))=0,4-0,3=0,1(mol)`

`m_(Zn(dư))=n*M=0,1*65=6,5(g)`

Zn+H2SO4->ZnSO4+H2

0,05-------------------------0,05

n Zn=\(\dfrac{4}{65}\) mol

n H2SO4=\(\dfrac{4,9}{98}\)=0,05 mol

=>Zn dư

m Zn=(\(\dfrac{4}{65}\)-0,05).65=0,75 g

VH2=0,05.22,4=1,12l