Đáp án C.

Kim loại không phản ứng với H₂SO₄ loãng là Cu.

Gọi n_Cu = x, n_Mg = y, n_Al = z

Ta có:

64x + 24y + 27z = 33,2 (1)

Bảo toàn e:

2n_Mg + 3n_Al = 2n_H2  

=> 2y + 3z = 2.1 (2)

2n_Cu = 2n_SO2  =>  x = 0.2 (mol) (3)

Từ 1, 2, 3 => x = 0,2; y = z = 0,4 (mol)

m_Cu = 0,2.64 = 12,8 (g)

m_Mg = 0,4.24 = 9,6 (g)

m_Al = 10,8 (g)

\(a,n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=0,2mol\\ m_{Fe}=0,2.56=11,2g\\ m_{Cu}=25-11,2=13,8g\\ b,\%m_{Fe}=\dfrac{11,2}{25}\cdot100=44,8\%\\ \%m_{Cu}=100-44,8=55,2\%\)
c, Gọi CTHH của sắt là \(Fe_xO_y\)

\(Fe_xO_y+yH_2\xrightarrow[t^0]{}xFe+yH_2O\\ \Rightarrow n_{Fe_xO_y}=n_{H_2}:y\\ \Leftrightarrow\dfrac{11,6}{56x+16y}=\dfrac{0,2}{y}\\ \Leftrightarrow11,6y=11,2x+3,2y\\ \Leftrightarrow11,6y-3,2y=11,2x\\ \Leftrightarrow8,4y=11,2x\\ \Leftrightarrow\dfrac{x}{y}=\dfrac{8,4}{11,2}=\dfrac{3}{4}\\ \Rightarrow x=3;y=4\\ \Rightarrow CTHH:Fe_3O_4\)

\(1)n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\\ Zn+H_2SO_4\rightarrow ZnSO_4+H_2\\ n_{Zn}=n_{H_2SO_4}=n_{H_2}=0,2mol\\ \%m_{Zn}=\dfrac{0,2.65}{29,2}\cdot100=44,52\%\\ \%m_{ZnO}=100-44,52=55,48\%)))2\)

\(2)n_{ZnO}=\dfrac{29,2-0,2.65}{81}=0,2mol\\ ZnO+H_2SO_4\rightarrow ZnSO_4+H_2O\\ n_{ZnO}=n_{H_2SO_4}=0,2mol\\ C_{M_{H_2SO_4}}=\dfrac{0,2+0,2}{0,5}=0,8M\)

PTHH: \(Mg+2HCl\rightarrow MgCl_2+H_2\uparrow\)

             \(MgO+2HCl\rightarrow MgCl_2+H_2O\)

Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)=n_{Mg}\)

\(\Rightarrow m_{Mg}=0,1\cdot24=2,4\left(g\right)\) \(\Rightarrow m_{MgO}=2\left(g\right)\)

mg+2hcl-> mgcl2+ h2

mgo+2hcl->mgcl2+ h2o

đặt nmg=a, nmgo=b

theo bài ra và theo pthh ta có hệ:

24a+40b=4,4

a=2,24/22,4

=> a=0,1, b=0,05

-> %m Mg=0,1*24/4,4*100=54,54%

%m MgO=100-54,54=45,45%

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: 

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

0,2     0,2               0,2       0,2

\(a,\%m_{Fe}=\dfrac{0,2.56}{20}.100\%=56\%\)

\(\%m_{Cu}=100\%-56\%=44\%\)

\(b,C_{M\left(H_2SO_4\right)}=\dfrac{0,2}{0,1}=2\left(M\right)\)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

  \(1\)          \(1\)                             \(1\)

  \(0,2\)        \(0,2\)                      \(0,2\)

\(n_{H_2}=\dfrac{V}{22,4}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

\(m_{Fe}=n.M=0,2.56=11,2\left(g\right)\)

\(^0/_0Fe=\dfrac{11,2}{20}.100^0/_0=56^0/_0\)

\(^0/_0Cu=100^0/_0-56^0/_0=44^0/_0\)

\(C_{M_{H_2SO_4}}=\dfrac{n}{V_{dd}}=\dfrac{0,2}{0,1}=2M\)

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1(mol)\\ n_{Mg}=a(mol);n_{Fe}=b(mol)\\ \Rightarrow 24a+27b=4,46(1)\\ Fe+H_2SO_4\to FeSO_4+H_2\\ Mg+H_2SO_4\to MgSO_4+H_2\\ \Rightarrow a+b=0,1(2)\\ (1)(2)\Rightarrow a=\dfrac{-44}{75}(mol);b=\dfrac{103}{150}(mol)\)

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Đáp án C