a) \(n_{Al}=\dfrac{12,15}{27}=0,45\left(mol\right)\)

\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH: 4Al + 3O₂ --t^o--> 2Al₂O₃

Xét tỉ lệ: \(\dfrac{0,45}{4}>\dfrac{0,3}{3}\)=> Al dư, O₂ hết

PTHH: 4Al + 3O₂ --t^o--> 2Al₂O₃

            0,4<--0,3-------->0,2

=> \(m_{Al\left(dư\right)}=\left(0,45-0,4\right).27=1,35\left(g\right)\)

b) \(m_{Al_2O_3}=0,2.102=20,4\left(g\right)\)

\(n_{Fe}=\dfrac{12.6}{56}=0.225\left(mol\right)\)

\(n_{O_2}=\dfrac{4.2}{22.4}=0.1875\left(mol\right)\)

\(3Fe+2O_2\underrightarrow{^{^{t^0}}}Fe_3O_4\)

\(3.........2\)

\(0.225......0.1875\)

Lập tỉ lệ : \(\dfrac{0.225}{3}< \dfrac{0.1875}{2}\Rightarrow O_2dư\)

\(m_{O_2\left(dư\right)}=\left(0.1875-0.225\cdot\dfrac{2}{3}\right)\cdot32=1.2\left(g\right)\)

\(m_{Fe_3O_4}=\dfrac{0.225}{3}\cdot232=17.4\left(g\right)\)

a)

\(n_{Al} = \dfrac{12,15}{27} = 0,45(mol)\\ n_{O_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ 4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ \dfrac{n_{Al}}{4} = 0,1125 < \dfrac{n_{O_2}}{3} = 0,1\)

Do đó, Al dư.

\(n_{Al\ pư} = \dfrac{4}{3}n_{O_2} = 0,4(mol)\\ m_{Al\ dư} = (0,45-0,4).27 =1,35(gam)\)

b) Nhôm oxit được tạo thành.

\(n_{Al_2O_3} = \dfrac{2}{3}n_{O_2} = 0,2(mol)\\ \Rightarrow m_{Al_2O_3} = 0,2.102 = 20,4(gam)\)

\(n_{Al}=\dfrac{m}{M}=0,45\left(mol\right)\)

\(n_{O_2}=\dfrac{V}{22,4}=0,3\left(mol\right)\)

a, \(PTHH:4Al+3O_2\rightarrow2Al_2O_3\)

=> Sau phản ứng O2 hết, Al dư ( dư 0,05 mol )

=> \(m_{Aldu}=n.M=1,35\left(g\right)\)

b, Chất được tạo thành là Al₂O₃ .

Theo PTHH : \(n_{Al_2O_3}=0,2\left(mol\right)\)

\(\Rightarrow m_{Al_2O_3}=n.M=20,4\left(g\right)\)

Vậy ...

\(a)\\ n_{O_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\\ \dfrac{n_P}{4} = 0,05 < \dfrac{n_{O_2}}{5} = 0,06\)

Do đó, Oxi dư.

\(n_{O_2\ pư} = \dfrac{5}{4}n_P = 0,25(mol)\\ \Rightarrow m_{O_2\ dư} = (0,3 - 0,25).32 = 1,6(gam)\\ b)\\ n_{P_2O_5} = \dfrac{n_P}{2} = 0,1(mol)\\ \Rightarrow m_{P_2O_5} = 0,1.142 = 14,2(gam)\)

nAl=\(\dfrac{5,4}{27}\)=0,2mol

nO2=\(\dfrac{4,48}{22,4}\)=0,2mol

PTHH:

4Al + 3O2--to->2Al2O3

Tỉ lệ \(\dfrac{0,2}{4}\) <\(\dfrac{0,2}{3}\)->Al hết O2 dưtính theo Al

=>m O2=\(\dfrac{1}{60}\).32=\(\dfrac{8}{15}\)g

2KMnO4-to>K2MnO4+MnO2+O2

0,4--------------------------------------0,2

m KMnO4=0,4.158=63,2g

.

\(n_P=\dfrac{6,2}{31}=0,2\left(mol\right)\\ n_{O_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ PTHH:4P+5O_2\underrightarrow{t^o}2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,4}{5}\Rightarrow O_2dư\)

\(n_{O_2\left(pư\right)}=\dfrac{5}{4}n_P=\dfrac{5}{4}.0,2=0,25\left(mol\right)\\ n_{O_2\left(dư\right)}=0,4-0,25=0,15\left(mol\right)\)

\(n_{P_2O_5\left(lt\right)}=\dfrac{1}{2}n_P=\dfrac{1}{2}.0,2=0,1\left(mol\right)\\ m_{P_2O_5\left(lt\right)}=0,1.142=14,2\left(g\right)\\ m_{P_2O_5\left(tt\right)}=0,1.142.80\%=11,36\left(g\right)\)

PTHH: \(4P+5O_2\underrightarrow{t^o}2P_2O_5\)

a) Ta có: \(\left\{{}\begin{matrix}n_{P_2O_5}=\dfrac{10,65}{142}=0,075\left(mol\right)\\\Sigma n_{O_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\end{matrix}\right.\) 

\(\Rightarrow\left\{{}\begin{matrix}n_P=0,15mol\\n_{O_2\left(dư\right)}=0,0625mol\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_P=0,15\cdot31=4,65\left(g\right)\\m_{O_2\left(dư\right)}=0,0625\cdot32=2\left(g\right)\end{matrix}\right.\)

b) Ta có: \(n_{O_2\left(pư\right)}=0,1875mol\) \(\Rightarrow\left\{{}\begin{matrix}m_{O_2\left(pư\right)}=0,1875\cdot32=6\left(g\right)\\V_{O_2\left(pư\right)}=0,1875\cdot22,4=4,2\left(l\right)\end{matrix}\right.\)

Sau phản ứng chất nào được tạo thành vậy bạn?