\(\left(a\right)2Al+3H_2O\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ \left(b\right)n_{H_2}=\dfrac{13,44}{22,4}=0,6mol\\ n_{Al}=\dfrac{0,6.2}{3}=0,4mol\\ m_{Al}=0,4.27=10,8g\\ \left(c\right)n_{O_2}=\dfrac{4,8}{32}=0,15mol\\ 4Al+3O_2\underrightarrow{t^0}2Al_2O_3\\ \Rightarrow\dfrac{0,4}{4}>\dfrac{0,15}{3}\Rightarrow Al.dư\\ n_{Al_2O_3}=\dfrac{0,15.2}{3}=0,1mol\\ m_{oxit}=m_{Al_2O_3}=0,1.102=10,2g\)

a: \(2Al+3H_2SO_4\rightarrow1Al_2\left(SO_4\right)_3+3H_2\uparrow\)

    0,4           0,6                0,2             0,6

b: \(n_{H_2}=\dfrac{13.44}{22.4}=0.6\left(mol\right)\)

=>\(n_{Al}=0.4\left(mol\right)\)

\(m_{Al}=0.4\cdot27=10.8\left(g\right)\)

c: \(4Al+3O_2\rightarrow2Al_2O_3\)

0,4                      0,2

\(m_{Al_2O_3}=0.2\left(27\cdot2+16\cdot3\right)=0.2\cdot102=20.4\left(g\right)\)

\(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

PTHH ;

2Al + 3H2SO4 --> Al2(SO4)3 + 3H2↑

  0,4           0,6               0,2           0,6

4Al + 3O2 ---> 2Al2O3

0,2       0,15          0,1 

\(n_{O_2}=\dfrac{4,8}{32}=0,15\left(mol\right)\)

\(\dfrac{0,4}{4}>\dfrac{0,15}{3}\)

--> Tính theo oxi

\(b,m_{Al}=0,4.27=10,8\left(g\right)\)

\(c,m_{Al_2O_3}=0,1.102=10,2\left(g\right)\)

2Al+3H2SO4->Al2(SO4)3+3H2

0,1----------------------0,075----0,15

n H2=0,15 mol

=>mAl=0,1.27=2,7g

=>m Al2(SO4)3=0,075.342=25,65g

a) PTHH: \(2Al+3H_2SO_2\rightarrow Al_2\left(SO_4\right)_3+3H_2\)

b) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

\(n_{Al}=\dfrac{2}{3}.0,15=0,1\left(mol\right)\)

\(m_{Al}=0,1.27=2,7\left(g\right)\)

c) \(n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)

\(m_{Al_2\left(SO_4\right)_3}=0,05.342=17,1\left(g\right)\)

2Al+3H2SO4->Al2(SO4)3+3H2

0,1----------------------0,075----0,15

n H2=0,15 mol

=>mAl=0,1.27=2,7g

=>m Al2(SO4)3=0,075.342=25,65g

\(a,n_{H_2SO_4}=0,5\cdot0,1=0,05\left(mol\right)\\ PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ \Rightarrow n_{H_2}=n_{H_2SO_4}=0,05\left(mol\right)\\ \Rightarrow V_{H_2\left(đktc\right)}=0,05\cdot22,4=1,12\left(l\right)\\ b,n_{Al}=\dfrac{2}{3}n_{H_2SO_4}=\dfrac{1}{30}\left(mol\right)\\ \Rightarrow m_{Al}=\dfrac{1}{30}\cdot27=0,9\left(g\right)\\ c,n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{3}n_{H_2SO_4}\approx0,017\left(mol\right)\\ \Rightarrow C_{M_{Al_2\left(SO_4\right)_3}}=\dfrac{0,017}{0,1}\approx0,17M\)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

\(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

\(n_{H_2}=n_{Fe}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)

\(m_{CuO}=35.2-0.2\cdot56=24\left(g\right)\)

\(n_{CuO}=\dfrac{24}{80}=0.3\left(mol\right)\)

\(\%Fe=\dfrac{11.2}{35.2}\cdot100\%=31.82\%\)

\(\%CuO=100-31.82=68.18\%\)

\(n_{H_2SO_4}=0.2+0.3=0.5\left(mol\right)\)

\(m_{H_2SO_4}=0.5\cdot98=49\left(g\right)\)

\(C\%H_2SO_4=\dfrac{49}{800}\cdot100\%=6.125\%\)

\(m_{FeSO_4}=0.2\cdot152=30.4\left(g\right)\)

\(m_{CuSO_4}=0.3\cdot160=48\left(g\right)\)

Bài 1:

\(n_{H_2SO_4}=\dfrac{300.19,6\%}{98}=0,6\left(mol\right);n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ PTHH:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\\ Vì:\dfrac{0,1}{2}< \dfrac{0,6}{3}\Rightarrow H_2SO_4dư\\ n_{Al_2\left(SO_4\right)_3}=\dfrac{3n_{Al}}{2}=\dfrac{3.0,1}{2}=0,15\left(mol\right)\\ a,m_{Al_2\left(SO_4\right)_3}=342.0,15=51,3\left(g\right)\\ b,m_{ddsau}=m_{Al}+m_{ddH_2SO_4}-m_{H_2}=2,7+300-\dfrac{3}{2}.0,1.2=302,4\left(g\right)\\ c,C\%_{ddAl_2\left(SO_4\right)_3}=\dfrac{51,3}{302,4}.100\%\approx16,964\%\\ n_{H_2SO_4\left(dư\right)}=0,6-\dfrac{3}{2}.0,1=0,45\left(mol\right)\\ C\%_{ddH_2SO_4\left(dư\right)}=\dfrac{0,45.98}{302,4}.100\%\approx14,583\%\)

Bài 2:

\(PTHH:2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Mg+2HCl\rightarrow MgCl_2+H_2\\ Đặt:n_{Al}=a\left(mol\right);n_{Mg}=b\left(mol\right)\left(a,b>0\right)\\ Hpt:\left\{{}\begin{matrix}27a+24b=7,8\\1,5a+b=\dfrac{8,96}{22,4}=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,2\\b=0,1\end{matrix}\right.\\ \%m_{Al}=\dfrac{0,2.27}{7,8}.100\%\approx69,231\%\Rightarrow\%m_{Mg}\approx100\%-69,231\%\approx30,769\%\)

a, \(n_{Fe}=\dfrac{0,56}{56}=0,01\left(mol\right)\)

PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

Theo PT: \(n_{FeSO_4}=n_{H_2}=n_{Fe}=0,01\left(mol\right)\)

\(\Rightarrow m_{FeSO_4}=0,01.152=1,52\left(g\right)\)

\(V_{H_2}=0,01.22,4=0,224\left(l\right)\)

b, \(n_{H_2SO_4}=n_{Fe}=0,01\left(mol\right)\Rightarrow m_{ddH_2SO_4}=\dfrac{0,01.98}{19,6\%}=5\left(g\right)\)

c, Ta có: m _{dd sau pư} = 0,56 + 5 - 0,01.2 = 5,54 (g)

\(\Rightarrow C\%_{FeSO_4}=\dfrac{1,52}{5,54}.100\%\approx27,44\%\)

Sửa: \(14,7\%\)

\(n_{H_2SO_4}=\dfrac{200.14,7\%}{100\%.98}=0,3(mol)\\ a,PTHH:2Al+3H_2SO_4\to Al_2(SO_4)_3+3H_2\\ \Rightarrow n_{H_2}=0,3(mol)\\ \Rightarrow V_{H_2}=0,3.22,4=6,72(l)\\ b,n_{Al}=\dfrac{2}{3}n_{H_2SO_4}=0,2(mol)\\ \Rightarrow m_{Al}=0,2.27=5,4(g)\\ c,n_{Al_2(SO_4)_3}=\dfrac{1}{2}n_{Al}=0,1(mol)\\ \Rightarrow C\%_{Al_2(SO_4)_3}=\dfrac{0,1.342}{200+5,4-0,3.2}.100\%=16,7\%\\ c,m_{Al_2(SO_4)_3}=0,1.342=34,2(g)\)

\(n_{Al}=\dfrac{21,6}{27}=0,8\left(mol\right)\)

Pt : \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2O|\)

        2             3                  1                3

       0,8          1,2               0,4             1,2

a) \(n_{H2}=\dfrac{0,8.3}{2}=1,2\left(mol\right)\)

\(V_{H2\left(dktc\right)}=1,2.22,4=26,88\left(l\right)\)

b) \(n_{H2SO4}=\dfrac{0,8.3}{2}=1,2\left(mol\right)\)

⇒ \(m_{H2SO4}=1,2.98=117,6\left(g\right)\)

\(m_{ddH2SO4}=\dfrac{117,6.100}{29,4}=400\left(g\right)\)

c) \(n_{Al2\left(SO4\right)3}=\dfrac{1,2.1}{3}=0,4\left(mol\right)\)

⇒ \(m_{Al2\left(SO4\right)3}=0,4.342=136,8\left(g\right)\)

\(m_{ddspu}=21,6+400-\left(1,2.2\right)=419,2\left(g\right)\)

\(C_{Al2\left(SO4\right)3}=\dfrac{136,8.100}{419,2}=32,63\)⁰/₀

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