PTHH: \(MO+H_2SO_4\rightarrow MSO_4+H_2O\)

Giả sử \(V_{ddH_2SO_4}=3720\left(ml\right)\)

Ta có: \(m_{ddH_2SO_4}=\dfrac{3720}{1,86}=2000\left(g\right)\) \(\Rightarrow n_{H_2SO_4}=\dfrac{2000\cdot4,9\%}{98}=1\left(mol\right)=n_{MO}=n_{MSO_4}\)

\(\Rightarrow\left\{{}\begin{matrix}m_{MO}=M+16\left(g\right)\\m_{MSO_4}=M+96\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{MO}+m_{ddH_2SO_4}=M+2016\left(g\right)\)

\(\Rightarrow C\%_{MSO_4}=\dfrac{M+96}{M+2016}=0,0769\) \(\Rightarrow M=64\)

  Vậy kim loại cần tìm là Đồng

`MO + H_2 SO_4 -> MSO_4 + H_2 O`

  `1`            `1`                   `1`             `1`            `(mol)`

Giả sử `n_[H_2 SO_4] = 1 (mol)`

`m_[dd H_2 SO_4] = [ 1 . 98 ] / [ 17,5 ] . 100 = 560 (g)`

`C%_[MSO_4] = [ 1 ( M_M + 96 ) ] / [ 1 . ( M_M + 16 ) + 560 ] . 100 = 20`

        `<=> M_M = 24`

     `=> M` là `Mg`

Gọi CTHH oxit kim loại là \(RO\)

Giả sử có 1mol oxit pứ

\(RO+H_2SO_4\rightarrow RSO_4+H_2O\)

\(1-\rightarrow1---\rightarrow1\)

\(m_{ddH_2SO_4}=\dfrac{1.98}{4,9}\cdot100=2000\left(g\right)\\ m_{ddRSO_4}=1\left(R+16\right)+2000=2016+R\left(g\right)\\ C_{\%RSO_4}=\dfrac{1\left(R+96\right)}{2016+R}\cdot100=5,88\%\\ \Rightarrow R\approx24\left(g/mol\right)\)

Vậy R là Mg

Sửa 5,78 thành 5,88%

Gọi kim loại là R $\Rightarrow$ Oxit là RO

Gỉa sử nRO=1 mol

$RO+{}^{}S{}^{}\to RS{}^{}+{}^{}O$

Ta có: nRO=nH2SO4=nRSO4=1(mol)nRO=nH2SO4=nRSO4=1(mol)

⇒mH2SO4=198=98(g)⇒mH2SO4=198=98(g)

mddH2SO4=984,9%=2000(g)mddH2SO4=984,9%=2000(g)

BTKL: m dung dịch sau phản ứng=mRO + m dd H2SO4

$=1\left(R+15\right)+200=R+2016($

\(Đặt.oxit:A_2O_3\\ A_2O_3+3H_2SO_4\rightarrow A_2\left(SO_4\right)_3+3H_2O\\ n_{Al_2O_3}=\dfrac{34,2-10,2}{96.3-16.3}=0,1\left(mol\right)\\ M_{A_2O_3}=\dfrac{10,2}{0,1}=102\left(\dfrac{g}{mol}\right)=2M_A+48\\ \Rightarrow M_A=27\left(\dfrac{g}{mol}\right)\\ a,\Rightarrow A.là.nhôm\left(Al=27\right)\\ b,n_{H_2SO_4}=3.0,1=0,3\left(mol\right)\\ C\%_{ddH_2SO_4}=\dfrac{0,3.98}{100}.100=29,4\%\\ c,n_{Al_2\left(SO_4\right)_3}=n_{Al_2O_3}=0,1\left(mol\right)\\ Al_2\left(SO_4\right)_3+6NaOH\rightarrow2Al\left(OH\right)_3+3Na_2SO_4\\ n_{NaOH}=6.0,1=0,6\left(mol\right)\\ V_{ddNaOH}=\dfrac{0,6}{1,5}=0,4\left(l\right)\)

Giả sử có 100 g dung dịch acid.

\(n_{MO}=n_{MSO_4}=n_{H_2SO_4}=\dfrac{a}{98}\left(mol\right)\\ m_{ddsau}=\dfrac{\left(M+16\right)a}{98}+100=\dfrac{\left(M+96\right)a}{98\cdot\dfrac{b}{100}}=\dfrac{a\left(M+96\right)}{0,98b} \)

\(\dfrac{M+16}{98}+100=\dfrac{M+96}{0,98b}\\ M+16+9800=\dfrac{100M+9600}{b}\\ bM+9816=100M+9600\\ M\left(100-b\right)=216\\ M=\dfrac{216}{100-b}\left(g\cdot mol^{-1}\right)\)

CT oxit : MO

Đặt số mol oxit phản ứng là 1 mol

\(MO+H_2SO_4\rightarrow MSO_4+H_2O\)

\(m_{ddH_2SO_4}=\dfrac{1.98}{15,8\%}=620,25\left(g\right)\)

\(m_{ddsaupu}=620,25+M+16=M+636,25\left(g\right)\)

Ta có : \(C\%_{MSO_4}=\dfrac{M+96}{M+636,25}.100=22,959\)

=> M=65 (Zn)

=> Oxit kim loại : ZnO (Kẽm oxit)