Sửa đề 2,6 -> 2,3 gam

a) $2Na + 2H_2O \to 2NaOH + H_2$

n Na = 2,3/23 = 0,1(mol)

n H2 = 1/2 n Na = 0,05(mol)

=> V H2 = 0,05.22,4 = 1,12(lít)

b) n NaOH = n Na = 2,3/23 = 0,1(mol)

=> CM NaOH = 0,1/0,2 = 0,5M

Mg+2HCl->MgCl2+H2

0,15--0,3--------------0,15

CuO+2HCl->CuCl2+H2O

0,1------0,2

n H2=\(\dfrac{3,36}{22,4}\)=0,15 mol
=>%m Mg=\(\dfrac{0,15.24}{11,6}.100=31,03\%\)

=>m CuO=8g =>n CuO=\(\dfrac{8}{80}\)=0,1 mol

=>%m CuO=68,97%

=>CM HCl=\(\dfrac{0,3+0,2}{0,2}\)=2,5M

nFe = 5.6/56 = 0.1 (mol) 

nHCl = 0.2*2 = 0.4 (mol) 

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

LTL : 0.1/1 < 0.4/2 => HCl dư 

mHCl dư = ( 0.4 - 0.2 ) * 36.5 = 7.3 (g) 

VH2 = 0.2*22.4 = 4.48 (l) 

CM FeCl2 = 0.1/0.2 = 0.5(M)

CM HCl dư = 0.2 / 0.2 = 1(M) 

$a\big)$

$Zn+2CH_3COOH\to (CH_3COO)_2Zn+H_2$

$ZnO+2CH_3COOH\to (CH_2COO)_2Zn+H_2O$

Theo PT: $n_{Zn}=n_{H_2}=\frac{4,48}{22,4}=0,2(mol)$

$\to \%m_{Zn}=\frac{0,2.65}{21,1}.100\%\approx 61,61\%$

$\to \%m_{ZnO}=100-61,61=38,39\%$

$b\big)$

$n_{ZnO}=\frac{21,1-0,2.65}{81}=0,1(mol)$

Theo PT: $\sum n_{CH_3COOH}=2n_{Zn}+2n_{ZnO}=0,6(mol)$

$\to C_{M_{CH_3COOH}}=\dfrac{0,6}{\frac{200}{1000}}=3M$

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)

\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)

 0,2                                                                0,2     ( mol )

\(m_{Zn}=0,2.65=13g\)

\(\%m_{Zn}=\dfrac{13}{21,1}.100=61,61\%\)

\(\%m_{ZnO}=100\%-61,61\%=38,39\%\)

\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)

0,2               0,4                                                  ( mol )

\(n_{ZnO}=\dfrac{21,1-13}{81}=0,1mol\)

\(ZnO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2O\)

 0,1              0,2                                                        ( mol )

\(C_{M\left(CH_3COOH\right)}=\dfrac{0,4+0,2}{0,2}=3M\)

Bài 1:

\(2Na+2H_2O\rightarrow2NaOH+H_2\\ n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ n_{Na}=n_{Na_2O}=0,2.2=0,4\left(mol\right)\\ a.m_{Na}=0,4.23=9,2\left(g\right)\\ b.C_{MddA}=\dfrac{0,4}{0,5}=0,8\left(M\right)\\ C\%_{ddA}=\dfrac{0,4.40}{500.1,2}.100\approx2,667\%\)

a) PTHH: \(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

                   a_____2a______a_____a      (mol)

                \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

                    b_____3b_______b_____\(\dfrac{3}{2}\)b         (mol)

Ta lập HPT: \(\left\{{}\begin{matrix}56a+27b=36,1\\a+\dfrac{3}{2}b=\dfrac{21,28}{22,4}=0,95\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}a=0,5\\b=0,3\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Fe}=0,5\cdot56=28\left(g\right)\\m_{Al}=8,1\left(g\right)\end{matrix}\right.\)

b+c) Theo các PTHH: \(\left\{{}\begin{matrix}n_{HCl}=2a+3b=1,9\left(mol\right)\\n_{FeCl_2}=0,5\left(mol\right)\\n_{AlCl_3}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{HCl}}=\dfrac{1,9}{0,2}=9,5\left(M\right)\\C_{M_{FeCl_2}}=\dfrac{0,5}{0,2}=2,5\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\end{matrix}\right.\)

Bài 1 : 

a) $2Na + 2H_2O \to 2NaOH + H_2$

b) $n_{H_2} = \dfrac{5,6}{22,4} = 0,25(mol) \Rightarrow n_{Na} = 2n_{H_2} = 0,5(mol)$
$m_{Na} = 0,5.23 = 11,5(gam)$

c) $n_{NaOH} = n_{Na} = 0,5(mol)$

$C_{M_{NaOH}} = \dfrac{0,5}{0,2} = 2,5M$

$m_{H_2O} = D.V = 200.1 = 200(gam)$

$m_{dd} = 11,5 + 200 - 0,25.2 = 211(gam)$
$C\%_{NaOH} = \dfrac{0,5.40}{211}.100\% = 9,48\%$

Bài 2:

\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ n_{O_2}=\dfrac{11,2.20\%}{22,4}=0,1\left(mol\right)\\ 4Al+3O_2\underrightarrow{^{to}}2Al_2O_3\\ Vì:\dfrac{0,1}{4}< \dfrac{0,3}{1}\Rightarrow O_2dư\\ \Rightarrow Sau.p.ứng:Al_2O_3,O_2dư,N_2\\ n_{N_2}=\dfrac{80}{20}.0,1=0,4\left(mol\right)\Rightarrow m_{N_2}=28.0,4=11,2\left(g\right)\\ n_{O_2\left(dư\right)}=0,1-\dfrac{3}{4}.0,1=0,025\left(mol\right)\\ m_{O_2\left(dư\right)}=0,025.32=0,8\left(g\right)\\ n_{Al_2O_3}=\dfrac{2}{4}.0,1=0,05\left(mol\right)\\ m_{Al_2O_3}=102.0,05=5,1\left(g\right)\)

Bài 2 : 

$n_{Al} = \dfrac{2,7}{27} = 0,1(mol) ; n_{O_2} = \dfrac{11,2.20\%}{22,4} = 0,1(mol)$
$4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3$

Ta thấy : 

$n_{Al} : 4 < n_{O_2} : 3$ nên $O_2$ dư

Sau phản ứng, thu được : 

$n_{Al_2O_3} = \dfrac{1}{2}n_{Al} = 0,05(mol) \Rightarrow m_{Al_2O_3} = 0,05.102 = 5,1(gam)$
$n_{O_2\ pư} = \dfrac{3}{4}n_{Al} = 0,075(mol) \Rightarrow m_{O_2\ dư} = (0,1 - 0,075).32 = 0,8(gam)$
$n_{N_2} = 0,5 - 0,1 = 0,4(mol) \Rightarrow m_{N_2} = 0,4.28 = 11,2(gam)$

\(n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ a.2Na+2H_2O\rightarrow2NaOH+H_2\\ b.0,5.......0,5.........0,5..........0,25\left(mol\right)\\ b.m_{Na}=0,5.23=11,5\left(g\right)\\ c.C\%_{ddA}=C\%_{ddNaOH}=\dfrac{0,5.40}{0,5.23+200.1-0,25.2}.100\approx9,479\%\)