Ta có     1đvC = 1,9926 .10-23 / 12 = 0,16605 .10-23 (g)

Khối lương nguyên tử Natri tính bằng gam là :

      0,16605 .10-23 . 23 = 3,81915 .10-23 ( g )

 1đvc =1,9926.10^-23/12=0,16605.10^-23

mNa=0,16605.10^-23.23=3,81915.10^-23 (g)

Gọi x là số mol \(SO_2\), y là số mol \(SO_3\)

có: 64x + 80y = 1,408 (1)

2,2 g khí X = 1 g khí O\(_2\) có thể tích bằng nhau

=> 1,408g X = 0,64 g khí \(O_2\)

<=> x + y      = \(\dfrac{0,64}{32}=0,02\) (2)

Từ (1), (2) suy ra:

x = 0,012

y = 0,008

=> \(n_{O\left(trong.hh.X\right)}=0,012.2+0,008.3=0,048\left(mol\right)\)

=> \(n_{Fe_2\left(SO_4\right)_3}=0,048:12=0,004\left(mol\right)\)

=> \(m_{Fe_2\left(SO_4\right)_3}=0,004.400=1,6\left(g\right)\)

\(a.n_{Fe_2O_3}=\dfrac{32}{160}=0,2mol\\ Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)

0,2             0,6                0,2                      0,6

\(m_{Fe_2\left(SO_4\right)_3}=0,2.400=80g\\ b.m_{H_2SO_4}=0,6.98=58,8g\\ c)Fe_2\left(SO_4\right)_3+6NaOH\rightarrow3Na_2SO_3+2Fe\left(OH\right)_3\)

\(n_{Fe\left(OH\right)_3}=2.0,2=0,4mol\\ m_{Fe\left(OH\right)_3}=0,4.107=42,8g\)

`n_(Fe_2O_3)=m/M=32/160=0,2(mol)`

\(PTHH:Fe_2O_3+3H_2SO_4->Fe_2\left(SO_4\right)_3+3H_2O\)

tỉ lệ          1         :     3            :          1           ;      3

n(mol)    0,2--------->0,6------------>0,2------------->0,6

\(m_{Fe_2\left(SO_4\right)_3}=n\cdot M=0,2\cdot400=80\left(g\right)\)

\(m_{H_2SO_4}=n\cdot M=0,6\cdot98=58,8\left(g\right)\)

\(PTHH:Fe_2\left(SO_4\right)_3+6NaOH->2Fe\left(OH\right)_3+3Na_2SO_4\)

tỉ lệ              1           :       6           ;           2           ;     3

n(mol)        0,2------------->1,2------------->0,4---------->0,6

\(m_{Fe\left(OH\right)_3}=n\cdot M=0,4\cdot107=42,8\left(g\right)\)

\(n_{Fe_3O_4}=\dfrac{23.2}{232}=0.1\left(mol\right)\)

\(PTHH:Fe_3O_4+4H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+FeSO_4+4H_2O\)

\(...........0.1....................0.1.......0.1.........0.1\)

\(m_{FeSO_4}=0.1\cdot152=15.2\left(g\right)\)

\(m_{Fe_2\left(SO_4\right)_3}=0.1\cdot400=40\left(g\right)\)

\(m_{H_2O}=0.1\cdot18=1.8\left(g\right)\)

a)

$Fe_3O_4 + 4H_2SO_4 \to FeSO_4 + Fe_2(SO_4)_3 + 4H_2O$
b)

Theo PTHH : 

$n_{FeSO_4} = n_{Fe_2(SO_4)_3} = n_{Fe_3O_4} = \dfrac{23,2}{232} = 0,1(mol)$
$m_{FeSO_4} = 0,1.152 = 15,2(gam)$

c)

$m_{Fe_2(SO_4)_3} = 0,1.400 = 40(gam)$
d)

$n_{H_2O} = 4n_{Fe_3O_4} = 0,4(mol)$

$m_{H_2O} = 0,4.18 = 7,2(gam)$

a) Giả sử có 100 gam hỗn hợp

=> \(m_S=\dfrac{100.22,61}{100}=22,61\left(g\right)\)

=> \(n_S=\dfrac{22,61}{32}=\dfrac{2261}{3200}\left(mol\right)\)

Mà n_O = 4n_S 

=> \(n_O=\dfrac{2261}{800}\left(mol\right)\)

\(\%m_O=\dfrac{\dfrac{2261}{800}.16}{100}.100\%=45,22\%\)

b) 

\(n_{Fe}=\dfrac{18.10^{24}}{6.10^{23}}=30\left(mol\right)\)

=> \(n_{Fe_2\left(SO_4\right)_3}=15\left(mol\right)\)

Gọi số mol CuSO₄ là x (mol)

=> m_hh = 160x + 6000 (g)

n_S = 15.3 + x = x + 45 (mol)

\(\%m_S=\dfrac{\left(x+45\right).32}{160x+6000}.100\%=22,61\%\)

=> x = 20 (mol)

m_hh = 160.20 + 6000 = 9200 (g)

Ta có: n_C= \(\dfrac{1,9926.10^{-23}}{12}\) = 1,6605.10^-24

=> m_Na = ( 1,6605. 10^-24) .23= 3,81915.10^-23