PTHH: \(CaCl_2+Na_2CO_3\rightarrow CaCO_3\downarrow+2NaCl\)

a+b) Ta có: \(n_{CaCl_2}=0,1\cdot2=0,2\left(mol\right)\) 

\(\Rightarrow\left\{{}\begin{matrix}n_{CaCO_3}=0,2\left(mol\right)\\n_{NaCl}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CaCO_3}=0,2\cdot100=20\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,4}{0,1+0,2}\approx1,33\left(M\right)\end{matrix}\right.\)

c) PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\)

Theo PTHH: \(n_{HCl}=2n_{CaCO_3}=0,4\left(mol\right)\) \(\Rightarrow m_{ddHCl}=\dfrac{0,4\cdot36,5}{10\%}=146\left(g\right)\)

a.PTHH:CaCl2+Na2CO3--->CaCO3+2NaCl

Ta có:nCaCl2=0,2

=>nCaCO3=nCaCl2=0,2(mol)=>mCaCO3(kết tủa)=100.0,2=2(g)

b.Vdd=100+200=300(ml)=0,3(l)

CM Nacl=(2.0,2)/0,3=4/3(M)(Đề cho 2 chất td vừa đủ nên dd sau pứ chỉ có NaCl)

c.CaCO3+2HCl--->CaCl2+CO2+H2O

nHCl(cần dùng)=2.0.2=0,4(mol)=>mHCl=36,5.0,4=14,6(g)

=>mddHCl=14,6/10%=146(g)

\(n_{HCl}=0,1.1=0,1\left(mol\right)\)

\(n_{Ba\left(OH\right)_2}=0,1.1=0,1\left(mol\right)\)

PTHH :

                 \(2HCl+Ba\left(OH\right)_2\rightarrow BaCl_2+2H_2O\)

trc p/u :        0,1          0,1 

p/u :               0,1       0,05            0,05        0,1

sau p/u :      0            0,05             0,05        0,1 

\(C_{M_{BaCl_2}}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)

\(C_{M_{Ba\left(OH\right)_2dư}}=\dfrac{0,05}{0,2}=0,25\left(M\right)\)

\(m_{BaCl_2}=0,05.208=10,4\left(g\right)\)

\(n_{KOH}=0.1\cdot1=0.1\left(mol\right)\)

\(n_{HCl}=0.1\cdot0.5=0.05\left(mol\right)\)

\(KOH+HCl\rightarrow KCl+H_2O\)

\(0.05.......0.05.......0.05\)

Dung dịch D : 0.05 (mol) KOH , 0.05 (mol) KCl

\(\left[K^+\right]=\dfrac{0.05+0.05}{0.1+0.1}=0.5\left(M\right)\)

\(\left[Cl^-\right]=\dfrac{0.05}{0.2}=0.25\left(M\right)\)

\(\left[OH^-\right]=\dfrac{0.05}{0.2}=0.25\left(M\right)\)

\(2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)

\(0.05.........0.025\)

\(V_{dd_{H_2SO_4}}=\dfrac{0.025}{1}=0.025\left(l\right)\)

D. 4M

\(Na_2O + 2HCl \rightarrow 2NaCl + H_2O\)

Theo PTHH:

\(n_{HCl}= 2n_{Na_2O}= 2 . 0,2 = 0,4 mol\)

\(\Rightarrow C_M= \dfrac{n_{HCl}}{V_{HCl}}= \dfrac{0,4}{0,1}= 4M\)

\(CuO+2HCl\rightarrow CuCl_2+H_2O\\ n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\\ n_{HCl}=2.0,1=0,2\left(mol\right)\\ V_{ddHCl}=\dfrac{0,2}{1}=0,2\left(l\right)\\ V_{ddsau}=V_{ddHCl}=0,2\left(l\right)\\ n_{CuCl_2}=n_{CuO}=0,2\left(mol\right)\\ C_{MddCuCl_2}=\dfrac{0,2}{0,2}=1\left(M\right)\)

nAl=\(\dfrac{5,4}{27}\)=0,2 mol

2Al+3H₂SO₄→Al₂(SO₄)₃+3H₂

0,2-----0,3---------0,1-----------0,3

=>VH2=0,3.22,4=6,72l

=>CMH2SO4=\(\dfrac{0,3}{0,1}\)=3M

=>CM Al2(SO4)3=\(\dfrac{0,1}{0,1}\)=1M