\(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)

PTHH:

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

0,2                      0,2          0,3 

\(V_{H_2}=n.22,4=6,72\left(l\right)\)

\(m_{AlCl_3}=n.M=0,2.133,5=26,7\left(g\right)\)

a) \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

b) \(n_{Al}=\dfrac{m}{M}=\dfrac{5,4}{27}=0,2\left(mol\right)\) ;    \(n_{HCl}=\dfrac{m}{M}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

 \(2Al\)    \(+\)   \(6HCl\)    →    \(2AlCl_3\)  \(+\)  \(3H_2\)

Tỉ lệ:   \(\dfrac{0,2}{2}>\dfrac{0,5}{6}\)                                          ⇒  Al dư, tính theo HCl

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

           \(0,5\)    →   \(\dfrac{1}{6}\)    →   \(0,25\)       ( mol )

\(V_{H_2}=n.22,4=0,25.22,4=5,6\left(l\right)\)

c) \(m_{AlCl_3}=n.M=\dfrac{1}{6}.\left(27+35,5.3\right)=22,25\left(g\right)\)

1)

a) Fe + 2HCl --> FeCl₂ + H₂

b) \(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)

PTHH: Fe + 2HCl --> FeCl₂ + H₂

           0,15->0,3--->0,15-->0,15

=> V_H2 = 0,15.22,4 = 3,36 (l)

c) m_{dd sau pư} = 8,4 + 250 - 0,15.2 = 258,1 (g)

=> \(C\%_{FeCl_2}=\dfrac{0,15.127}{258,1}.100\%=7,38\%\)

2)

a) Zn + 2HCl --> ZnCl₂ + H₂

b) \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

            0,2-->0,4---->0,2--->0,2

=> V_H2 = 0,2.22,4 = 4,48 (l)

m_ZnCl2 = 0,2.136 = 27,2 (g)

c) \(C_{M\left(dd.HCl\right)}=\dfrac{0,4}{0,2}=2M\)

d) 

PTHH: A + 2HCl --> ACl₂ + H₂

           0,2<--0,4

=> \(M_A=\dfrac{4,8}{0,2}=24\left(g/mol\right)\)

=> A là Mg(Magie)

\(n_{Fe}=\dfrac{2.8}{56}=0.05\left(mol\right)\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(0.05................................0.05\)

\(V_{H_2}=0.05\cdot22.4=1.12\left(l\right)\)

\(n_{CuO}=\dfrac{6}{80}=0.075\left(mol\right)\)

\(CuO+H_2\underrightarrow{^{^{t^0}}}Cu+H_2O\)

\(1............1\)

\(0.075......0.05\)

Chất khử : H₂ . Chất OXH : CuO 

\(LTL:\dfrac{0.075}{1}>\dfrac{0.05}{1}\Rightarrow CuOdư\)

\(m_{CuO\left(dư\right)}=\left(0.075-0.05\right)\cdot64=1.6\left(g\right)\)

a) n_Al = 43,2/27 = 1,6 mol

2Al + 6HCl → 2AlCl3 + 3H2

1,6                                 \(\dfrac{1,6\times3}{2}=2,4\)

→ n_H2 = 2,4 mol → V_H2 = 2,4 x 22, 4 = 53,76 lít

b) nCuO = 64/80 = 0,8 mol

nH2 = 2,4 mol

→ H2 dư, phương trình tính theo số mol của CuO

CuO + H2 → Cu + H2O

0,8        0,8       0,8    0,8

Chất rắn sau phản ứng có Cu

mCu = 0,8 x 64 = 51,2 gam

a)  \(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\)

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

           0,4--------------------->0,4

=> V_H2 = 0,4.22,4 = 8,96 (l)

b) 

\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)        

PTHH: Fe₂O₃ + 3H₂ --t^o--> 2Fe + 3H₂O

Xét tỉ lệ: \(\dfrac{0,1}{1}< \dfrac{0,4}{3}\) => Fe₂O₃ hết, H₂ dư

PTHH: Fe₂O₃ + 3H₂ --t^o--> 2Fe + 3H₂O

                0,1---------------->0,2

=> m_Fe = 0,2.56 = 11,2 (g)

a, nZn = 26/65 = 0,4 (mol)

PTHH: Zn + 2HCl -> ZnCl2 + H2

nZn = nH2 = 0,4 (mol)

VH2 = 0,4 . 22,4 = 8,96 (l)

b, nFe2O3 = 16/160 = 0,1 (mol)

PTHH: Fe2O3 + 3H2 -> (t°) 2Fe + 3H2O

LTL: 0,1 < 0,4/3 => H2 dư

nFe = 0,1 . 3 = 0,3 (mol)

mFe = 0,3 . 56 = 16,8 (g)

2Al  +  6HCl   →  2AlCl₃  +  3H₂

nAl = \(\dfrac{3,375}{27}\)= 0,125 mol

a) Theo tỉ lệ phản ứng => nH₂ = \(\dfrac{3}{2}\)nAl = 0,1875 mol

<=> V H₂ = 0,1875.22,4 = 4,2 lít

b) nAlCl₃ = nAl = 0,125 mol

=> mAlCl₃ = 0,125 . 133,5 = 16,6875 gam

\(a)n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ 2Al+6HCl\xrightarrow[]{}2AlCl_3+3H_2\\ n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}\cdot0,4=0,6\left(mol\right)\\ V_{H_2}=0,6.22,4=13,44\left(l\right)\\ b)n_{HCl}=3n_{Al}=3.0,4=1,2\left(mol\right)\\ m_{HCl}=1,2.36,5=43,8\left(g\right)\\ m_{dd_{HCl}}=\dfrac{43,8}{10,95\%}\cdot100\%=400\left(g\right)\\ c)n_{AlCl_3}=n_{Al}=0,4mol\\ m_{AlCl_3}=0,4.133,5=53,4\left(g\right)\\ m_{H_2}=0,6.2=1,2\left(g\right)\\ m_{dd_{AlCl_3}}=10,8+400-1,2=409,6\left(g\right)\\ C_{\%AlCl_3}=\dfrac{53,4}{409,6}\cdot100\%\approx13\%\)

n_Al = 5.4 / 27 = 0.2 (mol)

2Al + 6HCl => 2AlCl₃ + 3H₂

0.2......0.6............0.2.......0.3

a) V_H2 = 0.3 * 22.4 = 6.72 (l) 

b) m_AlCl3 = 0.2 * 133.5 = 26.7 (g) 

c) VddHCl = 0.6 / 1.5 = 0.4 (l) 

d) C_MAlCl3 = 0.2 / 0.4 = 0.5 (M) 

PTHH: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\uparrow\)

Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,6\left(mol\right)\\n_{AlCl_3}=0,2\left(mol\right)\\n_{H_2}=0,3\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\m_{AlCl_3}=0,2\cdot133,5=26,7\left(g\right)\\V_{HCl}=\dfrac{0,6}{1,5}=0,4\left(l\right)=400\left(ml\right)\\C_{M_{AlCl_3}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\end{matrix}\right.\)