\(a)\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ 2C_2H_2 + 5O_2 \xrightarrow{t^o} 4CO_2 + 2H_2O\\ CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O\\ C_2H_2 + 2Br_2 \to C_2H_2Br_4\\ b) n_{Br_2} = \dfrac{8}{160}=0,05(mol)\\ \Rightarrow n_{C_2H_2}= \dfrac{1}{2}n_{Br_2}= 0,025(mol)\\ n_{CO_2} = n_{CH_4} + 2n_{C_2H_2} = n_{CaCO_3} = \dfrac{50}{100} = 0,5(mol)\\ \Rightarrow n_{CH_4} = 0,5 - 0,025.2 = 0,45(mol)\\ \Rightarrow m = 0,45.16 + 0,05.26 = 8,5(gam)\)

\(\%m_{CH_4} = \dfrac{0,45.16}{8,5}.100\% = 84,7\%\\ \%m_{C_2H_2} = 100\% - 84,7\% = 15,3\%\)

Sửa : 29,25 \(\to\) 29,55

\(C_2H_4 + Br_2 \to C_2H_4Br_2\\ n_{C_2H_4} = n_{Br_2} = \dfrac{8}{160} = 0,05(mol)\\ \Rightarrow m_{C_2H_4} = 0,05.28 = 1,4(gam)\\ CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_4 +3O_2 \xrightarrow{t^o} 2CO_2 + 2H_2O\\ CO_2 + Ba(OH)_2 \to BaCO_3 + H_2O\\ n_{CO_2} = n_{CH_4} + 2n_{C_2H_4} = n_{CH_4} + 0,05.2 = n_{BaCO_3} = \dfrac{29,55}{197}=0,15(mol) \\ \Rightarrow n_{CH_4} = 0,05(mol)\\ \Rightarrow m_{CH_4} = 0,05.16 = 0,8(gam)\)

Đầu tiên, không có nước Br chỉ có nước Br2 em nhé!

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nBr2= 8/160=0,05(mol)

PTHH: C2H4 + Br2 -> C2H4Br2

nC2H4=nBr2=0,05(mol) => mC2H4=0,05.28=1,4(g)

- Khí bay ra là khí CH4.

CH4 + 2 O2 -to-> CO2 + 2 H2O

CO2 + Ba(OH)2 -> BaCO3 + H2O

nBaCO3=29,25/197= 117/ 788 (mol ) (Số xấu quá em ơi)

=> nCH4=nCO2=nBaCO3= 117/788(mol)

=> mCH4=16. 117/788= 468/197(g)

\(n_{hh}=\dfrac{11,2}{22,4}=0,5mol\)

Gọi \(\left\{{}\begin{matrix}n_{CH_4}=x\\n_{C_2H_4}=y\end{matrix}\right.\)

\(CH_4+2O_2\rightarrow\left(t^o\right)CO_2+2H_2O\)

  x                              x                     ( mol )

\(C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\)

   y                              2y                   ( mol )

\(n_{CaCO_3}=\dfrac{80}{100}=0,8mol\)

\(Ca\left(OH\right)_2+CO_2\rightarrow\left(t^o\right)CaCO_3+H_2O\)

                     0,8                0,8                      ( mol )

Ta có:

\(\left\{{}\begin{matrix}x+y=0,5\\x+2y=0,8\end{matrix}\right.\) \(\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,3\end{matrix}\right.\)

\(\%V_{CH_4}=\dfrac{0,2}{0,5}.100=40\%\)

\(\%V_{C_2H_4}=100\%-40\%=60\%\)

\(m_{tăng}=m_{Ca\left(OH\right)_2}+m_{CaCO_3}=0,8.\left(74+100\right)=139,2g\)

\(n_{hh}=6,72:22,4=0,3mol\\ C_2H_2+2Br_2->C_2H_2Br_4\\ C_2H_4+Br_2->C_2H_2Br_2\\ n_{Br_2}=0,4mol\\ n_{C_2H_2}=a;n_{C_2H_4}=b\\ a+b=0,3\\ 2a+b=0,4\\ a=0,2;b=0,1\\ \%V_{C_2H_2}=\dfrac{0,2}{0,3}.100\%=66,67\%\\ \%V_{C_2H_4}=33,33\%\)

1/2 hỗn hợp có 0,1 mol C2H2 và 0,05mol C2H4

\(BT.C:n_{CO_2}=2n_{C_2H_2}+2n_{C_2H_4}=0,3mol\\ n_{CaCO_3}=n_{CO_2}=0,3\\ m_{KT}=0,3.100=30g\)

a, \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

\(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)

Theo PT: \(n_{C_2H_2}=\dfrac{1}{2}n_{Br_2}=0,05\left(mol\right)\)

\(\Rightarrow V_{C_2H_2}=0,05.22,4=1,12\left(l\right)\)

\(\Rightarrow V_{CH_4}=3,36-1,12=2,24\left(l\right)\)

b, \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)

\(n_{CH_4}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{5}{2}n_{C_2H_2}=0,325\left(mol\right)\)

\(\Rightarrow V_{O_2}=0,325.22,4=7,28\left(l\right)\Rightarrow V_{kk}=5V_{O_2}=36,4\left(l\right)\)

Theo PT: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=0,2\left(mol\right)\)

\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)

\(\Rightarrow n_{CaCO_3}=n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CaCO_3}=0,2.100=20\left(g\right)\)

PTHH: Fe + 2HCl --> FeCl₂ + H₂

            FeS + 2HCl --> FeCl₂ + H₂S

=> \(n_{Fe}+n_{FeS}=n_{H_2}+n_{H_2S}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

Và 56.n_Fe + 88.n_FeS = 18,8

=> \(\left\{{}\begin{matrix}n_{Fe}=0,1\left(mol\right)\\n_{FeS}=0,15\left(mol\right)\end{matrix}\right.\)

Bảo toàn S: n_CaSO3 = 0,15 (mol)

=> m = 0,15.120 = 18 (g)

=> B

B

B

a) C3H6 +Br2 --> C3H6Br2 (1)

nBr2=0,17 (mol) => nC3H6=0,17(mol)

=> mC3H6=7,14(g) => mC2H6=3,9(g)

=> nC2H6=0,13(mol)

=> %V_C3H6 =56,67(%)

%V_C2H6 =43,33 (%)

b) C2H6 --> 2CO2

0,13 --> 0,26

C3H6 --> 3CO2

0,17 --> 0,51

=> \(\Sigma\)nCO2=0,77(mol)

CO2 --> CaCO3

0,77 --> 0,77

=> mCaCO3=77(g)