\(a,2KMnO_4+16HCl_{đặc}\rightarrow\left(t^o\right)2KCl+2MnCl_2+5Cl_2+8H_2O\\ 2Fe+3Cl_2\rightarrow\left(t^o\right)2FeCl_3\\ Ta.có:n_{FeCl_3}=\dfrac{39}{162,5}=0,24\left(mol\right)\\ n_{Fe}=n_{FeCl_3}=0,24\left(mol\right)\\ n_{Cl_2}=\dfrac{3}{2}.0,24=0,36\left(mol\right)\\ n_{K_2MnO_4}=\dfrac{2}{5}.0,36=0,144\left(mol\right)\\ n_{HCl}=\dfrac{16}{5}.0.36=1,152\left(mol\right)\\ \Rightarrow a=m_{KMnO_4}=0,144.158=22,752\left(g\right)\\ b=C_{MddHCl}=\dfrac{1,152}{0,1}=11,52\left(M\right)\\ x=m_{Fe}=0,24.56=13,44\left(g\right)\\ V=V_{Cl_2\left(đktc\right)}=0,36.22,4=8,064\left(l\right) \)

\(b,n_{KCl}=n_{MnCl_2}=\dfrac{2}{5}.0,36=0,144\left(mol\right)\\ KCl+AgNO_3\rightarrow AgCl\downarrow\left(trắng\right)+KNO_3\\ MnCl_2+2AgNO_3\rightarrow2AgCl\downarrow\left(trắng\right)+Mn\left(NO_3\right)_2\\ n_{AgNO_3}=n_{AgCl}=n_{KCl}+2.n_{MnCl_2}=0,144+2.0,144=0,432\left(mol\right)\\ \Rightarrow m_{AgCl\downarrow\left(trắng\right)}=143,5.0,432=61,992\left(g\right)\\ m_{AgNO_3}=0,432.170=73,44\left(g\right)\\ \Rightarrow m_{ddAgNO_3}=\dfrac{73,44.100}{5}=1468,8\left(g\right)\)

\(n_{Zn}=\dfrac{13}{65}=0,2mol\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

0,2      0,4          0,2         0,2

\(V_{H_2}=0,2\cdot22,4=4,48l\)

\(m_{HCl}=0,4\cdot36,5=14,6g\)

c)Cho dẫn qua copper (ll) oxit:

\(CuO+H_2\rightarrow Cu+H_2O\)

0,2       0,2      0,2       0,2

\(m_{Cu}=0,2\cdot64=12,8g\)

\(n_{Zn}=\dfrac{m}{M}=\dfrac{3,25}{65}=0,05\left(mol\right)\) 

\(PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\) 

                1        2               1           1

             0,05      0,1          0,05       0,05

a) \(V_{H_2}=n.24,79=0,05.24,79=1,2395\left(l\right)\) 

\(m_{ZnCl_2}=n.M=0,05.\left(65+35,5.2\right)=6,8\left(g\right)\) 

b) \(PTHH:CuO+H_2\underrightarrow{t^o}Cu+H_2O\) 

Ta cos tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\Rightarrow\) CuO dư.

Theo ptr, ta có: \(n_{Cu}=n_{H_2}=0,05mol\\ \Rightarrow m_{Cu}=n.M=0,05.64=3,2\left(g\right).\)

a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

Ta có: \(n_{Zn}=\dfrac{3,25}{65}=0,05\left(mol\right)\)

THeo PT: \(n_{ZnCl_2}=n_{H_2}=n_{Zn}=0,05\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,05.24,79=1,2395\left(l\right)\)

\(m_{ZnCl_2}=0,05.136=6,8\left(g\right)\)

b, Ta có: \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)

PT: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)

Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\), ta được CuO dư.

Theo PT: \(n_{Cu}=n_{H_2}=0,05\left(mol\right)\Rightarrow m_{Cu}=0,05.64=3,2\left(g\right)\)

\(a.Fe+2HCl\rightarrow FeCl_2+H_2\\b.n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\\ n_{H_2}=n_{Fe}=0,1\left(mol\right)\\ \Rightarrow V_{H_2}=0,1.22,4=2,24\left(l\right)\\ c.n_{FeCl_2}=n_{Fe}=0,1\left(mol\right)\\ m_{FeCl_2}=0,1.127=12,7\left(g\right) \)

a, \(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

PTHH: 2Al + 6HCl → 2AlCl₃ + 3H₂

Mol:      x                                   1,5x

PTHH: Fe + 2HCl → FeCl₂ + H₂

Mol:     y                                   y

b, Ta có hpt: \(\left\{{}\begin{matrix}27x+56y=11\\1,5x+y=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)

\(\Rightarrow\%m_{Al}=\dfrac{0,2.27.100\%}{11}=49,09\%\Rightarrow\%m_{Fe}=100\%-49,09\%=50,91\%\)

c, \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)

Ta có: \(\dfrac{0,2}{1}< \dfrac{0,4}{1}\) ⇒ CuO hết, H₂ dư

PTHH: CuO + H₂ → Cu + H₂O

Mol:      0,2                0,2

\(m_{Cu}=0,2.64=12,8\left(g\right)\)

Gọi \(m_{Al}=a\left(g\right)\left(0< a< 11\right)\)

\(\rightarrow m_{Fe}=11-a\left(g\right)\)

\(\rightarrow\left\{{}\begin{matrix}n_{Al}=\dfrac{a}{27}\left(mol\right)\\n_{Fe}=\dfrac{11-a}{56}\left(mol\right)\end{matrix}\right.\)

PTHH:

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(\dfrac{a}{27}\)                                       \(\dfrac{a}{18}\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(\dfrac{11-a}{56}\)                             \(\dfrac{11-a}{56}\)

\(\rightarrow pt:\dfrac{a}{18}+\dfrac{11-a}{56}=0,4\\ \Leftrightarrow m_{Al}=a=5,4\left(g\right)\left(TM\right)\)

\(\rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{5,4}{11}=49,1\%\\\%m_{Fe}=100\%-49,1\%=50,9\%\end{matrix}\right.\)

\(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)

PTHH: \(CuO+H_2\underrightarrow{t^o}Cu+H_2O\)

LTL: \(0,2< 0,4\rightarrow\) H₂ dư

\(n_{Cu}=n_{CuO}=0,2\left(mol\right)\rightarrow m_{CuO}=0,2.64=12,8\left(g\right)\)

a. \(n_{H_2}=\dfrac{8.96}{22,4}=0,4\left(mol\right)\)

PTHH : 2Al + 6HCl -> 2AlCl₃ + 3H₂

              \(\dfrac{0.8}{3}\)                             0,4

             Fe + 2HCl -> FeCl₂ + H₂

\(m_{Al}=\dfrac{0,8.27}{3}=7,2\left(g\right)\)

\(m_{Fe}=11-7,2=3,8\left(g\right)\)

b. \(\%m_{Al}=\dfrac{7.2}{11}.100=65,5\%\)

\(\%m_{Fe}=100\%-65,5\%=34,5\%\)

c. \(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)

PTHH : H₂ + CuO ----t^o----> Cu + H₂O

                      0,2                  0,2

\(m_{Cu}=0,2.64=12,8\left(g\right)\)

nZn = 32.5/65 = 0.5 (mol) 

Zn  + 2HCl => ZnCl2 + H2 

0.5.......1.............0.5........0.5 

VH2 = 0.5 * 22.4 = 11.2 (l) 

mZnCl2 = 0.5  * 136 = 68 (g) 

mHCl = 36.5 (g) 

mdd HCl = 36.5 * 100 / 3.65 = 1000 (g) 

a, \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)

PTHH: Fe + 2HCl ---t^o---> FeCl₂ + H₂

Mol:    0,3       0,6                            0,3

\(V_{H_2}=0,3.22,4=6,72\left(l\right)\)

\(m_{HCl}=0,6.36,5=21,9\left(g\right)\)

b, \(n_{CuO}=\dfrac{32}{80}=0,4\left(mol\right)\)

PTHH: H₂ + CuO ---t^o---> Cu + H₂O

Mol:     0,3                         0,3

Ta có: \(\dfrac{0,3}{1}< \dfrac{0,4}{1}\) ⇒ H₂ pứ hết, CuO dư

\(m_{Cu}=0,3.64=19,2\left(g\right)\)

\(a.HCl+NaOH\rightarrow NaCl+H_2O\)

PỨ trung hoà 

\(b,n_{NaOH}=0,1.1=0,1mol\\ n_{NaCl}=n_{NaOH}=n_{HCl}0,1mol\\ m=m_{HCl}=0,1.36,5=3,65g\\ c,m_{NaCl}=0,1.58,5=5,85g\\ d,n_{HCl}=\dfrac{73.10}{100.36,5}=0,2mol\\ \Rightarrow\dfrac{0,1}{1}< \dfrac{0,2}{1}\Rightarrow HCl.dư\\ n_{HCl,pứ}=n_{NaOH}=0,1mol\\ m_{HCl,dư}=\left(0,2-0,1\right).36,5=3,65g\)