a) \(n_{CH_3COOH}=\dfrac{120.20\%}{60}=0,4\left(mol\right)\)

\(n_{Na_2CO_3}=\dfrac{53.30\%}{106}=0,15\left(mol\right)\)

PTHH: Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

Xét tỉ lệ: \(\dfrac{0,15}{1}< \dfrac{0,4}{2}\) => Na₂CO₃ hết, CH₃COOH dư

PTHH: Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

                0,15-------->0,3-------------->0,3------->0,15

=> \(m_{CH_3COONa}=0,3.82=24,6\left(g\right)\)

b) m_{dd sau pư} = 120 + 53 - 0,15.44 = 166,4 (g)

=> \(C\%=\dfrac{24,6}{166,4}.100\%=14,78\text{%}\)

PTHH: \(Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{Ba\left(OH\right)_2}=0,05\cdot0,5=0,025\left(mol\right)\\n_{HCl}=0,15\cdot0,1=0,015\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,025}{1}>\dfrac{0,015}{2}\) \(\Rightarrow\) Ba(OH)₂ còn dư, dd sau p/ứ có tính kiềm

\(\Rightarrow\left\{{}\begin{matrix}n_{BaCl_2}=0,0075\left(mol\right)\\n_{Ba\left(OH\right)_2\left(dư\right)}=0,0175\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{BaCl_2}}=\dfrac{0,0075}{0,05+0,15}=0,0375\left(M\right)\\C_{M_{Ba\left(OH\right)_2}}=\dfrac{0,0175}{0,2}=0,0875\left(M\right)\end{matrix}\right.\)

a)m_H2SO4=\(\dfrac{200.7,3\text{%}}{100\%}\)=14,6g

n_HCl=\(\dfrac{14,6}{36,5}\)=0,4(mol)

PTHH:

NaOH+ HCl→ NaCl+ H₂O

1            1            1         1

0,4        0,4         0,4     (mol)

⇒m_NaOH=0,4.40=16(g)

Nồng độ % của dd NaOH cần dùng là:

C_%NaOH=\(\dfrac{16}{200}\)   .100%=8%

b)Ta có:m_{dd spứ}=m_{dd trc pứ}=400g

m_NaCl=0,4.58,5=23,4g

Nồng độ % dd muối tạo thành sau pứ là:

C_%dd NaCl=\(\dfrac{23,4}{400}\)   .100%=5,85%        

Bài 2:

a) PTHH: \(Na_2O+H_2O\rightarrow2NaOH\)

b) Dung dịch A là dung dịch bazơ

Ta có: \(n_{Na_2O}=\dfrac{3,1}{62}=0,05\left(mol\right)\) \(\Rightarrow n_{NaOH}=0,1\left(mol\right)\) \(\Rightarrow C_{M_{NaOH}}=\dfrac{0,1}{1}=0,1\left(M\right)\)

c) Sửa đề: dd H₂SO₄ 9,8%

PTHH: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

Theo PTHH: \(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,05\left(mol\right)\)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,05\cdot98}{9,8\%}=50\left(g\right)\) \(\Rightarrow V_{ddH_2SO_4}=\dfrac{50}{1,14}\approx43,86\left(ml\right)\)

Bài 1:

PTHH: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot19,6\%}{98}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Axit còn dư

\(\Rightarrow n_{CuSO_4}=0,2\left(mol\right)=n_{H_2SO_4\left(dư\right)}\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{CuSO_4}=\dfrac{0,2\cdot160}{200+16}\cdot100\%\approx14,81\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,2\cdot98}{200+16}\cdot100\%\approx9,07\%\end{matrix}\right.\)

\(n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\)

a) Pt : \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O|\)  

             1            1                1            1

           0,2          0,2             0,2

b) \(n_{H2SO4}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

⇒ \(m_{H2SO4}=0,2.98=19,6\left(g\right)\)

\(C_{ddH2SO4}=\dfrac{19,6.100}{200}=9,8\)⁰/₀

c) \(n_{CuSO4}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

⇒ \(m_{CuSO4}=0,2.160=32\left(g\right)\)

\(m_{ddspu}=16+200=216\left(g\right)\)

\(C_{CuSO4}=\dfrac{32.100}{216}=14,81\)⁰/₀

PTHH: \(Fe_2O_3+3H_2SO_4\rightarrow Fe_2\left(SO_4\right)_3+3H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot9,8\%}{98}=0,2\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,2}{3}\) \(\Rightarrow\) Fe₂O₃ còn dư, tính theo axit 

\(\Rightarrow\left\{{}\begin{matrix}n_{Fe_2\left(SO_4\right)_3}=0,1\left(mol\right)\\n_{Fe_2O_3\left(dư\right)}=\dfrac{1}{30}\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{Fe_2\left(SO_4\right)_3}=0,1\cdot400=40\left(g\right)\\m_{Fe_2O_3\left(dư\right)}=\dfrac{1}{30}\cdot160\approx5,3\left(g\right)\end{matrix}\right.\)

\(\Rightarrow C\%_{Fe_2\left(SO_4\right)_3}=\dfrac{40}{16+200-5,3}\cdot100\%\approx18,98\%\)

rất mog nhận đc sự giúp đỡ từ mn

Bài 9:

\(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\\ n_{HCl}=\dfrac{14,6\%.100}{36,5}=0,4\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ Vì:\dfrac{0,1}{1}< \dfrac{0,4}{2}\Rightarrow HCldư\\ n_{HCl\left(dư\right)}=0,4-2.0,1=0,2\left(mol\right)\\ m_{HCl\left(dư\right)}=0,2.36,5=7,3\left(g\right)\)

Bài 10:

\(n_{CaO}=\dfrac{5,6}{56}=0,1\left(mol\right)\\ PTHH:CaO+H_2O\rightarrow Ca\left(OH\right)_2\\ n_{Ca\left(OH\right)_2}=n_{CaO}=0,1\left(mol\right)\\ m_{Ca\left(OH\right)_2}=0,1.74=7,4\left(g\right)\\ m_{ddCa\left(OH\right)_2}=m_{CaO}+m_{H_2O}=5,6+500.1=505,6\left(g\right)\\ a,C\%_{ddCa\left(OH\right)_2}=\dfrac{7,4}{505,6}.100\approx1,464\%\\ b,V_{ddCa\left(OH\right)_2}=V_{H_2O}=500\left(ml\right)=0,5\left(l\right)\\ C_{MddCa\left(OH\right)_2}=\dfrac{0,1}{0,5}=0,2\left(M\right)\)