a) \(n_{Al}=\dfrac{12,15}{27}=0,45\left(mol\right)\)

\(n_{O_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH: 4Al + 3O₂ --t^o--> 2Al₂O₃

Xét tỉ lệ: \(\dfrac{0,45}{4}>\dfrac{0,3}{3}\)=> Al dư, O₂ hết

PTHH: 4Al + 3O₂ --t^o--> 2Al₂O₃

            0,4<--0,3-------->0,2

=> \(m_{Al\left(dư\right)}=\left(0,45-0,4\right).27=1,35\left(g\right)\)

b) \(m_{Al_2O_3}=0,2.102=20,4\left(g\right)\)

a)

\(n_{Al} = \dfrac{12,15}{27} = 0,45(mol)\\ n_{O_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ 4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ \dfrac{n_{Al}}{4} = 0,1125 < \dfrac{n_{O_2}}{3} = 0,1\)

Do đó, Al dư.

\(n_{Al\ pư} = \dfrac{4}{3}n_{O_2} = 0,4(mol)\\ m_{Al\ dư} = (0,45-0,4).27 =1,35(gam)\)

b) Nhôm oxit được tạo thành.

\(n_{Al_2O_3} = \dfrac{2}{3}n_{O_2} = 0,2(mol)\\ \Rightarrow m_{Al_2O_3} = 0,2.102 = 20,4(gam)\)

\(n_{Al}=\dfrac{m}{M}=0,45\left(mol\right)\)

\(n_{O_2}=\dfrac{V}{22,4}=0,3\left(mol\right)\)

a, \(PTHH:4Al+3O_2\rightarrow2Al_2O_3\)

=> Sau phản ứng O2 hết, Al dư ( dư 0,05 mol )

=> \(m_{Aldu}=n.M=1,35\left(g\right)\)

b, Chất được tạo thành là Al₂O₃ .

Theo PTHH : \(n_{Al_2O_3}=0,2\left(mol\right)\)

\(\Rightarrow m_{Al_2O_3}=n.M=20,4\left(g\right)\)

Vậy ...

nP = 6.2/31 = 0.2 (mol) 

nO2 = 6.72/22.4 = 0.3 (mol) 

4P + 5O2 -to-> 2P2O5 

0.2___0.25_____0.1

mO2 dư = ( 0.3 - 0.25) * 32 = 1.6(g) 

mP2O5 = 0.1*142 = 14.2 (g) 

Ta có: \(n_P=\dfrac{6.2}{31}=0.29mol\)

\(n_{O_2}=\dfrac{6.72}{22.4}=0.3mol\)

PTHH:

\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)

ta có:

\(\left\{{}\begin{matrix}\dfrac{n_{P\left(bra\right)}}{nP_{\left(pthh\right)}}=\dfrac{0.2}{4}=0.05\\\dfrac{n_{O_2\left(bra\right)}}{n_{O_2}\left(pthh\right)}=\dfrac{0.3}{5}=0.06\end{matrix}\right.\)

=> \(O_2\) dư 

\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)

4   ----------->2                

0.2---------->0.1=n_P2O5

=>\(m_{P_2O_5}=142.0.1=14.2\left(g\right)\)

\(a)\\ n_{O_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ 4P + 5O_2 \xrightarrow{t^o} 2P_2O_5\\ \dfrac{n_P}{4} = 0,05 < \dfrac{n_{O_2}}{5} = 0,06\)

Do đó, Oxi dư.

\(n_{O_2\ pư} = \dfrac{5}{4}n_P = 0,25(mol)\\ \Rightarrow m_{O_2\ dư} = (0,3 - 0,25).32 = 1,6(gam)\\ b)\\ n_{P_2O_5} = \dfrac{n_P}{2} = 0,1(mol)\\ \Rightarrow m_{P_2O_5} = 0,1.142 = 14,2(gam)\)

nAl=\(\dfrac{5,4}{27}\)=0,2mol

nO2=\(\dfrac{4,48}{22,4}\)=0,2mol

PTHH:

4Al + 3O2--to->2Al2O3

Tỉ lệ \(\dfrac{0,2}{4}\) <\(\dfrac{0,2}{3}\)->Al hết O2 dưtính theo Al

=>m O2=\(\dfrac{1}{60}\).32=\(\dfrac{8}{15}\)g

2KMnO4-to>K2MnO4+MnO2+O2

0,4--------------------------------------0,2

m KMnO4=0,4.158=63,2g

.

\(n_{Fe}=\dfrac{12.6}{56}=0.225\left(mol\right)\)

\(n_{O_2}=\dfrac{4.2}{22.4}=0.1875\left(mol\right)\)

\(3Fe+2O_2\underrightarrow{^{^{t^0}}}Fe_3O_4\)

\(3.........2\)

\(0.225......0.1875\)

Lập tỉ lệ : \(\dfrac{0.225}{3}< \dfrac{0.1875}{2}\Rightarrow O_2dư\)

\(m_{O_2\left(dư\right)}=\left(0.1875-0.225\cdot\dfrac{2}{3}\right)\cdot32=1.2\left(g\right)\)

\(m_{Fe_3O_4}=\dfrac{0.225}{3}\cdot232=17.4\left(g\right)\)

Bài 1:

\(a,2Cu+O_2\underrightarrow{t^o}2CuO\)

b, \(n_{O_2}=\dfrac{1,12}{32}=0,035mol\)

\(n_{Cu}=\dfrac{6,4}{64}=0,1mol\)

\(\dfrac{0,1}{2}>\dfrac{0,035}{1}\) => Cu dư, O₂ đủ

\(n_{Cu}\left(dư\right)=0,1-0,07=0,039\left(mol\right)\)

c, \(m_{CuO}=0,07.80=5,6g\)

Bài 2:

\(n_{Al}=\dfrac{13,5}{27}=0,5mol\)

\(n_{O_2}=\dfrac{6,67}{32}=0,21\left(mol\right)\)

\(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)

\(\dfrac{0,5}{4}>\dfrac{0,21}{3}\) => Al dư, O₂ đủ

\(n_{Al_2O_3}=\dfrac{2}{3}.0,21=0,14\left(mol\right)\)

\(m_{Al_2O_3}=0,14.102=14,28g\)

nP=\(\dfrac{62}{31}\)=0,2(mol)

nO2=\(\dfrac{7,84}{22,4}\)=0,35(mol)

PTHH:4P+5O2to→2P2O5

tpứ:    0,2     0,35     

pứ:     0,2     0,25     0,1

spứ:     0     0,1         0,1

a)chất còn dư là oxi

mO2dư=0,1.32=3,2(g)

b)mP2O5=n.M=0,1.142=14,2(g)

\(a.n_P=0,2\left(mol\right);n_{O_2}=0,35\left(mol\right)\\ 4P+5O_2-^{t^o}\rightarrow2P_2O_5\\ LTL:\dfrac{0,2}{4}< \dfrac{0,35}{5}\\ \Rightarrow SauphảnứngO_2dư\\ n_{O_2\left(pứ\right)}=\dfrac{5}{4}n_P=0,25\left(mol\right)\\ \Rightarrow m_{P\left(dư\right)}=\left(0,35-0,25\right).32=3,2\left(g\right)\\ b.n_{P_2O_5}=\dfrac{1}{2}n_P=0,1\left(mol\right)\\ \Rightarrow m_{P_2O_5}=0,1.142=14,2\left(g\right)\)

a) n\(_P\) = \(\dfrac{6,2}{31}\) = 0,2(mol); n\(_{O_2}\) = \(\dfrac{7,84}{22,4}\) = 0,35(mol).

Theo phương trình hóa học:

\(4P+5O_2\) \(\underrightarrow{t^o}\) \(2P_2O_5\)

4        5          2 (mol)

0,2 \(\rightarrow\)0,25 \(\rightarrow\) 0,1(mol)

Tỉ lệ số mol: \(\dfrac{0,2}{4}< \dfrac{0,35}{5}\) \(\Rightarrow\) \(O_2\) phản ứng dư, P phản ứng hết.

\(n_{O_2}\)dư = 0,35 - \(\dfrac{0,2.5}{4}\) = 0,1(mol) \(\Rightarrow\) \(m_{O_2}\)dư = 0,1.32 = 3,2g

b) \(n_{P_2O_5}\) = 0,1.142 = 14,2g