Giả sử hỗn hợp chỉ chứa : Mg

\(n_{Mg}=\dfrac{6.5}{24}=0.27\left(mol\right)\)

\(n_{HCl}=0.3\cdot2=0.6\left(mol\right)\)

\(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(0.27.........0.54\)

\(n_{HCl}=0.54< 0.6\)

=> A tan hết .

\(2.\)

\(n_{Fe}=n_{Mg}=a\left(mol\right),n_{Zn}=b\left(mol\right)\)

\(n_{hh}=2a+b=0.15\left(mol\right)\)

\(m_{hh}=80a+65b=6.5\left(g\right)\)

\(\Rightarrow a=0.065,b=0.02\)

\(\%Fe=\dfrac{0.065\cdot56}{6.5}\cdot100\%=56\%\)

\(\%Mg=\dfrac{0.065\cdot24}{6.5}\cdot100\%=24\%\)

\(\%Zn=20\)

a, Ta có: \(n_{H_2}=\dfrac{17,472}{22,4}=0,78\left(mol\right)\)

\(n_{HCl}=0,5.1=0,5\left(mol\right)\)

\(\Rightarrow2n_{H_2}>n_{HCl}\) → HCl hết, KL dư pư với H₂O.

Gọi: \(\left\{{}\begin{matrix}n_A=5x\left(mol\right)\\n_B=4x\left(mol\right)\end{matrix}\right.\) 

BT e, có: n_A + 2n_B = 2n_H2 ⇒ 5x + 4x.2 = 0,78.2 ⇒ x = 0,12

\(\Rightarrow\left\{{}\begin{matrix}n_A=0,6\left(mol\right)\\n_B=0,48\left(mol\right)\end{matrix}\right.\) 

\(\Rightarrow0,6M_A+0,48M_B=42,6\Rightarrow5M_A+4M_B=355\)

Với M_A = 39 (g/mol) và M_B = 40 (g/mol) thì thỏa mãn.

→ A là K, B là Ca.

\(\Rightarrow\left\{{}\begin{matrix}\%m_K=\dfrac{0,6.39}{42,6}.100\%\approx54,93\%\\\%m_{Ca}\approx45,07\%\end{matrix}\right.\)

b, Dung dịch Y gồm: \(\left\{{}\begin{matrix}K^+\\Ca^{2+}\\Cl^-\\OH^-\end{matrix}\right.\)

BTNT Ca, có: n_Ca²⁺ = n_Ca = 0,48 (mol) 

BTNT H, có: n_OH^- = 2n_H2 - n_HCl = 1,06 (mol)

TH1:

 \(CO_2+2OH^-\rightarrow CO_3^{2-}+H_2O\)

\(Ca^{2+}+CO_3^{2-}\rightarrow CaCO_3\)

Có: n_CO2 = n_CO3^2- = n_Ca²⁺ = 0,48 (mol)

TH2: 

\(CO_2+2OH^-\rightarrow CO_3^{2-}+H_2O\)

0,53____1,06______0,53 (mol)

\(CO_2+CO_3^{2-}+H_2O\rightarrow2HCO_3^-\)

0,05____0,05 (mol)

\(Ca^{2+}+CO_3^{2-}\rightarrow CaCO_3\)

0,48____0,48 (mol)

⇒ n_CO2 = 0,05 + 0,53 = 0,58 (mol)

⇒ 0,48 ≤ n_CO2 ≤ 0,58 thì thu được lượng kết tủa lớn nhất.

⇒ 10,752 (l) ≤ V_CO2 ≤ 12,992 (l)

https://hoc24.vn/cau-hoi/hoa-tan-hoan-toan-426-gam-hon-hop-x-gom-mot-kim-loai-kiem-va-mot-kim-loai-kiem-tho-co-ti-le-mol-tuong-ung-la-54-vao-500-ml-dung-dich-hcl-1m-thu-duoc.4485788491246

Ta có nR = x, nRO = y.

R(x+y)+16y=6,4.

x+y=0,2.

=> 16<R<32.

=> R là magie

=> Đáp án D

a) Gọi \(n_{Mg}=4x\left(mol\right)\Rightarrow n_{Al}=5x\left(mol\right)\)

=> \(24.4x+27.5x=6,93\Leftrightarrow x=0,03mol\)

=> \(n_{Mg}=4.0,03=0,12mol\Rightarrow m_{Mg}=2,88g,mAl=6,93-2,88=4,05g\)

b) pt: 

\(Mg+2HCl\rightarrow MgCl_2+H_2\)

0,12     0,24

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

0,15     0,45

=> nHCl = 0,24+0,45=0,69 mol

=> VHCl = 0,69:4=0,1725 lít

a) \(\left\{{}\begin{matrix}24.n_{Mg}+27.n_{Al}=6,93\\\dfrac{n_{Mg}}{n_{Al}}=\dfrac{4}{5}\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}n_{Mg}=0,12\left(mol\right)\\n_{Al}=0,15\left(mol\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}m_{Mg}=0,12.24=2,88\left(g\right)\\m_{Al}=0,15.27=4,05\left(g\right)\end{matrix}\right.\)

b) 

PTHH: Mg + 2HCl --> MgCl₂ + H₂

            0,12->0,24

            2Al + 6HCl --> 2AlCl₃ + 3H₂

           0,15-->0,45

=> n_HCl(min) = 0,24 + 0,45 =0,69 (mol)

=> \(V_{dd.HCl\left(min\right)}=\dfrac{0,69}{4}=0,1725\left(l\right)\)

=> KL M là Kali (M=39, n=1)

Đáp án D