\(C_{M_{NaOH}}=\dfrac{0.3\cdot1.5+0.4\cdot2.5}{0.3+0.4}=2.07\left(M\right)\)

a, \(NaHCO_3+NaOH\rightarrow Na_2CO_3+H_2O\)

\(HCO_3^-+OH^-\rightarrow CO_3^{2-}+H_2O\)

b, \(\left[Na^+\right]=\dfrac{0,2.1,5+0,12.1,6}{0,2+0,12}=1,5376M\)

\(\left[CO_3^{2-}\right]=\dfrac{0,2.1,5}{0,2+0,12}=0,9375M\)

\(n_{H^+}=0,3\left(mol\right)\)

\(n_{OH^-}=0,192\left(mol\right)\)

\(\Rightarrow n_{H^+dư}=0,108\left(mol\right)\)

\(\Rightarrow\left[H^+\right]=\dfrac{0,108}{0,2+0,12}=0,3375M\)

\(\Rightarrow pH\approx0,47\)

\(V_{\text{dd}}=0,2+0,3=0,5\left(l\right)\\ n_{HCl}=0,2.1+0,3.0,5=0,35\\ C_M=\dfrac{0,35}{0,5}=0,7M\)

200ml = 0,2(l)

=> nHCl (1) = 0,2 .1 = 0,2 (mol)

300ml = 0,3 (l)

=> nHCl(2) = 0,3 . 0,5 = 0,15 (mol)

=> CM (sau khi trộn) = n/V = (0,15+0,2) / (0,2+0,3 ) = 0,35 / 0,5 = 0,7 M

\(n_{OH^-}=n_{NaOH}=0,3.1,5=0,45\left(mol\right)\\ n_{H^+}=n_{HCl}+2n_{H_2SO_4}=0,2x+0,5.0,2.2=0,2x+0,2\left(mol\right)\)

PT ion rút gọn: \(H^++OH^-\rightarrow H_2O\)

                      0,45<---0,45

\(\Rightarrow0,2x+0,2=0,45\Leftrightarrow x=1,25M\)

Ta có: \(V_{dd}=0,3+0,2=0,5\left(l\right)\) và \(\left\{{}\begin{matrix}n_{Na^+}=0,45\left(mol\right)\\n_{Cl^-}=0,2.1,25=0,25\left(mol\right)\\n_{SO_4^{2-}}=0,2.0,5=0,1\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}C_{Na^+}=\dfrac{0,45}{0,5}=0,9M\\C_{Cl^-}=\dfrac{0,25}{0,5}=0,5M\\C_{SO_4^{2-}}=\dfrac{0,1}{0,5}=0,2M\end{matrix}\right.\)

\(n_{NaCl}=0,1.0,2=0,02\left(mol\right)\)

\(m_{Na_2CO_3}=0,1.0,3=0,03\left(mol\right)\)

\(\left\{{}\begin{matrix}n_{Na^+}=0,02+0,03.2=0,08\left(mol\right)\\n_{Cl^-}=0,02\left(mol\right)\\n_{CO_3^{2-}}=0,03\left(mol\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}C_{M\left(Na^+\right)}=\dfrac{0,08}{0,2+0,3}=0,16M\\C_{M\left(Cl^-\right)}=\dfrac{0,02}{0,2+0,3}=0,04M\\C_{M\left(CO_3^{2-}\right)}=\dfrac{0,03}{0,2+0,3}=0,06M\end{matrix}\right.\)

B4:

nNaOH = 0,3 . 1,5 + 0,4 . 2,5 = 1,45 (mol)

VddNaOH = 0,3 + 0,4 = 0,7 (l)

CMddNaOH = 1,45/0,7 = 2,07M

B5:

nHCl (sau khi pha) = 0,5 . 2 = 1 (mol)

Gọi VHCl (0,2) = x (l); VHCl (0,8) = y (l)

x + y = 2 (1)

nHCl (0,2) = 0,2x (mol)

nHCl (0,8) = 0,8y (mol)

=> 0,2x + 0,8y = 1 (2)

(1)(2) => x = y = 1 (l)

\(\sum\)n_HCl=0,2.2+0,3.4=1,6(mol)

C_M dd HCl=\(\dfrac{1,6}{0,5}=3,2M\)

Đáp án C

C_{M HCl}= (0,2+0,3.2)/0,5= 1,6M

a) \(n_{NaOH}=0,2.1=0,2\left(mol\right)\); \(n_{HNO_3}=0,2.0,5=0,1\left(mol\right)\)

\(NaOH+HNO_3\rightarrow NaNO_3+H_2O\)

0,2.............0,1

Lập tỉ lệ : \(\dfrac{0,2}{1}>\dfrac{0,1}{1}\) => Sau phản ứng NaOH dư

Dung dịch D gồm NaNO3 và NaOH dư

\(n_{NaNO_3}=n_{HNO_3}=0,1\left(mol\right)\)

\(n_{NaOH\left(pứ\right)}=n_{HNO_3}=0,1\left(mol\right)\)

\(n_{NaOH\left(dư\right)}=0,2-0,1=0,1\left(mol\right)\)

Ion trong dung dịch D : Na+ , NO3-, OH-

\(\left[Na^+\right]=\dfrac{0,1+0,1}{0,2}=1M\)

\(\left[NO_3^-\right]=\dfrac{0,1}{0,2}=0,5M\)

\(\left[OH^-\right]=\dfrac{0,1}{0,2}=0,5M\)

b)Trong dung dịch D chỉ có NaOH dư phản ứng

 \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)

0,1................0,05

=> \(V_{H_2SO_4}=\dfrac{0,05}{1}=0,05\left(l\right)\)

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