nNa2CO3= 25/106(mol)

PTHH: Na2CO3 + 2 HCl -> 2 NaCl + CO2 + H2O

a) nHCl=25/106 . 2= 25/53 (mol)

=> m=mddHCl={[25/53].36,5]/15%}=114,78(g)

b) nCO2= 25/106 x 22,4= 5,28(l)

c) mNaCl=25/53. 58,5=27,59(g)

mddNaCl=25+114,78- 25/106.44=129,4(g)

=>C%ddNaCl=(27,59/129,4).100=21,32%

nCO2= 0.15 mol

CH3COOH + NaHCO3 --> CH3COONa + CO2 + H2O

0.15_________0.15_________0.15______0.15

VddCH3COOH= 0.15/0.5=0.3 l

mCH3COONa = 12.3g

C%NaHCO3= 12.6/300*100%=4.2%

PTHH: 2CH3COOH+Na2CO3→2CH3COONa+CO2+H2O

Ta có:

n_CO2=3,36/22,4=0,15mol

=> n_CH3COOH=2n_CO2=0,3mol

=> V_CH3COOH=0,3/0,5=0,6l

=> n_CH3COONa=2n_CO2=0,3mol

=> m_CH3COONa=0,3.82=24,6g

n_Na2CO3 = n_CO2 = 0,15mol

=> C%_Na2CO3 = (0,15.106)/300.100%=5,3%

Rượu etylic \(C_2H_5OH\)

Axit axetic \(CH_3COOH\)

\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1mol\)

\(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+H_2O+CO_2\uparrow\)

      0,2                  0,1                 0,2                  0,1         0,1

\(\%m_{CH_3COOH}=\dfrac{0,2\cdot60}{39,6}\cdot100\%=30,3\%\)      

\(\%m_{C_2H_5OH}=100\%-30,3\%=69,7\%\)

a)

\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

PTHH: 2CH₃COOH + Na₂CO₃ --> 2CH₃COONa + CO₂ + H₂O

                 0,2<----------0,1<-------------0,2<-------0,1

=> \(m_{CH_3COOH}=0,2.60=12\left(g\right)\)

\(\%m_{CH_3COOH}=\dfrac{12}{39,6}.100\%=30,3\%\)

\(\%m_{C_2H_5OH}=\dfrac{39,6-12}{39,6}.100\%=69,7\%\)

b) dd sau pư chứa \(\left\{{}\begin{matrix}CH_3COONa:0,2\left(mol\right)\\C_2H_5OH:\dfrac{39,6-12}{46}=0,6\left(mol\right)\end{matrix}\right.\)

\(V_{dd}=\dfrac{0,1}{2}=0,05\left(l\right)\)

=> \(\left\{{}\begin{matrix}C_{M\left(CH_3COONa\right)}=\dfrac{0,2}{0,05}=4M\\C_{M\left(C_2H_5OH\right)}=\dfrac{0,6}{0,05}=12M\end{matrix}\right.\)

a.\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{14,2}{142}=0,1mol\)

\(2CH_3COOH+Mg\rightarrow\left(CH_3COO\right)_2Mg+H_2\)

         0,2                                0,1                    0,1   ( mol )

\(C_{M_{CH_3COOH}}=\dfrac{0,2}{0,25}=0,8M\)

\(V_{H_2}=0,1.22,4=2,24l\)

b.\(NaOH+CH_3COOH\rightarrow CH_3COONa+H_2O\)

      0,2               0,2                                               ( mol )

\(V_{NaOH}=\dfrac{0,2}{0,5}=0,4l\)

\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{14,2}{142}=0,1\left(mol\right)\)

PTHH: 2CH₃COOH + Mg ---> (CH₃COO)₂Mg + H₂

              0,2<---------------------------0,1---------->0,1

=> \(\left\{{}\begin{matrix}C_{M\left(CH_3COOH\right)}=\dfrac{0,2}{0,25}=0,8M\\V_{H_2}=0,1.22,4=2,4\left(l\right)\end{matrix}\right.\)

PTHH: CH₃COOH + NaOH ---> CH₃COONa + H₂O

           0,2------------->0,2

=> \(V_{ddNaOH}=\dfrac{0,2}{0,5}=0,4\left(l\right)\)

a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1,42}{142}=0,01\left(mol\right)\)

PTHH: Mg + 2CH₃COOH --> (CH₃COO)₂Mg + H₂

                           0,02<-----------0,01-------->0,01

=> V_H2 = 0,01.22,4 = 0,224 (l)

\(C_{M\left(CH_3COOH\right)}=\dfrac{0,02}{0,2}=0,1M\)

b) 

PTHH: CH₃COOH + NaOH --> CH₃COONa + H₂O

                  0,02------>0,02

=> \(V_{dd.NaOH}=\dfrac{0,02}{0,2}=0,1\left(l\right)=100\left(ml\right)\)

\(CaCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Ca+CO_2+H_2O\\ a,n_{CH_3COOH}=0,2.1=0,2\left(mol\right)\Rightarrow n_{CO_2}=\dfrac{0,2}{2}=0,1\left(mol\right)\Rightarrow V_{CO_2\left(đktc\right)}=0,1.22,4=2,24\left(l\right)\\ b,CH_3COOH+C_2H_5OH⇌\left(H^+,t^o\right)CH_3COOC_2H_5+H_2O\\ n_{CH_3COOH}=\dfrac{50}{200}.0,2=0,05\left(mol\right)\\ n_{C_2H_5OH}=\dfrac{23}{46}=0,5\left(mol\right)\\ Vì:\dfrac{0,5}{1}>\dfrac{0,05}{1}\Rightarrow Rượu.dư\\ \Rightarrow n_{este\left(LT\right)}=n_{axit}=0,05\left(mol\right)\\ \Rightarrow n_{este\left(TT\right)}=80\%.0,05=0,04\left(mol\right)\\ m_{CH_3COOC_2H_5}=88.0,04=3,52\left(g\right)\)

Gọi M là kí hiệu nguyên tử khối của kim loại hoá trị I. Công thức muối là M 2 CO 3 . Phương trình hoá học của phản ứng :

M 2 CO 3  + 2HCl → 2 MCl 2  + H 2 O + CO 2

(2M + 60)g     22400ml

1,06g      224ml

Theo phương trình hóa học trên ta có:

→ M = 23. Đó là muối  Na 2 CO 3

Đáp án D

Đặt công thức của hai muối là RCO₃: x mol

RCO₃+ 2HCl → RCl₂+ CO₂+ H₂O

x             2x                      x       x mol

Theo định luật bảo toàn khối lượng:

m_{muối cacbonat}+ m_HCl= m _{muối clorua}+ m_CO2+ m_H2O

→ 7,0 + 2x. 36,5=9,2+ 44x+18x → x= 0,2 mol→ V_CO2= 0,2.22,4= 4,48 lít