a.\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{14,2}{142}=0,1mol\)
\(2CH_3COOH+Mg\rightarrow\left(CH_3COO\right)_2Mg+H_2\)
0,2 0,1 0,1 ( mol )
\(C_{M_{CH_3COOH}}=\dfrac{0,2}{0,25}=0,8M\)
\(V_{H_2}=0,1.22,4=2,24l\)
b.\(NaOH+CH_3COOH\rightarrow CH_3COONa+H_2O\)
0,2 0,2 ( mol )
\(V_{NaOH}=\dfrac{0,2}{0,5}=0,4l\)
\(n_{\left(CH_3COO\right)_2Mg}=\dfrac{14,2}{142}=0,1\left(mol\right)\)
PTHH: 2CH3COOH + Mg ---> (CH3COO)2Mg + H2
0,2<---------------------------0,1---------->0,1
=> \(\left\{{}\begin{matrix}C_{M\left(CH_3COOH\right)}=\dfrac{0,2}{0,25}=0,8M\\V_{H_2}=0,1.22,4=2,4\left(l\right)\end{matrix}\right.\)
PTHH: CH3COOH + NaOH ---> CH3COONa + H2O
0,2------------->0,2
=> \(V_{ddNaOH}=\dfrac{0,2}{0,5}=0,4\left(l\right)\)