\(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\\ n_{NaOH}=0,2.0,1=0,02\left(mol\right)\\ n_{CH_3COOH}=n_{NaOH}=0,02\left(mol\right)\\ C_{MddCH_3COOH}=\dfrac{0,02}{0,1}=0,2\left(M\right)\)

\(n_{NaOH}=C_M\cdot V_{NaOH}=0,2\cdot0,1=0,02\left(mol\right)\)

PTHH:\(CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\)

Theo PTHH: \(n_{CH_3COOH}=n_{NaOH}=0,02\left(mol\right)\)

Nồng độ mol của axit axetic là:

\(C_{M_{CH_3COOH}}=\dfrac{n_{CH_3COOH}}{V_{CH_3COOH}}=\dfrac{0,02}{0,1}=0,2\left(M\right)\)

\(n_{HCl}=0,2.0,2=0,04\left(mol\right)\)

Để trung hòa thì:

\(n_{NaOH}=n_{HCl}\)

\(\Leftrightarrow0,1.V_{NaOH}=0,04\)

\(\Leftrightarrow V_{NaOH}=0,4\left(l\right)=400\left(ml\right)\)

PTHH: \(HCl+NaOH\rightarrow NaCl+H_2O\)

\(\Rightarrow n_{NaCl}=n_{HCl}=0,04\left(mol\right)\)

\(V_{dd}=0,2+0,4=0,6\left(l\right)\)

\(\Rightarrow C_{M\left(NaCl\right)}=\dfrac{0,04}{0,6}=0,67M\)

2CH3COOH+Mg->(CH3COO)2Mg+H2

0,02---------------0,01-------0,01----------0,01

n muối=0,01mol

=>CM=\(\dfrac{0,02}{0,04}=0,5M\)

=>VH2=0,01.22,4=0,224l

CH3COOH+NaOH->CH3COONa+H2O

0,02--------------0,02

=>VNaOH=\(\dfrac{0,02}{0,75}=0,03l\)

a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1,42}{142}=0,01\left(mol\right)\)

PTHH: Mg + 2CH₃COOH --> (CH₃COO)₂Mg + H₂

           0,01<-------0,02<------------0,01------->0,01

=> \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,02}{0,04}=0,5M\)

b) V_H2 = 0,01.22,4 = 0,224 (l)

c) 

PTHH: NaOH + CH₃COOH --> CH₃COONa + H₂O

             0,02<------0,02

=> \(V_{dd.NaOH}=\dfrac{0,02}{0,75}=\dfrac{2}{75}\left(l\right)=\dfrac{80}{3}\left(ml\right)\)

\(a.2CH_3COOH+Mg\rightarrow\left(CH_3COO\right)_2Mg+H_2\\ n_{\left(CH_3COO\right)_2Mg}=0,01\left(mol\right)\\ n_{CH_3COOH}=2n_{\left(CH_3COO\right)_2Mg}=0,02\left(mol\right)\\ \Rightarrow CM_{CH_3COOH}=\dfrac{0,02}{0,04}=0,5M\\ b.n_{H_2}=n_{\left(CH_3COO\right)_2Mg}=0,01\left(mol\right)\\ \Rightarrow V_{H_2}=0,01.22,4=0,224\left(l\right)\\ c.CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\\ n_{CH_3COOH}=n_{NaOH}=0,02\left(mol\right)\\ \Rightarrow V_{NaOH}=\dfrac{0,02}{0,75}=0,02667\left(l\right)=26,67ml\)

a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1,42}{142}=0,01\left(mol\right)\)

PTHH: Mg + 2CH₃COOH --> (CH₃COO)₂Mg + H₂

                           0,02<-----------0,01-------->0,01

=> V_H2 = 0,01.22,4 = 0,224 (l)

\(C_{M\left(CH_3COOH\right)}=\dfrac{0,02}{0,2}=0,1M\)

b) 

PTHH: CH₃COOH + NaOH --> CH₃COONa + H₂O

                  0,02------>0,02

=> \(V_{dd.NaOH}=\dfrac{0,02}{0,2}=0,1\left(l\right)=100\left(ml\right)\)

$a\big)$

$n_{CH_3COOH}=\dfrac{100}{1000}.1=0,1(mol)$

$CH_3COOH+NaOH\to CH_3COONa+H_2O$

Theo PT: $n_{NaOH}=n_{CH_3COOH}=0,1(mol)$

$\to C\%_{NaOH}=\dfrac{0,1.40}{50}.100\%=80\%$

$b\big)$

$n_{Na_2CO_3}=\dfrac{10,6}{106}=0,1(mol)$

$2CH_3COOH+Na_2CO_3\to 2CH_3COONa+CO_2+H_2O$

Theo PT: $\begin{cases} n_{CO_2}=n_{Na_2CO_3}=0,1(mol)\\ n_{CH_3COONa}=2n_{Na_2CO_3}=0,2(mol) \end{cases}$

$\to C\%_{CH_3COONa}=\dfrac{0,2.82}{60+10,6-0,1.44}.100\%\approx 24,77\%$

nKOH = 0,5.0,3 = 0,15 mol 

CH3COOH + KOH → CH3COOK + H2O

   0,15            0,15         0,15                   mol

a) C_{M CH3COOH} = 0,15/0,2 =0,75M

b) Thể tích của dung dịch thu được sau phản ứng: 500 ml

C_{M CH3COOK} = 0,15/0,5 = 0,3M

c) Phản ứng lên men giấm

C2H5OH + O2 → CH3COOH + H2O

0,15                          0,15

→ mC2H5OH = 0,15.46 = 6,9 gam

\(n_{KOH}=0,5\cdot0,3=0,15mol\)

\(CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)

0,15                     0,15          0,15            0,15

a)\(C_{M_{CH_3COOH}}=\dfrac{0,15}{0,2}=0,75M\)

b)\(C_{M_{CH_3COOK}}=\dfrac{0,15}{0,2+0,3}=0,3M\)

\(n_{NaOH}=0,2.1,5=0,3\left(mol\right)\)

PTHH: CH₃COOH + NaOH ---> CH₃COONa + H₂O

              0,1---------->0,1

=> m_NaOH = 0,1.40 = 4 (g)

=> \(C\%_{NaOH}=\dfrac{4}{80}.100\%=5\%\)

PTHH: CH₃COOH + C₂H₅OH --H₂SO_4(đặc), t^o--> CH₃COOC₂H₅ + H₂O

              0,3------------------------------------------------>0,3

=> m_este = 0,3.88.80% = 21,12 (g)

CH3COOH+NaOH->CH3COONa+H2O

0,3--------------0,3-------0,3--------------0,3

n CH3COOH=0,3 mol

=>C% NaOH=\(\dfrac{0,3.40}{80}.100\)=15%

H=80%

=>m CH3COOC2H5=0,3.88.80%=21,12g