PTHH: Cu + Cl₂ -t^o-> CuCl₂

Ta có: \(n_{Cl_2}=\frac{10,8}{22,4}\approx0,482\left(mol\right)\\ n_{CuCl_2}=\frac{63,9}{135}\approx0,473\left(mol\right)\)

Theo PTHH và đề bài, ta có:

\(\frac{0,482}{1}>\frac{0,473}{1}\)

=> Cl₂ dư , Cu hết nên tính theo n_Cu

Theo PTHH và đề bài, ta có:

\(n_{CuCl_2}=n_{Cu}=0,473\left(mol\right)\)

b) Khối lượng CuCl₂:

\(m_{CuCl_2}=0,473.135=63,855\left(g\right)\)

=> \(\%Cu=\frac{64}{135}.100=47,407\%\)

\(\%Cl=100\%-47,407\%=52,593\%0\)

@NTTĐ sai rồi

1. nCu = m/ M = 0,4 ( mol )

PTHH : 2Cu + O2 -> 2CuO

...............0,4................0,4.....

=> mCuO = n.M = 32g > 28,8 g .

=> Cu dư .

- Gọi mol Cu và CuO trong X là x và y :

Theo bài ra ta có : \(\left\{{}\begin{matrix}x+y=0,4\\64x+80y=28,8\end{matrix}\right.\)

=> x = y = 0,2 (mol )

=> mCu = n.M = 12,8 g, mCuO = n.M = 16 ( g )

Vậy ..

2, - Gọi kim loại cần tìm là X .

\(X+2HCl\rightarrow XCl_2+H_2\)

Theo PTHH : \(n_X=n_{H2}=\dfrac{2,4}{M}=\dfrac{V}{22,4}=0,1\)

=> M = 24 ( TM )

Vậy X là Mg .

Chọn A.

4,4.

Chọn A

\(n_{H_2}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\)

PTHH: Fe + H₂SO₄ → FeSO₄ + H₂

Mol:     0,4                                         0,4

\(m_{Fe}=0,4.56=22,4\left(g\right)\)

\(m_{hh}=22,4+5=27,4\left(g\right)\)

\(\%m_{Fe}=\dfrac{22,4.100\%}{27,4}=81,75\%;\%m_{Cu}=100-81,75=18,25\%\)

\(n_{HCl}=\dfrac{58,4.15\%}{36,5}=0,24\left(mol\right)\\ Fe+2HCl\rightarrow\left(t^o\right)FeCl_2+H_2\\ n_{Fe}=n_{H_2}=\dfrac{0,24}{2}=0,12\left(mol\right)\\ \Rightarrow V1=V_{H_2\left(đktc\right)}=0,12.22,4=2,688\left(l\right)\\ x=m_{Cu}=m_{hhA}-m_{Fe}=15,68-0,12.56=8,96\left(g\right)\\ b,n_{Cu}=\dfrac{8,96}{64}=0,14\left(mol\right)\\ 2Fe+3Cl_2\rightarrow\left(t^o\right)2FeCl_3\\ Cu+Cl_2\rightarrow\left(t^o\right)CuCl_2\\ n_{Cl_2}=\dfrac{3}{2}.n_{Fe}+n_{Cu}=\dfrac{3}{2}.0,12+0,14=0,32\left(mol\right)\\ \Rightarrow V2=V_{Cl_2\left(đktc\right)}=0,32.22,4=7,168\left(l\right)\\ y=m_{muối}=m_{AlCl_3}+m_{CuCl_2}=0,12.133,5+0,14.135=34,92\left(g\right)\)

155,2

\(n_{Cu} = a ; n_{Al} = b ; n_{Fe} = c(mol)\\ \Rightarrow 64a + 27b + 56c = 28,6(1)\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ Fe + 2HCl \to FeCl_2 + H_2\\ n_{H_2} = 1,5b + c = \dfrac{13,44}{22,4} = 0,6(2)\\ \text{Mặt khác} : n_{O_2} = \dfrac{8,96}{22,4} = 0,4(mol)\\ 2Cu + O_2 \xrightarrow{t^o} 2CuO\\ 4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3\\ 4Fe + 3O_2 \xrightarrow{t^o} 2Fe_2O_3\\ \)

Ta có :

\(\dfrac{n_X}{n_{O_2}}=\dfrac{a+b+c}{0,5a +0,75b + 0,75c} = \dfrac{0,6}{0,4}(3)\\ (1)(2)(3)\Rightarrow a = \dfrac{317}{1460} ; b = \dfrac{121}{365}; c = \dfrac{15}{146}\\ \%m_{Cu} = \dfrac{\dfrac{317}{1460}.64}{28,6}.100\% = 48,59\%\\ \%m_{Al} = \dfrac{\dfrac{121}{365}.27}{28,6}.100\% = 31,3\%\\ \%m_{Fe} = 100\% - 41,59\% - 31,3\% = 27,11\%\)