1) \(n_{Al\left(OH\right)_3}=\dfrac{0,78}{78}=0,01\left(mol\right)\)

PTHH: \(Al_2\left(SO_4\right)_3+6NaOH\rightarrow3Na_2SO_4+2Al\left(OH\right)_3\) 

                                   0,03<----------------------0,01

=> n_{NaOH min} = 0,03 (mol)

=> \(C_{M\left(NaOH\right)}=\dfrac{0,03}{0,2}=0,15M\)

2) \(n_{Al_2O_3}=\dfrac{5,1}{102}=0,05\left(mol\right)\)

\(n_{Al_2\left(SO_4\right)_3}=0,3.0,25=0,075\left(mol\right)\)

PTHH: \(6NaOH+Al_2\left(SO_4\right)_3\rightarrow3Na_2SO_4+2Al\left(OH\right)_3\)

           0,45<------0,075-------------------------->0,15

            \(NaOH+Al\left(OH\right)_3\rightarrow NaAlO_2+2H_2O\)

             0,05<----0,05

            \(2Al\left(OH\right)_3\underrightarrow{t^o}Al_2O_3+3H_2O\)

              0,1<-------0,05

=> n_{NaOH max} = 0,5 (mol)

=> \(V_{dd}=\dfrac{0,5}{2}=0,25\left(l\right)=250\left(ml\right)\)

3)

\(n_{KOH\left(1\right)}=0,15.1,2=0,18\left(mol\right)\)

\(n_{Al\left(OH\right)_3\left(1\right)}=\dfrac{4,68}{78}=0,06\left(mol\right)\)

\(n_{AlCl_3}=0,1.x\left(mol\right)\)

Do khi cho KOH tác dụng với dd Y xuất hiện kết tủa

=> Trong Y chứa AlCl₃ dư

PTHH: \(3KOH+AlCl_3\rightarrow3KCl+Al\left(OH\right)_3\)

           0,18---->0,06----------------->0,06

\(n_{KOH\left(2\right)}=0,175.1,2=0,21\left(mol\right)\)

\(n_{Al\left(OH\right)_3\left(2\right)}=\dfrac{2,34}{78}=0,03\left(mol\right)\)

PTHH: \(3KOH+AlCl_3\rightarrow3KCl+Al\left(OH\right)_3\)

   (0,3x-0,18)<--(0,1x-0,06)------->(0,1x-0,06)

            \(KOH+Al\left(OH\right)_3\rightarrow KAlO_2+2H_2O\)

     (0,1x-0,09)<-(0,1x-0,09)

=> \(\left(0,3x-0,18\right)+\left(0,1x-0,09\right)=0,21\)

=> x = 1,2

300ml = 0,3l

\(n_{HNO3}=1.0,3=0,3\left(mol\right)\)

Pt : \(NaOH+HNO_3\rightarrow NaNO_3+H_2O|\)

          1               1               1              1

         0,3            0,3            0,3

\(n_{NaOH}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)

200ml = 0,2l

\(C_{M_{NaOH}}=\dfrac{0,3}{0,2}=1,5\left(M\right)\)

\(n_{NaNO3}=\dfrac{0,3.1}{1}=0,3\left(mol\right)\)

⇒ \(m_{NaNO3}=0,3.85=25,5\left(g\right)\)

Sau phản ứng :

\(V_{dd}=0,2+0,3=0,5\left(l\right)\)

\(C_{M_{NaNO3}}=\dfrac{0,3}{0,5}=0,6\left(M\right)\)

 Chúc bạn học tốt

\(n_{HNO_3}=0,3\left(mol\right)\)

\(NaOH+HNO_3\rightarrow NaNO_3+H_2O\)

Theo PT: \(n_{NaOH}=n_{NaNO_3}=n_{HNO_3}=0,3\left(mol\right)\)

\(\Rightarrow CM_{NaOH}=\dfrac{0,3}{0,2}=1,5M\)

\(m_{NaNO_3}=0,3.85=25,5\left(g\right)\)

a)

C% CuSO4 = 16/(16 + 184)  .100% = 8%
b)

n NaOH = 20/40 = 0,5(mol)

CM NaOH = 0,5/4 = 0,125M

\(a.\)

\(m_{dd_{CuSO_4\:}}=16+184=200\left(g\right)\)

\(C\%_{CuSO_4}=\dfrac{16}{200}\cdot100\%=8\%\)

\(b.\)

\(n_{NaOH}=\dfrac{20}{40}=0.5\left(mol\right)\)

\(C_{M_{NaOH}}=\dfrac{0.5}{4}=0.125\left(M\right)\)

a)   \(m_{dmCUSO4}\) =  16+184 = 200g 

C% = \(\dfrac{16}{200}\)  x 100% =8 % 

b) \(n_{NaOH}\) = \(\dfrac{20}{40}\) = 0,5 (Mol)

\(C_M\) = \(\dfrac{0.5}{4}\) = 0,125 (M)  Vì 4000ml= 4l

a) \(n_{NaOH}=\dfrac{4}{40}=0,1\left(mol\right)\)

 \(C_M=\dfrac{0,1}{0,2}=0,5M\)

b) \(n_{K_2O}=\dfrac{2,82}{94}=0,03\left(mol\right)\)

PTHH: K₂O + H₂O --> 2KOH

            0,03------------->0,06

=> \(C_M=\dfrac{0,06}{0,25}=0,24M\)

\(n_{NaOH}=\dfrac{4}{40}=0,1\left(mol\right)\\ C_M=\dfrac{0,1}{0,2}.=0,5M\) 
 \(n_{K_2O}=\dfrac{2,82}{94}=0,03\left(mol\right)\\ C_M=\dfrac{0,03}{0,25}=0,12M\)

a, \(\left\{{}\begin{matrix}n_{Ba^{2+}}=4.10^{-3}\left(mol\right)\\n_{Na^+}=3.10^{-3}\left(mol\right)\\n_{OH^-}=0,011\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=\dfrac{4.10^{-3}}{0,2+0,3}=0,008M\\\left[Na^+\right]=\dfrac{3.10^{-3}}{0,2+0,3}=0,006M\\\left[OH^-\right]=\dfrac{0,011}{0,2+0,3}=0,022M\end{matrix}\right.\)

b, Để trung hòa dung dịch A thì:

\(n_{H^+}=n_{OH^-}\)

\(\Leftrightarrow0,01.V_{ddHCl}=\left(0,02.2+0,01\right).0,2\)

\(\Leftrightarrow V_{ddHCl}=1\left(l\right)\)

cần lời giải chi tiết ạ

Câu 2 : 

$n_{HCl} = 0,2.1 + 0,3.1,5 = 0,65(mol)$
$V_{dd} = 0,2 + 0,3 = 0,5(mol)$
$C_{M_{HCl}} = \dfrac{0,65}{0,5} =1,3M$

Câu 3 : 

Gọi $m_{H_2O\ cần\ thêm} =a (gam)$

Sau khi thêm : 

$m_{NaOH} = 100.35\% = 35(gam)$
$m_{dd} = 100 + a(gam)$

Suy ra:  $\dfrac{35}{100 + a}.100\% = 20\%$

Suy ra: a = 75(gam)

Câu 4 : 

Gọi $V_{dd\ HCl\ 2M} =a (lít) ; V_{dd\ HCl\ 3M} = b(lít)$

Ta có : 

$a + b = 4$
$2a + 3b = 4.2,75$

Suy ra a = 1(lít) ; b = 3(lít)

a)

$BaO + H_2O \to Ba(OH)_2$
$n_{Ba(OH)_2} = n_{BaO} = \dfrac{30,6}{153} = 0,2(mol)$
$C_{M_{Ba(OH)_2}} = \dfrac{0,2}{0,2} = 1M$

b)

$Ba(OH)_2 + 2HCl \to BaCl_2 + 2H_2O$
$n_{HCl} = 2n_{Ba(OH)_2} = 0,4(mol)$
$V_{dd\ HCl} = \dfrac{0,4}{0,5} = 0,8(lít)$

\(n_{AgNO_3}=0,25\cdot0,2=0,05\left(mol\right);n_{MgCl_2}=0,1\cdot0,3=0,03\left(mol\right)\\ a,PTHH:2AgNO_3+MgCl_2\rightarrow2AgCl\downarrow+Mg\left(NO_3\right)_2\\ \text{Vì }\dfrac{n_{AgNO_3}}{2}< \dfrac{n_{MgCl_2}}{1}\text{ nên sau phản ứng }MgCl_2\text{ dư}\\ \Rightarrow n_{AgCl}=n_{AgNO_3}=0,05\left(mol\right)\\ \Rightarrow a=m_{AgCl}=0,05\cdot143,5=7,175\left(g\right)\\ 2,n_{Mg\left(NO_3\right)_2}=\dfrac{1}{2}n_{AgNO_3}=0,025\left(mol\right)\\ \Rightarrow C_{M_{Mg\left(NO_3\right)_2}}=\dfrac{0,025}{0,2+0,3}=0,05M\)

Đáp án:

  CÂU 3:

 PTHH: 

nAgNO3=0,2×0,25=0,05(mol)nAgNO3=0,2×0,25=0,05(mol)

nMgCl2=0,3×0,1=0,03(mol)nMgCl2=0,3×0,1=0,03(mol)

 Xét nMgCl21nMgCl21

→  hết,  dư.

Tính theo số mol 

→ nMg(NO3)2=12×0,05=0,025(mol)nMg(NO3)2=12×0,05=0,025(mol)

⇒ a=mAgCl=0,05×143,5=7,175(g)a=mAgCl=0,05×143,5=7,175(g)

 - Dung dịch  gồm:  dư và 

Xem như thể tích dung dịch sau phản ứng thay đổi không đáng kể.

→ Vdd=0,2+0,3=0,5(l)Vdd=0,2+0,3=0,5(l)

⇒ C(M)Mg(NO3)2=0,0250,5=0,05(M)