\(n_{CuSO_4}=\dfrac{200.16}{160.100}=0,2mol\)

\(n_{NaOH}=\dfrac{200.10}{40.100}=0,5mol\)

CuSO₄+2NaOH\(\rightarrow\)Cu(OH)₂\(\downarrow\)+Na₂SO₄

-Ta có tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\rightarrow\)CuSO₄ hết, NaOH dư.

Cu(OH)₂\(\overset{t^0}{\rightarrow}\)CuO+H₂O

\(n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuSO_4}=0,2mol\)

a=\(m_{CuO}=0,2.80=16gam\)

\(m_{Cu\left(OH\right)_2}=0,2.98=19,6gam\)

\(n_{NaOH\left(pu\right)}=2n_{CuSO_4}=0,4mol\rightarrow n_{NaOH\left(dư\right)}=0,5-0,4=0,1mol\)

\(m_{NaOH\left(dư\right)}=0,1.40=4gam\)

\(n_{Na_2SO_4}=n_{CuSO_4}=0,2mol\rightarrow m_{Na_2SO_4}=0,2.136=27,2gam\)

\(m_{dd}=200+200-19,6=380,4gam\)

C%_NaOH=\(\dfrac{4.100}{380,4}\approx1,05\%\)

C%Na₂SO₄=\(\dfrac{27,2.100}{380,4}\approx7,15\%\)

PTHH: \(2NaOH+CuSO_4\rightarrow Na_2SO_4+Cu\left(OH\right)_2\downarrow\)

a) Ta có: \(n_{CuSO_4}=\dfrac{320\cdot20\%}{160}=0,4\left(mol\right)=n_{Cu\left(OH\right)_2}\) \(\Rightarrow m_{Cu\left(OH\right)_2}=0,4\cdot98=39,2\left(g\right)\)

b) Theo PTHH: \(n_{NaOH}=2n_{CuSO_4}=0,8mol\) \(\Rightarrow m_{ddNaOH}=\dfrac{0,8\cdot40}{10\%}=320\left(g\right)\)

c) Theo PTHH: \(n_{Na_2SO_4}=n_{CuSO_4}=0,4mol\) \(\Rightarrow m_{Na_2SO_4}=0,4\cdot142=56,8\left(g\right)\)

Mặt khác: \(m_{dd}=m_{ddNaOH}+m_{ddCuSO_4}-m_{Cu\left(OH\right)_2}=600,8\left(g\right)\)

\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{56,8}{600,8}\cdot100\%\approx9,45\%\) 

CaCl₂ trộn với NaOH không tạo kết tủa nha em!

\(n_{CuSO_4}=\dfrac{200.16\%}{160}=0,2\left(mol\right)\)

PTHH :

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2\downarrow+Na_2SO_4\)

0,2              0,4                  0,2               0,2 

\(m_{NaOH}=0,4.40=16\left(g\right)\)

\(m_{ddNaOH}=\dfrac{16.100}{10}=160\left(g\right)\)

\(c,m_{Na_2SO_4}=0,2.142=28,4\left(g\right)\)

\(m_{ddNa_2SO_4}=200+160-\left(0,2.98\right)=340,4\left(g\right)\)

\(C\%_{Na_2SO_4}=\dfrac{28,4}{240,4}.100\%\approx8,34\%\)

\(d,PTHH:\)

\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)

0,2               0,2 

\(m_{CuO}=0,2.80=16\left(g\right)\)

a, \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

b, \(m_{CuSO_4}=200.16\%=32\left(g\right)\Rightarrow n_{CuSO_4}=\dfrac{32}{160}=0,2\left(mol\right)\)

\(n_{NaOH}=2n_{CuSO_4}=0,4\left(mol\right)\Rightarrow m_{ddNaOH}=\dfrac{0,4.40}{10\%}=160\left(g\right)\)

c, \(n_{Cu\left(OH\right)_2}=n_{Na_2SO_4}=n_{CuSO_4}=0,2\left(mol\right)\)

\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{0,2.142}{200+160-0,2.98}.100\%\approx8,34\%\)

d, \(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)

\(n_{CuO}=n_{Cu\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)

nH2SO4=0,2.0,5=0,1(mol)

nMgSO4=0,3.0,5=0,15(mol)

nMgO=\(\dfrac{4}{40}=0,1mol\)

PTHH: 2NaOH + H₂SO₄ --> Na₂SO₄ + 2H₂O

                0,2<-----0,1

             2NaOH + MgSO₄ --> Mg(OH)₂ + Na₂SO₄

                0,2<------------------0,1

             Mg(OH)₂ --t^o--> MgO + H₂O

                0,1<------------0,1

=> n_NaOH = 0,2 + 0,2 = 0,4 (mol)

=> m_NaOH = 0,4.40 = 16 (g)

=> 

\(m_{ct}=\dfrac{13,5.100}{100}=13,5\left(g\right)\)

\(n_{CuCl2}=\dfrac{13,5}{135}=0,1\left(mol\right)\)

\(m_{ct}=\dfrac{5.200}{100}=10\left(g\right)\)

\(n_{NaOH}=\dfrac{10}{40}=0,25\left(mol\right)\)

Pt : \(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl|\)

           1              2                 1                  2

          0,1         0,25              0,1

a) Lập tỉ số so sánh : \(\dfrac{0,1}{1}< \dfrac{0,25}{2}\)

                      ⇒ CuCl₂ phản ứng hết , NaOH dư

                      ⇒ Tính toán dựa vào số mol của CuCl₂

\(n_{Cu\left(OH\right)2}=\dfrac{0,1.1}{1}=0,1\left(mol\right)\)

⇒ \(m_{Cu\left(OH\right)2}=0,1.98=9,8\left(g\right)\)

b) Pt : \(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O|\)

                1              1           1

              0,1           0,1

\(n_{CuO}=\dfrac{0.1.1}{1}=0,1\left(mol\right)\)

⇒ \(m_{CuO}=0,1.80=8\left(g\right)\)

 Chúc bạn học tốt

Ta có: \(n_K=\dfrac{1,56}{39}=0,04\left(mol\right)\)

\(m_{CuSO_4}=200.8\%=16\left(g\right)\Rightarrow n_{CuSO_4}=\dfrac{16}{160}=0,1\left(mol\right)\)

PT: \(2K+2H_2O\rightarrow2KOH+H_2\)

___0,04___________0,04___0,02 (mol)

 \(2KOH+CuSO_4\rightarrow K_2SO_4+Cu\left(OH\right)_{2\downarrow}\)

Xét tỉ lệ: \(\dfrac{0,04}{2}< \dfrac{0,1}{1}\), ta được CuSO₄ dư.

Theo PT: \(n_{Cu\left(OH\right)_2}=n_{CuSO_4\left(pư\right)}=n_{K_2SO_4}=\dfrac{1}{2}n_{KOH}=0,02\left(mol\right)\)

⇒ n_{CuSO4 (dư)} = 0,08 (mol)

\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)

___0,02____0,02 (mol)

a, Ta có: V_B = 0,02.22,4 = 0,448 (l)

b, m_CuO = 0,02.80 = 1,6 (g)

c, Ta có: m _{dd sau pư} = 1,56 + 200 - 0,02.2 - 0,02.98 = 199,56 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{K_2SO_4}=\dfrac{0,02.174}{199,56}.100\%\approx1,74\%\\C\%_{CuSO_4\left(dư\right)}=\dfrac{0,08.160}{199,56}.100\%\approx6,41\%\end{matrix}\right.\)

Bạn tham khảo nhé!

\(n_K=\dfrac{1,56}{39}=0,04\left(mol\right)\)

\(n_{CuSO4}=\dfrac{200.8}{100.160}=0,1\left(mol\right)\)

\(2K+2H2O\rightarrow2KOH+H2\)

0,04--------------->0,04------------->0,02(mol)

\(2KOH+CuSO4\rightarrow Cu\left(OH\right)2+K2SO4\)

0,04-------->0,02----->0,02------->0,02(mol)

=> dd A gồm CuSO4 dư và K2SO4

=> Khí B là H2

=>Kết tủa C là Cu(OH)2

a) \(V_{H2}=0,02.22,4=0,448\left(l\right)\)

b)\(Cu\left(OH\right)2\rightarrow CuO+H2O\)

0,02---------------->0,02(mol)

\(m_{CuO}=0,02.80=1,6\left(g\right)\)

c) \(m_{KOH}=0,04.56=2,24\left(g\right)\)

\(m_{Cu\left(OH\right)2}=0,02.98=1,96\left(g\right)\)

\(\Rightarrow\)\(m_{dd}=200+2,24-1,96=200,28\left(g\right)\)

\(C\%_{K2SO4}=\dfrac{0,02.174}{200,28}.100\%=1,74\%\)

\(n_{CuSO4}dư=0,1-0,02=0,08\left(mol\right)\)

\(C\%_{CuSO4}=\dfrac{0,08.160}{200,28}.100\%=6,39\%\)

Chúc bạn học tốt^^