Ta có: \(n_K=\dfrac{1,56}{39}=0,04\left(mol\right)\)
\(m_{CuSO_4}=200.8\%=16\left(g\right)\Rightarrow n_{CuSO_4}=\dfrac{16}{160}=0,1\left(mol\right)\)
PT: \(2K+2H_2O\rightarrow2KOH+H_2\)
___0,04___________0,04___0,02 (mol)
\(2KOH+CuSO_4\rightarrow K_2SO_4+Cu\left(OH\right)_{2\downarrow}\)
Xét tỉ lệ: \(\dfrac{0,04}{2}< \dfrac{0,1}{1}\), ta được CuSO4 dư.
Theo PT: \(n_{Cu\left(OH\right)_2}=n_{CuSO_4\left(pư\right)}=n_{K_2SO_4}=\dfrac{1}{2}n_{KOH}=0,02\left(mol\right)\)
⇒ nCuSO4 (dư) = 0,08 (mol)
\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)
___0,02____0,02 (mol)
a, Ta có: VB = 0,02.22,4 = 0,448 (l)
b, mCuO = 0,02.80 = 1,6 (g)
c, Ta có: m dd sau pư = 1,56 + 200 - 0,02.2 - 0,02.98 = 199,56 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{K_2SO_4}=\dfrac{0,02.174}{199,56}.100\%\approx1,74\%\\C\%_{CuSO_4\left(dư\right)}=\dfrac{0,08.160}{199,56}.100\%\approx6,41\%\end{matrix}\right.\)
Bạn tham khảo nhé!
\(n_K=\dfrac{1,56}{39}=0,04\left(mol\right)\)
\(n_{CuSO4}=\dfrac{200.8}{100.160}=0,1\left(mol\right)\)
\(2K+2H2O\rightarrow2KOH+H2\)
0,04--------------->0,04------------->0,02(mol)
\(2KOH+CuSO4\rightarrow Cu\left(OH\right)2+K2SO4\)
0,04-------->0,02----->0,02------->0,02(mol)
=> dd A gồm CuSO4 dư và K2SO4
=> Khí B là H2
=>Kết tủa C là Cu(OH)2
a) \(V_{H2}=0,02.22,4=0,448\left(l\right)\)
b)\(Cu\left(OH\right)2\rightarrow CuO+H2O\)
0,02---------------->0,02(mol)
\(m_{CuO}=0,02.80=1,6\left(g\right)\)
c) \(m_{KOH}=0,04.56=2,24\left(g\right)\)
\(m_{Cu\left(OH\right)2}=0,02.98=1,96\left(g\right)\)
\(\Rightarrow\)\(m_{dd}=200+2,24-1,96=200,28\left(g\right)\)
\(C\%_{K2SO4}=\dfrac{0,02.174}{200,28}.100\%=1,74\%\)
\(n_{CuSO4}dư=0,1-0,02=0,08\left(mol\right)\)
\(C\%_{CuSO4}=\dfrac{0,08.160}{200,28}.100\%=6,39\%\)
Chúc bạn học tốt^^
