câu 1 
\(n_{Fe}=\dfrac{14}{56}=0,25\left(mol\right)\\ pthh:Fe+2HCl\rightarrow FeCl_2+H_2\) 
           0,25   0,5         0,25       0,25 
\(m_{FeCl_2}=0,25.127=31,75g\\ V_{H_2}=0,25.22,4=5,6\\ C_{M\left(HCl\right)}=\dfrac{0,5}{0,2}=2,5M\)
câu 2 
1 ) \(m_{\text{dd}}=35+100=135g\\ 2,C\%=\dfrac{204}{204+100}.100=60\%\\ =>m\text{dd}=\dfrac{100.204}{60}=340g\)
 

\(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)

a) PTHH : \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

Theo Pt : \(n_{Fe}=n_{H2SO4}=n_{FeSO4}=n_{H2}=0,2\left(mol\right)\)

b) \(V_{H2\left(dktc\right)}=0,2.22,4=4,48\left(l\right)\)

c) \(C_{MddH2SO4}=\dfrac{0,2}{0,2}=1\left(M\right)\)

d) \(m_{muối}=m_{FeSO4}=0,2.152=30,4\left(g\right)\)

a, \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

Ta có: \(n_{Fe}=\dfrac{0,56}{56}=0,01\left(mol\right)\)

Theo PT: \(n_{H_2SO_4}=n_{FeSO_4}=n_{H_2}=n_{Fe}=0,01\left(mol\right)\)

b, \(m_{FeSO_4}=0,01.152=1,52\left(g\right)\)

\(V_{H_2}=0,01.22,4=0,224\left(l\right)\)

c, \(m_{ddH_2SO_4}=\dfrac{0,01.98}{19,6\%}=5\left(g\right)\)

a) \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)

PTHH: 2Al + 3H₂SO₄ --> Al₂(SO₄)₃ + 3H₂

           0,4-->0,6---------->0,2------->0,6

=> \(C_{M\left(dd.H_2SO_4\right)}=\dfrac{0,6}{0,15}=4M\)

b) V_H2 = 0,6.22,4 = 13,44 (l)

c) \(C_{M\left(Al_2\left(SO_4\right)_3\right)}=\dfrac{0,2}{0,15}=\dfrac{4}{3}M\)

\(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ pthh:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\) 
           0,4     0,6                   0,2             0,6 
\(C_M_{H_2SO_4}=\dfrac{0,6}{0,15}=4M\\ V_{H_2}=0,622,4=13,44L\) 
\(C_M=\dfrac{0,2}{0,15}=1,3M\)

nFe = 5.6/56 = 0.1 (mol) 

nHCl = 0.2*2 = 0.4 (mol) 

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

LTL : 0.1/1 < 0.4/2 => HCl dư 

mHCl dư = ( 0.4 - 0.2 ) * 36.5 = 7.3 (g) 

VH2 = 0.2*22.4 = 4.48 (l) 

CM FeCl2 = 0.1/0.2 = 0.5(M)

CM HCl dư = 0.2 / 0.2 = 1(M) 

\(n_{HCl}=0,2.2=0,4\left(mol\right)\\ PTHH:Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=n_{FeCl_2}=\dfrac{0,4}{2}=0,2\left(mol\right)\\ a,m_{Fe}=0,2.56=11,2\left(g\right)\\ b,V_{H_2\left(đktc\right)}=0,2.22,4=4,48\left(l\right)\\ c,V_{ddFeCl_2}=V_{ddHCl}=0,2\left(l\right)\\ C_{MddFeCl_2}=\dfrac{0,2}{0,2}=1\left(M\right)\)

Ta có: \(n_{Zn}=\dfrac{6,5}{65}=0,1\left(mol\right)\)

\(a.PTHH:Zn+H_2SO_4--->ZnSO_4+H_2\uparrow\)

b. Theo PT: \(n_{ZnSO_4}=n_{H_2}=n_{Zn}=0,1\left(mol\right)\)

\(\Rightarrow m_{ZnSO_4}=0,1.161=16,1\left(g\right)\)

\(V_{H_2}=0,1.22,4=2,24\left(lít\right)\)

c. Theo PT: \(n_{H_2SO_4}=n_{Zn}=0,1\left(mol\right)\)

\(\Rightarrow m_{H_2SO_4}=0,1.98=9,8\left(g\right)\)

Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{9,8}{m_{dd_{H_2SO_4}}}.100\%=20\%\)

\(\Rightarrow m_{dd_{H_2SO_4}}=49\left(g\right)\)

n_Al = 5.4/27 = 0.2  (mol) 

2Al + 3H2SO4 => Al2(SO4)3 + 3H2 

0.2____0.3_________________0.3 

VH2 = 0.3*22.4 = 6.72(l) 

CM H2SO4 = 0.3/0.1 = 3 M

PTHH: \(2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\)

Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\) 

\(\Rightarrow n_{H_2}=0,3mol=n_{H_2SO_4}\) \(\Rightarrow\left\{{}\begin{matrix}V_{H_2}=0,3\cdot22,4=6,72\left(l\right)\\C_{M_{H_2SO_4}}=\dfrac{0,3}{0,1}=3\left(M\right)\end{matrix}\right.\)

a. \(n_{SO_3}=\dfrac{8}{80}=0,1\left(mol\right)\)

\(C_M=\dfrac{0,1}{200}=0,0005\left(mol\text{/}l\right)\)