Bài 2:

a) PTHH: \(Na_2O+H_2O\rightarrow2NaOH\)

b) Dung dịch A là dung dịch bazơ

Ta có: \(n_{Na_2O}=\dfrac{3,1}{62}=0,05\left(mol\right)\) \(\Rightarrow n_{NaOH}=0,1\left(mol\right)\) \(\Rightarrow C_{M_{NaOH}}=\dfrac{0,1}{1}=0,1\left(M\right)\)

c) Sửa đề: dd H₂SO₄ 9,8%

PTHH: \(2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\)

Theo PTHH: \(n_{H_2SO_4}=\dfrac{1}{2}n_{NaOH}=0,05\left(mol\right)\)

\(\Rightarrow m_{ddH_2SO_4}=\dfrac{0,05\cdot98}{9,8\%}=50\left(g\right)\) \(\Rightarrow V_{ddH_2SO_4}=\dfrac{50}{1,14}\approx43,86\left(ml\right)\)

Bài 1:

PTHH: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{CuO}=\dfrac{16}{80}=0,2\left(mol\right)\\n_{H_2SO_4}=\dfrac{200\cdot19,6\%}{98}=0,4\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\) Axit còn dư

\(\Rightarrow n_{CuSO_4}=0,2\left(mol\right)=n_{H_2SO_4\left(dư\right)}\)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{CuSO_4}=\dfrac{0,2\cdot160}{200+16}\cdot100\%\approx14,81\%\\C\%_{H_2SO_4\left(dư\right)}=\dfrac{0,2\cdot98}{200+16}\cdot100\%\approx9,07\%\end{matrix}\right.\)

\(n_{H_2SO_4}=\dfrac{200.19,6}{100.98}=0,4mol\\ CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4\left(A\right)}=n_{CuO}=n_{H_2SO_4}=0,4mol\\ n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\\\Rightarrow\dfrac{0,4}{1}>\dfrac{0,3}{1}\Rightarrow CuSO_4.pư.không.hết\)

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

0,3mol        0,6mol                                        0,3mol

\(m_{ddB}=0,4.80+200+0,6.40-29,4=226,6g\\ C_{\%Na_2SO_4\left(B\right)}=\dfrac{0,3.142}{226,6}\cdot100=18,8\%\)

\(a)n_{H_2SO_4}=\dfrac{58,8.20}{100.98}=0,12mol\\ n_{BaCl_2}=\dfrac{200.5,2}{100.208}=0,05mol\\ BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl\\ \Rightarrow\dfrac{0,12}{1}>\dfrac{0,05}{2}\Rightarrow H_2SO_4.dư\\ BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl\)

0,05         0,05             0,05           0,1

\(m_{BaSO_4}=0,05.233=11,65g\\ b)m_{dd}=58,8+200-11,65=247,15g\\ C_{\%HCl}=\dfrac{0,1.36,5}{247,15}\cdot100=1,48\%\\ C_{\%H_2SO_4,dư}=\dfrac{\left(0,12-0,05\right).98}{247,15}\cdot100=2,78\%\)

Ta có: \(n_{H_2SO_4}=\dfrac{200.19,6\%}{98}=0,4\left(mol\right)\)

\(n_{Cu\left(OH\right)_2}=\dfrac{29,4}{98}=0,3\left(mol\right)\)

PT: \(CuO+H_2SO_4\rightarrow CuSO_4+H_2O\)

Dung dịch A gồm: CuSO₄ và H₂SO₄ dư

\(H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O\)

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

Đề có cho dữ kiện gì liên quan đến dd NaOH không bạn nhỉ?

giup mk voi

\(\text{1)}m_{KOH}=40.35\%=14\left(g\right)\\ \rightarrow n_{KOH}=\dfrac{14}{56}=0,25\left(mol\right)\\ PTHH:KOH+HCl\rightarrow KCl+H_2O\\ \text{Theo pthh}:n_{HCl}=n_{KOH}=0,25\left(mol\right)\\ \rightarrow V_{ddHCl}=0,25.0,5=0,125\left(l\right)\)

\(\text{2)}n_{Al}=\dfrac{4,05}{27}=0,15\left(mol\right)\\ n_{H_2SO_4}=200.14,7\%=29,4\left(g\right)\\ \rightarrow n_{H_2SO_4}=\dfrac{29,4}{98}=0,3\\ \text{PTHH}:2Al+3H_2SO_4\rightarrow Al_2\left(SO_4\right)_3+3H_2\uparrow\\ \text{LTL}:\dfrac{0,15}{2}< \dfrac{0,3}{3}\rightarrow H_2SO_4\text{ dư}\)

\(\text{Theo pthh}:\left\{{}\begin{matrix}n_{H_2SO_4\left(pư\right)}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}.0,15=0,225\left(mol\right)\\n_{H_2}=n_{H_2SO_4\left(pư\right)}=0,225\left(mol\right)\\n_{Al_2\left(SO_4\right)_3}=\dfrac{1}{2}n_{Al}=\dfrac{1}{2}.0,15=0,075\left(mol\right)\end{matrix}\right.\\ \rightarrow m_{dd\left(\text{sau phản ứng}\right)}=200+4,05-0,3.2=203,45\left(g\right)\)

\(\rightarrow\left\{{}\begin{matrix}C\%_{H_2SO_4\text{ dư}}=\dfrac{\left(0,3-0,225\right).98}{203,45}=3,61\%\\C\%_{Al_2\left(SO_4\right)_3}=\dfrac{342.0,075}{203,45}=12,61\%\end{matrix}\right.\)

\(n_{Zn}=\dfrac{26}{65}=0,4\left(mol\right)\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\) 
           0,4       0,8        0,4           0,4
\(a,V_{H_2}=0,4.22,4=8,96\left(l\right)\\ b,C\%_{HCl}=\dfrac{0,8.36,5}{150}.100\%=19,5\%\\ c,m_{\text{dd}}=26+150-\left(0,4.2\right)=175,2\left(g\right)\\ C\%_{ZnCl_2}=\dfrac{0,4.136}{175,2}.100\%=31\%\)

\(a,PTHH:CuO+H_2SO_4\rightarrow CuSO_4+H_2O\\ n_{CuSO_4}=n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\\ \Rightarrow m_{CuSO_4}=0,1\cdot160=16\left(g\right)\\ b,n_{H_2SO_4}=n_{CuO}=0,1\left(mol\right)\\ \Rightarrow m_{CT_{H_2SO_4}}=0,1\cdot98=9,8\left(g\right)\\ \Rightarrow C\%_{H_2SO_4}=\dfrac{9,8}{200}\cdot100\%=4,9\%\)

Câu B chịu nka~~

→nH2O(dd bđ)=1120−190,418=51,6(mol)→nH2O(dd bđ)=1120−190,418=51,6(mol)

$S{}^{}+{}^{}O\to {}^{}S{}^{}$

$\to S{}^{}$ hết, ${}^{}O$ dư

nH2

PTHH: \(SO_3+H_2O\rightarrow H_2SO_4\)

Ta có: \(n_{SO_3}=\dfrac{200}{80}=2,5\left(mol\right)=n_{H_2SO_4}\)

Mặt khác: \(m_{ddH_2SO_4}=1000\cdot1,12=1120\left(g\right)\) \(\Rightarrow m_{H_2SO_4\left(ban.đầu\right)}=1120\cdot17\%=190,4\left(g\right)\)

Bảo toàn khối lượng: \(m_{ddH_2SO_4\left(sau\right)}=m_{SO_3}+m_{ddH_2SO_4\left(ban.đầu\right)}=1320\left(g\right)\)

\(\Rightarrow C\%=\dfrac{2,5\cdot98+190,4}{1320}\cdot100\%\approx32,98\%\)