nCuSO4= 32/160=0.2 mol

nNaOH= 2*0.25=0.5 mol

2NaOH + CuSO4 --> Na2SO4 + Cu(OH)2

Bđ: 0.5_______0.2

Pư: 0.4_______0.2_______0.2________0.2

Kt: 0.1________0________0.2________0.2

Cu(OH)2 -to-> CuO + H2O

0.2___________0.2

mCuO= 0.2*80=16g

mNaOH ( dư) = 0.1*40=4g

mNa2SO4= 0.2*142=28.4g

CaCl₂ trộn với NaOH không tạo kết tủa nha em!

\(n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)

a) \(CuCl_2+2NaOH\rightarrow Cu\left(OH\right)_2+2NaCl\left(1\right)\)

     \(Cu\left(OH\right)_2\xrightarrow[t^o]{}CuO+H_2O\left(2\right)\)

b) \(Pt\left(1\right):n_{Cu\left(OH\right)2}=\dfrac{1}{2}n_{NaOH}=0,25\left(mol\right)\)

  \(Pt\left(2\right):n_{Cu\left(OH\right)2}=n_{CuO}=0,25\left(mol\right)\Rightarrow m_{Cu}=0,25.64=16\left(g\right)\)

c) Pt(1) : \(n_{NaOH}=n_{NaCl}=0,5\left(mol\right)\Rightarrow m_{NaCl}=0,5.58,5=29,25\left(g\right)\)

a, \(FeCl_3+3NaOH\rightarrow3NaCl+Fe\left(OH\right)_3\)

\(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O\)

b, \(n_{FeCl_3}=0,4.2=0,8\left(mol\right)\)

Theo PT: \(n_{NaCl}=3n_{FeCl_3}=2,4\left(mol\right)\)

\(\Rightarrow C_{M_{NaCl}}=\dfrac{2,4}{0,4+0,2}=4\left(M\right)\)

c, \(n_{Fe_2O_3}=\dfrac{1}{2}n_{Fe\left(OH\right)_3}=\dfrac{1}{2}n_{FeCl_3}=0,4\left(mol\right)\)

\(\Rightarrow m_{Fe_2O_3}=0,4.160=64\left(g\right)\)

\(n_{FeCl_3}=0,4.2=0,8\left(mol\right)\)

PTHH:

\(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)

0,8         2,4                 0,8             2,4

\(2Fe\left(OH\right)_3\underrightarrow{t^o}Fe_2O_3+3H_2O\)

0,8                 0,4         1,2

\(C_{M\left(NaCl\right)}=\dfrac{2,4}{0,6}=4\left(M\right)\)

\(m_{Fe_2O_3}=0,4.160=64\left(g\right)\)

\(n_{FeCl3}=2.0,4=0,8\left(mol\right)\)

PTHH : \(FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3+3NaCl\)

              0,8----------------------->0,8----------->2,4

b) \(C_{MNaCl}=\dfrac{2,4}{0,4+0,2}=4M\)

c) \(2Fe\left(OH\right)_3\xrightarrow[]{t^o}Fe_2O_3+3H_2O\)

0,8--------------->0,4

\(\Rightarrow a=m_{Fe2O3}=0,4.160=64\left(g\right)\)

a) \(n_{NaOH}=\dfrac{20}{40}=0,5\left(mol\right)\)

PTHH: CuCl₂ + 2NaOH --> Cu(OH)₂ + 2NaCl

Xét tỉ lệ: \(\dfrac{0,2}{1}< \dfrac{0,5}{2}\) => CuCl₂ hết, NaOH dư

PTHH: CuCl₂ + 2NaOH --> Cu(OH)₂ + 2NaCl

              0,2------>0,4-------->0,2------->0,4

            Cu(OH)₂ --t^o--> CuO + H₂O

               0,2-------------->0,2

=> m_CuO = 0,2.80 = 16(g)

b)

\(\left\{{}\begin{matrix}m_{NaOH\left(dư\right)}=20-0,4.40=4\left(g\right)\\m_{NaCl}=0,4.58,5=23,4\left(g\right)\end{matrix}\right.\)

\(n_{KOH}=\dfrac{22,4}{56}=0,4(mol)\\ a,PTHH:MgCl_2+2KOH\to Mg(OH)_2\downarrow+2KCl\\ Mg(OH)_2\buildrel{{t^o}}\over\to MgO+H_2O\\ b,\text {Vì } \dfrac{n_{MgCl_2}}{1}<\dfrac{n_{KOH}}{2} \Rightarrow \text {KOH dư}\\ \Rightarrow n_{MgO}=n_{Mg(OH)_2}=n_{MgCl_2}=0,15(mol)\\ \Rightarrow m_{MgO}=0,15.40=6(g)\\ c,\text {Chất tan trong nước lọc là KCl}\\ \text {Theo PT: }n_{KCl}=2n_{MgCl_2}=0,3(mol)\\ \Rightarrow m_{KCl}=0,3.74,5=22,35(g)\)