Gọi \(\left\{{}\begin{matrix}n_{Zn}=a\left(mol\right)\\n_{Fe}=b\left(mol\right)\\n_{Al}=c\left(mol\right)\end{matrix}\right.\) => 65a + 56b + 27c = 10,65 (1)

PTHH: Zn + 2HCl --> ZnCl₂ + H₂

            Fe + 2HCl --> FeCl₂ + H₂

            2Al + 6HCl --> 2AlCl₃ + 3H₂

=> \(n_{H_2}=a+b+1,5c=\dfrac{5,04}{22,4}=0,225\left(mol\right)\) (2)

PTHH: Zn + Cl₂ --t^o--> ZnCl₂

            2Fe + 3Cl₂ --t^o--> 2FeCl₃

            2Al + 3Cl₂ --t^o--> 2AlCl₃

=> \(n_{Cl_2}=a+1,5b+1,5c=\dfrac{5,6}{22,4}=0,25\left(mol\right)\) (3)

(1)(2)(3) => \(\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,05\left(mol\right)\\c=0,05\left(mol\right)\end{matrix}\right.\) => \(\left\{{}\begin{matrix}m_{Zn}=0,1.65=6,5\left(g\right)\\m_{Fe}=0,05.56=2,8\left(g\right)\\m_{Al}=0,05.27=1,35\left(g\right)\end{matrix}\right.\)

a) \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{6,5}{10,65}.100\%=61,033\%\\\%m_{Fe}=\dfrac{2,8}{10,65}.100\%=26,291\%\\\%m_{Al}=\dfrac{1,35}{10,65}.100\%=12,676\%\end{matrix}\right.\)

b) n_HCl = 2a + 2b + 3c = 0,45 (mol)

=> m_HCl = 0,45.36,5 = 16,425 (g)

=> \(a\%=C\%=\dfrac{16,425}{200}.100\%=8,2125\%\)

c) m_{dd sau pư} = 10,65 + 200 - 0,225.2 = 210,2 (g)

=> \(\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,1.136}{210,2}.100\%=6,47\%\\C\%_{FeCl_2}=\dfrac{0,05.127}{210,2}.100\%=3,02\%\\C\%_{AlCl_3}=\dfrac{0,05.133,5}{210,2}.100\%=3,176\%\end{matrix}\right.\)

Gọi số mol Al, Fe là a, b (mol)

=> 27a + 56b = 11,1 (1)

\(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

            a----------------------->1,5a

           Fe + 2HCl --> FeCl₂ + H₂

           b------------------------>b

=> 1,5a + b = 0,3 (2)

(1)(2) => a = 0,1; b = 0,15

=> \(\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,1.27}{11,1}.100\%=24,32\%\\\%m_{Fe}=\dfrac{0,15.56}{11,1}.100\%=75,68\end{matrix}\right.\)

\(n_{Al}=a\left(mol\right)\)

\(n_{Fe}=b\left(mol\right)\)

\(m=27a+56b=19.3\left(g\right)\left(1\right)\)

\(n_{H^+}=0.2\cdot2+0.2\cdot2.25\cdot2=1.3\left(mol\right)\)

\(2Al+6H^+\rightarrow2Al^{3+}+3H_2\)

\(Fe+2H^+\rightarrow Fe^{2+}+H_2\)

\(n_{H^+}=3a+2b=1.3\left(mol\right)\left(2\right)\)

\(\left(1\right),\left(2\right):a=0.3,b=0.2\)

\(\%Al=\dfrac{0.3\cdot27}{19.3}\cdot100\%=41.96\%\)

\(\%Fe=58.04\%\)

\(b.\)

\(n_{H_2}=\dfrac{1}{2}n_{H^+}=0.65\left(mol\right)\)

Bảo toàn khối lượng : 

\(m_{Muối}=19.3+0.4\cdot36.5+0.45\cdot98-0.65\cdot2=76.7\left(g\right)\)

em cảm ơn ạ!

giúp em vs ạ

a, \(Mg+2HCl\rightarrow MgCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

b, 24n_Mg + 27n_Al = 6,12 (1)

Theo PT: \(n_{H_2}=n_{Mg}+\dfrac{3}{2}n_{Al}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Mg}=0,12\left(mol\right)\\n_{Al}=0,12\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,12.24}{6,12}.100\%\approx47,06\%\\\%m_{Al}\approx52,94\%\end{matrix}\right.\)

Gọi $n_{Fe} = a(mol), n_{Zn} = b(mol) , n_{Al} = c(mol) \Rightarrow 56a + 65b + 27c = 20,4(1)$

$Fe + H_2SO_4 \to FeSO_4 + H_2$
$Zn + H_2SO_4 \to ZnSO_4 + H_2$
$2Al +3 H_2SO_4 \to Al_2(SO_4)_3 +3 H_2$

Theo PTHH : $n_{H_2} = a + b + 1,5c = \dfrac{10,08}{22,4} = 0,45(mol)(2)$

Mặt khác : 

$2Fe + 3Cl_2 \xrightarrow{t^o} 2FeCl_3$
$Zn + Cl_2 \xrightarrow{t^o} ZnCl_2$
$2Al + 3Cl_2 \xrightarrow{t^o} 2AlCl_3$

Theo PTHH : $n_{Cl_2} = 1,5n_{Fe} + n_{Zn} + 1,5n_{Al}$

Suy ra : \dfrac{1,5a + b + 1,5c}{a + b + c} = \dfrac{0,275}{0,2}(3)$

Từ (1)(2)(3) suy ra : a = 0,2 ; b = 0,1 ; c = 0,1

$\%m_{Fe} = \dfrac{0,2.56}{20,4}.100\% = 54,9\%$

$\%m_{Zn} = \dfrac{0,1.65}{20,4}.100\% = 31,9\%$
$\%m_{Al} = 100\% - 54,9\% - 31,9\% = 13,2\%$