Ta có ptpu

MgCO3+ 2HCl ----> MgCl2 + H2O+ CO2

\(n_{MgCO3}\)= \(\frac{9,6}{84}\)= \(\frac{0,8}{7}\) ( mol)

\(m_{HCl}\)= \(\frac{14,6}{100}.100\)= 14,6(g)

=> \(n_{HCl}\)= \(\frac{14,6}{36,5}=0,4\left(mol\right)\)

 Theopt ta thấy sau phản ứng HCl dư và dư \(\frac{1,2}{7}\) mol==> m dư= 6,26 (g)

=> \(n_{CO2}\)= \(n_{MgCO3}\)= \(\frac{0,8}{7}\) mol

=> \(V_{CO2}\)= \(\frac{0,8}{7}.22,4=2,56\left(l\right)\)

b)

Ta có \(m_{CO2}\)= \(\frac{0,8}{7}.44=\frac{35,2}{7}\left(g\right)\)

\(m_{H2O}\)= \(\frac{0,8}{7}.18=\frac{14,4}{7}\)( g)

\(m_{MgCl2}\)= \(\frac{0,8}{7}.95=\frac{76}{7}\)(g)

=> \(m_{dd_{MgCl2}}\)= (9,6+100)-( \(\frac{49,6}{7}\))= 102,5(g)

=> \(C\%_{MgCl2}\)= \(\frac{\frac{76}{7}}{102,5}\). 100%= 10,6 ( %)

\(C\%_{HCl_{dư}}\)= \(\frac{6,26}{102,5}.100\)=6,107 ( %)

đề có hơi vô lý một tý nha: hỗn hợp thì phải 2 chất trở lên, nhưng trong đề chỉ có mỗi MgCO3....Đề ghi vậy thì anh làm theo đề nha

mHCl=(14.6*100)/100=14.6g=>nHCl=0.4 mol

nMgCO3=9.6/84=4/35\(\approx\) 0.114mol

theo pthh,HCl dư 2/7 mol=>mHCl dư=73/7g

MgCO3+2HCl --> MgCl2 + CO2+H2O

  4/35        0.4              4/35   4/35    

a)Vco2=(4/35)*22.4=2.56l

b)C%HCl dư=(73/7)/100*100=76/7\(\approx\) 10.42%

mMgCl2=4/35*95=76.7g

C%MgCl2=(76.7)/100*100=76/7\(\approx\) 10.85%

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MnO₂+4HCl->MnCl₂+H₂O+Cl₂

0,5---------2------0,5--------0,5---0,5

Cl₂+2NaOH->NaClO+NaCl+H₂O

0,5-----1--------0,5----------0,5------0,5

n _MnO2 =\(\dfrac{43.5}{87}\)=0,5 mol

n _NaOH=5.0,4=2 mol

=>NaOH dư :0,1 mol

=>CM _NaCl= CM _NaClO =\(\dfrac{1}{0,4}\)=2,5M

=>CM _{NaOH dư} =1\(\dfrac{1}{0,4}\)=2,5M

b)

C%_HCl =\(\dfrac{2.36,5}{250}100\)=29,2%

dùng dư 10%

=>C%_HCl=29,2+10=39,2%

PTHH: \(MgO+2HCl\rightarrow MgCl_2+H_2O\)

Ta có: \(n_{MgO}=\dfrac{10}{40}=0,25\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,5\left(mol\right)\\n_{MgCl_2}=0,25\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{HCl}}=\dfrac{0,5}{0,5}=1\left(M\right)\\C_{M_{MgCl_2}}=\dfrac{0,25}{0,5}=0,5\left(M\right)\end{matrix}\right.\)

Ta có: n_MgO = \(\dfrac{10}{40}=0,25\left(mol\right)\)

a. PTHH: MgO + 2HCl ---> MgCl₂ + H₂O

Theo PT: n_HCl = 2.n_MgO = 2.0,25 = 0,5(mol)

Đổi 500ml = 0,5 lít

=> \(C_{M_{HCl}}=\dfrac{0,25}{0,5}=0,5M\)

b. Ta có: \(V_{dd_{MgCl_2}}=10+0,5=10,5\left(lít\right)\)

Theo PT: \(n_{MgCl_2}=n_{MgO}=0,25\left(mol\right)\)

=> \(C_{M_{MgCl_2}}=\dfrac{0,25}{10,5}=0,024M\)

1. K₂O + SO₂ ---> K₂SO₃.

2. K₂O + N₂O₅ ---> 2KNO₃.

3. K₂O + CO₂ ---> K₂CO₃.

4. BaO + SO₂ ---> BaSO₃.

5. BaO + N₂O₅ ---> N₂O + BaO₅.

6. BaO + CO₂ ---> BaCO₃.

7. CuO + CO₂ ---> CuCO₃.

3.

\(n_{Ba^{2+}}=0,5.0,2=0,1\left(mol\right)\Rightarrow\left[Ba^{2+}\right]=\dfrac{0,1}{0,2+0,4}=0,17M\)

\(n_{Cl^-}=2.0,5.0,2=0,2\left(mol\right)\Rightarrow\left[Cl^-\right]=\dfrac{0,2}{0,2+0,4}=0,33M\)

\(n_{Na^+}=2.0,2.0,4=0,16\left(mol\right)\Rightarrow\left[Na^+\right]=\dfrac{0,16}{0,2+0,4}=0,27M\)

\(n_{SO_4^{2-}}=0,2.0,4=0,08\left(mol\right)\Rightarrow\left[SO_4^{2-}\right]=\dfrac{0,08}{0,2+0,4}=0,13M\)

4.

\(n_{H^+}=n_{Cl^-}=2.0,15=0,3\left(mol\right)\Rightarrow\left[Cl^-\right]=\left[H^+\right]=\dfrac{0,3}{0,15+0,05}=1,5M\)

\(n_{Ba^{2+}}=0,05.2,8=0,14\left(mol\right)\Rightarrow\left[Ba^{2+}\right]=\dfrac{0,14}{0,15+0,05}=0,7M\)

\(n_{OH^-}=2.0,05.2,8=0,28\left(mol\right)\Rightarrow\left[OH^-\right]=\dfrac{0,28}{0,15+0,05}=1,4M\)

Theo gt ta có: $n_{Al}=0,2(mol)$

$2Al+6HCl\rightarrow 2AlCl_3+3H_2$

a, Ta có: $n_{H_2}=0,3(mol)\Rightarrow V_{H_2}=6,72(l)$

b, Ta có: $n_{HCl}=0,6(mol)\Rightarrow \%C_{HCl}=10,95\%$

c, Sau phản ứng dung dịch chứa 0,2 mol AlCl3

Suy ra $\%C_{AlCl_3}=13,03\%$

\(C\%_{ddsau}=\dfrac{m_{ct}}{m_{dd}}.100\%=\dfrac{100.7,3\%+200.36,5\%}{100+200}.100=26,77\%\)

Khối lượng riêng \(d=\frac{m}{V}\Rightarrow m=dV\Rightarrow m_{ddNa_2SO_4}=1,55.200=310\left(g\right)\) (*)

\(\begin{cases}m_{CaCl2}=41,6\left(g\right);M_{CaCl2}=111\\mol_{CaCl2}.n_{CaCl2}=\frac{n}{M}=\frac{22,2}{111}=0,2\left(mol\right)\end{cases}\)

Phương trinh:

\(CaCl2+Na_2SO_4\rightarrow CaSO_4\downarrow+2NaCl\)

\(0,02mol\)                \(\rightarrow0,02mol\rightarrow0,04mol\)

\(\begin{cases}n_{NaCl}=0,4\left(mol\right);M_{NaCl}=58,5\\m_{CaCl}=m_{dd}=nM=23,4\left(g\right)\end{cases}\) (**)

\(\Rightarrow m_{dd}=m_{ddN\text{à}S\text{\text{O4 } }}+m_{CaCl2}-m_{CaS\text{O4}}\)

Giải hệ thu được: \(m_{CaS\text{O4}}=27,2\left(g\right)\)

Thay (*) (**) (***) \(\Rightarrow m_{dd}=324,4\left(g\right)\)

Vậy nồng độ là" \(7,21\%\)

a) \(n_{CH_3COOH}=\dfrac{100.12\%}{60}=0,2\left(mol\right)\)

PTHH: CH₃COOH + NaHCO₃ --> CH₃COONa + CO₂ + H₂O

                 0,2-------->0,2----------->0,2--------->0,2

=> m_NaHCO3 = 0,2.84 = 16,8 (g)

=> \(m_{dd.NaHCO_3}=\dfrac{16,8.100}{8,4}=200\left(g\right)\)

b) m_CH3COONa = 0,2.82 = 16,4 (g)

m_{dd sau pư} = 100 + 200 - 0,2.44 = 291,2 (g)

=> \(C\%_{dd.muối}=\dfrac{16,4}{291,2}.100\%=5,632\%\)

\(m_{ct}=\dfrac{12.100}{100}=12\left(g\right)\)

\(n_{CH3COOH}=\dfrac{12}{60}=0,2\left(mol\right)\)

Pt : \(CH_3COOH+NaHCO_3\rightarrow CH_3COONa+CO_2+H_2O|\)

                 1                   1                       1                1           1

               0,2                 0,2                    0,2              0,2

a) \(n_{NaHCO3}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

⇒ \(m_{NaHCO3}=0,2.84=16,8\left(g\right)\)

\(m_{ddNaHCO3}=\dfrac{16,8.100}{8,4}=200\left(g\right)\)

b) \(n_{CH3COONa}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

⇒ \(m_{CH3COONa}=0,2.82=16,4\left(g\right)\)

\(m_{ddspu}=100+200-\left(0,2.44\right)=291,2\left(g\right)\)

\(C_{CH3COONa}=\dfrac{16,4.100}{291,2}=5,63\)⁰/₀

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