1)

a)

$CaO + 2HCl \to CaCl_2 + H_2O$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$

$n_{CaCO_3} = n_{CO_2} = 0,2(mol)$
$n_{CaCl_2} = 0,3(mol)$

Suy ra: 

$n_{CaO} = 0,3 - 0,2 = 0,1(mol)$
$\%m_{CaO} = \dfrac{0,1.56}{0,1.56 + 0,2.100}.100\% = 21,875\%$

$\%m_{CaCO_3} = 78,125\%$

b) 

$m_{dd} = 0,1.56 + 0,2.100 + 50 - 0,2.44 = 66,8(gam)$
$C\%_{CaCl_2} = \dfrac{33,3}{66,8}.100\% = 49,85\%$

Câu 4 : 

a)

Gọi $n_{Fe} = a(mol) ; n_{MgO} = b(mol)$

Suy ra: $56a + 40b = 19,2(1)$

$Fe + 2HCl \to FeCl_2 + H_2$
$MgO + 2HCl \to MgCl_2 + H_2O$
Theo PTHH : $n_{HCl} = 2a + 2b = 0,4.2 = 0,8(2)$
Từ (1)(2) suy ra a = b = 0,2

$\%m_{Fe} = \dfrac{0,2.56}{19,2}.100\% = 58,33\%$
$\%m_{MgO} = 100\% -58,33\% = 41,67\%$

b)

$n_{FeCl_2} = a = 0,2(mol)$
$n_{MgCl_2} = b = 0,2(mol)$

$m_{muối} = 0,2.127 + 0,2.95 = 44,4(gam)$

Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\n_{CaCl_2}=\dfrac{33,3}{111}=0,3\left(mol\right)\end{matrix}\right.\)

PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2\uparrow+H_2O\)

                    0,2_____0,4_____0,2____0,2_____0,2  (mol)

            \(CaO+2HCl\rightarrow CaCl_2+H_2O\)

                 0,1_____0,2_____0,1____0,1    (mol)

Ta có: \(\left\{{}\begin{matrix}m_{CaO}=0,1\cdot56=5,6\left(g\right)\\m_{CaCO_3}=0,2\cdot100=20\left(g\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{CaO}=\dfrac{5,6}{5,6+20}\cdot100\%=21,875\%\\\%m_{CaCO_3}=78,125\%\end{matrix}\right.\)

Mặt khác: \(m_{CO_2}=0,2\cdot44=8,8\left(g\right)\)

\(\Rightarrow m_{dd\left(sau.p/ứ\right)}=m_{CaO}+m_{CaCO_3}+m_{ddHCl}-m_{CO_2}=66,8\left(g\right)\)

\(\Rightarrow C\%_{CaCl_2}=\dfrac{33,3}{66,8}\cdot100\%\approx49,85\%\)

nCO2=\(\dfrac{4,48}{22,4}=0,2\) mol

nCaCl₂=\(\dfrac{33,3}{111}=0,3\)

CaCO₂ + 2HCl → CaCl₂ + CO₂ + H₂O

  0,2           ←         0,2    ← 0,2

CaO + 2HCl  → CaCl₂ + H₂O     

 0,1              ←    0,1

a)  % CaO=\(\dfrac{0,1.56}{0,1.56+0,2.100}.100\%=21,875\%\)    

   % CaCO₃ =100% - 21,875%= 78,125%

b) a = mCaO+mCaCO₃ =0,1.56+0,2.100=25,6g

mdd sau pư= a + mddHCl - mCO2

                  = 25,6 + 50 - 0,2.44=66,8g

C%CaCl₂=\(\dfrac{33,3}{66,8}.100\%\simeq49,85\%\)

$n_{CaO} = 0,2(mol)$

$n_{HCl} = 0,2V(mol) ; n_{HNO_3} = 0,2V(mol)$
$CaO + 2HCl \to CaCl_2 + H_2O$
$CaO + 2HNO_3 \to Ca(NO_3)_2 + H_2O$

Theo PTHH : 

$n_{axit} = 0,2V + 0,2V = 2n_{CaO} = 0,4 \Rightarrow V = 1(lít)$

Theo PTHH : 

$n_{H_2O} = \dfrac{1}{2}n_{axit} = 0,2(mol)$

Bảo toàn khối lượng : 

$m_{muối} = 11,2 + 0,2.63 + 0,2.36,5 - 0,2.18 = 27,5(gam)$

\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ PTHH:Zn+2HCl\rightarrow ZnCl_2+H_2\\ n_{ZnCl_2}=n_{Zn}=n_{H_2}=0,15\left(mol\right);n_{HCl}=2.0,15=0,3\left(mol\right)\\ a,m=m_{Zn}=0,15.65=9,75\left(g\right)\\ b,C_{MddHCl}=\dfrac{0,3}{0,15}=0,2\left(l\right)\\ c,m_{ZnCl_2}=0,15.136=20,4\left(g\right)\)

a+b) PTHH: \(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\uparrow\)

Ta có: \(n_{CaCO_3}=\dfrac{10}{100}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{HCl}=0,2\left(mol\right)\\n_{CO_2}=0,1\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{HCl}=0,2\cdot36,5=7,3\left(g\right)\\V_{CO_2}=0,1\cdot22,4=2,24\left(l\right)\end{matrix}\right.\)

c) Ta có: \(\left\{{}\begin{matrix}n_{CO_2}=0,1\left(mol\right)\\n_{NaOH}=\dfrac{50\cdot40\%}{40}=0,5\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\) Tạo muối trung hòa, bazơ dư, tính theo CO₂

Bảo toàn Cacbon: \(n_{Na_2CO_3}=n_{CO_2}=0,1\left(mol\right)\) \(\Rightarrow m_{Na_2CO_3}=0,1\cdot106=10,6\left(g\right)\)

a)

$n_{CO_2} = \dfrac{0,224}{22,4} = 0,01(mol)$
\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)

0,01             0,02                        0,01                            (mol)

$C_{M_{HCl}} = \dfrac{0,02}{0,1} = 0,2M$

b)

$\%m_{CaCO_3} = \dfrac{0,01.100}{1,5}.100\% = 66,67\%$

$\%m_{CaSO_4} = 100\% -66,67\% = 33,33\%$

CaCO3 + 2HCl → CaCl2 + CO2 ↑ + H2O

1mol →                               1mol

Vì 1 < < 2 ⇒Tạo thành 2 muối

CO2 + NaOH → NaHCO3

  x          x               x            (mol)

CO2 + 2NaOH → Na2CO3 + H2O

  y         2y                y          (mol)

Ta có hệ phương trình: ⇒ x=y=0,5mol

= 84.0,5 = 42 (gam); = 106.0,5 = 53 (gam)

Khối lượng muối thu được:

mmuối =  mNaHCO3 +mNa2CO3  =  42 + 53 = 95 (gam).

Đặt số mol Na2CO3, NaHCO3 lần lượt là x, y mol → 106x + 84y= 100 (gam) 2NaHCO3 → Na2CO3+ CO2+ H2O ymol y/2 mol → mNa2CO3= (x+y/2).106= 69 gam Giải hệ trên ta có x= 8/53 mol; y= 1mol → %mNa2CO3= 16%; %mNaHCO3= 84%