Gọi số mol CuO, Fe_xO_y là a, b (mol)

=> 80a + (56x + 16y)b = 24 (1)

PTHH: CuO + H₂ --t^o--> Cu + H₂O

              a--------------->a

            Fe_xO_y + yH₂ --t^o--> xFe + yH₂O

               b----------------->bx

=> 64a + 56bx = 17,6 (2)

PTHH: Fe + 2HCl --> FeCl₂ + H₂

            bx------------------->bx

=> bx = \(\dfrac{4,48}{22,4}=0,2\) (3)

(2)(3) => a = 0,1 (mol)

(1) => 56bx +16by = 16

=> by = 0,3 (mol)

=> \(\dfrac{bx}{by}=\dfrac{0,2}{0,3}\Rightarrow\dfrac{x}{y}=\dfrac{2}{3}\) 

=> CTHH: Fe₂O₃

Gọi nFe=a(mol);nM=b(mol)⇒56a+Mb=9,6(1)


nH2=a+b=0,2⇒a=0,2−b

Ta có : 

⇒MM>4,60,25=18,4

+) Nếu 

Ta có : 

Suy ra a = 0,15 ; b = 0,05

mFe=0,15.56=8,4(gam)
mMg=0,05.24=1,2(gam)

+) Nếu 


Suy ra a = b = 0,1

mCa=0,1.40=4(gam)
mFe=0,1.56=5,6(gam)

Hỗn hợp 2 kim loại thu được sau khi khử 2 oxit =17,6 gam gồm :Fe và Cu.pt:Fe+2HCl--->FeCl2+H2, theo pt trên nFe=nH2=0,2 mol=>mFe=11,2 gam=>mCu=17,6-11,2=6,4=>nCu=0,1=>nCuO=nCu=0,1=>mCuO=8 gam=>mFexOy=24-8=16 gam.khối lượng Fe trong oxit=11,2 gam =>mO(FexOy)=4,8 gam.ta có: x:y=11,2/56:4,8:16=2:3=> CTPT của oxit sắt :Fe2O3.

Pt: CuO + H2 --to--> Cu + H2O

....0,1 mol<----------0,1 mol

......FexOy + yH2 --to--> xFe + yH2O

......0,2x0,2x mol<------------0,2 mol

......Fe + 2HCl --> FeCl2 + H2

0,2 mol<---------------------0,2 mol

nH2 = 4,4822,4=0,24,4822,4=0,2 mol

mFe = 0,2 . 56 = 11,2 (g)

mCu = mkim loại - mFe = 17,6 - 11,2 = 6,4 (g)

=> nCu = 6,464=0,16,464=0,1 mol

mCuO = 0,1 . 80 = 8 (g)

=> mFexOy = mhh - mCuO = 24 - 8 = 16 (g)

Ta có: 0,2x.(56x+16y)=160,2x.(56x+16y)=16

⇔11,2+3,2yx=16⇔11,2+3,2yx=16

⇔3,2yx=4,8⇔3,2yx=4,8

⇔4,8x=3,2y⇔4,8x=3,2y

⇔xy=3,24,8=23⇔xy=3,24,8=23

Vậy CTHH của oxit sắt: Fe2O3

Ta có:
mO(trong oxit) = 24 - 17.6 = 6.4 => nO = 0.4 (1)
nH2 = 0.2
2Fe + 2HCl --> FeCl2 + H2
0.4<------------------------0.2
=> nFe = 0.4 (2)
(1) (2) => FeO

\(Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=\dfrac{0,448}{22,4}=0,02\left(mol\right)\\ a,\%m_{Fe}=\dfrac{0,02.56}{4,36}.100\approx25,688\%\\ \Rightarrow\%m_{Ag}\approx74,312\%\\ b,Ta.thấy:2,18=\dfrac{1}{2}.4,36\\ \Rightarrow m_{hh\left(câuB\right)}=\dfrac{1}{2}.m_{hh\left(câuA\right)}\\ n_{Fe}=\dfrac{0,02}{2}=0,01\left(mol\right)\\ n_{Ag}=\dfrac{2,18-0,01.56}{108}=0,015\left(mol\right)\\ 2Fe+3Cl_2\rightarrow\left(t^o\right)2FeCl_3\\ 2Ag+Cl_2\rightarrow\left(t^o\right)2AgCl\\ n_{Cl_2}=\dfrac{3}{2}.n_{Fe}+\dfrac{1}{2}.n_{Ag}=\dfrac{3}{2}.0,01+\dfrac{1}{2}.0,015=0,0225\left(mol\right)\\ \Rightarrow V_{Cl_2\left(đktc\right)}=0,0225.22,4=0,504\left(l\right)\)

Bài 24:

\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\\ PTHH:A+2HCl\rightarrow ACl_2+H_2\uparrow\)

Theo pthh: n_A = n_H2 = 0,15 (mol)

=> M_A = \(\dfrac{3,6}{0,15}=24\left(\dfrac{g}{mol}\right)\)

=> A là Mg

Bài 25:

\(n_{H_2}=\dfrac{10,08}{22,4}=0,45\left(mol\right)\\ PTHH:2A+6HCl\rightarrow2ACl_3+3H_2\uparrow\\ Mol:0,3\leftarrow0,9\leftarrow0,3\leftarrow0,45\\ \rightarrow\left\{{}\begin{matrix}M_A=\dfrac{8,1}{0,3}=27\left(\dfrac{g}{mol}\right)\Rightarrow A:Al\\m_{HCl}=0,9.36,5=32,85\left(g\right)\end{matrix}\right.\)

Bài 24.

\(n_{H_2}=\dfrac{3,36}{22,4}=0,15mol\)

\(n_A=\dfrac{3,6}{M_A}\) mol

\(A+2HCl\rightarrow ACl_2+H_2\)

0,15                           0,15   ( mol )

\(\Rightarrow\dfrac{3,6}{M_A}=0,15mol\)

\(\Leftrightarrow M_A=24\) ( g/mol )

=> A là Magie ( Mg )

Bài 25.

\(n_{H_2}=\dfrac{10,08}{22,4}=0,45mol\)

\(n_A=\dfrac{8,1}{M_A}\) mol

\(2A+6HCl\rightarrow2ACl_3+3H_2\)

0,3                                0,45  ( mol )

\(\Rightarrow\dfrac{8,1}{M_A}=0,3\)

\(\Leftrightarrow M_A=27\) g/mol

=> A là nhôm ( Al )

úi ùi ms lm dc 2 ceo:>

1.

a,\(BaCl_2+H_2SO_4\rightarrow BaSO_4\downarrow+2HCl\)

b, \(3Cu+8HNO_3\rightarrow3Cu\left(NO_3\right)_2+2NO\uparrow+H_2O\)

c, \(2NaOH+Ca\left(HSO_3\right)_2\rightarrow CaSO_3\downarrow+Na_2SO_3+2H_2O\)

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\uparrow\)

 0,1                                 0,1

\(m_{Fe}=0,1\cdot56=5,6\)\(\Rightarrow\%_{Fe}=\dfrac{5,6}{10}\cdot100\%=56\%\)

\(\%Cu=100\%-56\%=44\%\)