\(a.BTNT\left(H\right):n_{HCl}=2n_{H_2}=0,65\left(mol\right)\\ \Rightarrow CM_{HCl}=\dfrac{0,65}{0,5}=1,3M\\ b.2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ Đặt:\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}\dfrac{3}{2}x+y=0,325\\27x+56y=9,65\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}x=0,15\\y=0,1\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{Al}=4,05\left(g\right)\\m_{Fe}=5,6\left(g\right)\end{matrix}\right.\)

Đặt hóa trị của M là x(x>0)

\(n_{O_2}=\dfrac{4,8}{32}=0,15(mol)\\ n_{H_2}=\dfrac{3,36}{22,4}=0,15(mol)\\ a,PTHH:4M+xO_2\xrightarrow{t^o}2M_2O_x\\ 2M+2xHCl\to 2MCl_x+xH_2\\ \Rightarrow \Sigma n_{M}=\dfrac{0,6}{x}+\dfrac{0,3}{x}=\dfrac{0,9}{x}\\ \Rightarrow M_{M}=\dfrac{8,1}{\dfrac{0,9}{x}}=9x(g/mol)\\ \text {Thay }x=3 \Rightarrow M_{M}=27(g/mol)\\ \text {Vậy M là nhôm (Al)}\)

\(b,\text {Dung dịch B là }AlCl_3\\ n_{Al}=\dfrac{8,1}{27}=0,3(mol)\\ \Rightarrow n_{AlCl_3}=n_{Al}=0,3(mol)\\ n_{Al(OH)_3}=\dfrac{15,6}{78}=0,2(mol)\\ PTHH:3NaOH+AlCl_3\to Al(OH)_3\downarrow +3NaCl\\ \text {Vì }\dfrac{n_{AlCl_3}}{1}>\dfrac{n_{Al(OH)_3}}{1} \text {nên } AlCl_3 \text { dư}\\ \Rightarrow n_{NaOH}=3n_{Al(OH)_3}=0,6(mol)\\ \Rightarrow V_{dd_{NaOH}}=0,6.2=1,2(l)\)

Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)

PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)

____0,1______0,2_____0,1____0,1 (mol)

a, \(C_{M_{HCl}}=\dfrac{0,2}{0,15}=\dfrac{4}{3}\left(M\right)\)

\(V_{H_2}=0,1.22,4=2,24\left(l\right)\)

b, \(FeCl_2+2NaOH\rightarrow2NaCl+Fe\left(OH\right)_2\)

Theo PT: \(n_{NaOH}=2n_{FeCl_2}=0,2\left(mol\right)\)

\(\Rightarrow V_{NaOH}=\dfrac{0,2}{2}=0,1\left(l\right)\)

a, \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

PTHH: Fe + 2HCl → FeCl₂ + H₂

Mol:     015    0,3         0,15     0,15

b, \(m_{Fe}=0,15.56=8,4\left(g\right)\)

    \(m_{FeCl_2}=0,15.127=19,05\left(g\right)\)

c, \(C_{M_{ddHCl}}=\dfrac{0,3}{0,05}=6M\)

Chọn đáp án C

Xét trong 100 ml dung dịch X: 2H⁺ + CO₃^2– → CO₂ + H₂O ⇒ n_CO3^2– = n_khí = 0,1 mol.

Ba²⁺ + CO₃^2– → BaCO₃ || Ba²⁺ + SO₄^2– → BaSO₄ ⇒ n_SO4^2– = (43 - 0,1 × 197) ÷ 233 = 0,1 mol.

NH₄⁺ + OH– → NH₃ + H₂O ⇒ n_NH4⁺ = n_NH3 = 0,4 ÷ 2 = 0,2 mol.Bảo toàn điện tích: n_Na+ = 0,2 mol.

⇒ m_{muối trong 300ml X} = 3 × (0,2 × 23 + 0,2 × 18 + 0,1 × 60 + 0,1 × 96) = 71,4(g) ⇒ chọn C.

Đáp án đúng : C

a. PTHH : Mg + 2HCl ➝ MgCl₂ + H₂ (1)

b. theo bài : nH₂ = 3,36 : 22,4 = 0,15 (mol)

theo (1) nMg = nH₂ = 0,15 (mol)

➞ mMg = 0,15 ✖ 24 = 3,6 (g)

➞ %mMg = (3,6 : 5)✖100 = 72%

➞ %mCu = 100% - 72% = 28%

c. theo (1) nHCl = 2nH₂ = 2✖0,15 = 0,3 (mol)

mHCl = 0,3✖36,5 = 10,95(g)

➜mddHCl = (10,95✖100):14,6 = 75(g)

d. dung dịch Y : MgCl₂

mdd_(spư)= 3,6+75-0,3 = 78,3(g)

theo (1) nMgCl₂ = nH₂ = 0,15(mol)

mMgCl₂ = 0,15✖95 = 14,25(g)

C%MgCl₂ = (14,25 : 78,3)✖100 = 18,199%

a) \(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

PTHH: Fe + 2HCl --> FeCl₂ + H₂

____0,15<--0,3<--------------0,15

=> m_Fe = 0,15.56 = 8,4 (g)

=> \(\left\{{}\begin{matrix}\%Fe=\dfrac{8,4}{21,2}.100\%=39,62\%\\\%Cu=\dfrac{21,2-8,4}{21,2}.100\%=60,38\%\end{matrix}\right.\)

b) m_HCl = 0,3.36,5 = 10,95(g)

=> \(m_{ddHCl}=\dfrac{10,95.100}{3,65}.100\%=300\left(g\right)\)