Đáp án C

C2H4+Br2->C2H4Br2

0,1---0,1

n Br=0,1 mol

=>%VC2H4=\(\dfrac{0,1.22,4}{3,2}100=70\%\)

\(V_{C_2H_6}=13,44-6,72=6,72\left(l\right)\)

=> \(n_{C_2H_6}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

\(n_{C_2Ag_2}=\dfrac{24}{240}=0,1\left(mol\right)\)

=> \(n_{C_2H_2}=0,1\left(mol\right)\)

=> \(n_{C_2H_4}=\dfrac{13,44}{22,4}-0,3-0,1=0,2\left(mol\right)\)

=> \(\left\{{}\begin{matrix}\%m_{C_2H_6}=\dfrac{0,3.30}{0,3.30+0,2.28+0,1.26}.100\%=52,326\%\\\%m_{C_2H_4}=\dfrac{0,2.28}{0,3.30+0,2.28+0,1.26}.100\%=32,558\%\\\%m_{C_2H_2}=\dfrac{0,1.26}{0,3.30+0,2.28+0,1.26}.100\%=15,116\%\end{matrix}\right.\)

a, \(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

\(n_{Br_2}=\dfrac{16}{160}=0,1\left(mol\right)\)

Theo PT: \(n_{C_2H_2}=\dfrac{1}{2}n_{Br_2}=0,05\left(mol\right)\)

\(\Rightarrow V_{C_2H_2}=0,05.22,4=1,12\left(l\right)\)

\(\Rightarrow V_{CH_4}=3,36-1,12=2,24\left(l\right)\)

b, \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)

\(n_{CH_4}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Theo PT: \(n_{O_2}=2n_{CH_4}+\dfrac{5}{2}n_{C_2H_2}=0,325\left(mol\right)\)

\(\Rightarrow V_{O_2}=0,325.22,4=7,28\left(l\right)\Rightarrow V_{kk}=5V_{O_2}=36,4\left(l\right)\)

Theo PT: \(n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=0,2\left(mol\right)\)

\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)

\(\Rightarrow n_{CaCO_3}=n_{CO_2}=0,2\left(mol\right)\Rightarrow m_{CaCO_3}=0,2.100=20\left(g\right)\)

\(n_{Br_2}=\dfrac{8}{160}=0,05mol\)

\(\Rightarrow n_{C_2H_4}=0,05mol\Rightarrow m_{C_2H_4}=1,4g\)

\(\%m_{C_2H_4}=\dfrac{1,4}{2}\cdot100\%=70\%\)

\(\%m_{CH_4}=100\%-70\%=30\%\)

Dẫn 2 khí qua dung dịch nước brom chỉ có C 2 H 4 phản ứng

PTHH: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Ta có: \(n_{Br_2}=\dfrac{4}{160}=0,025\left(mol\right)=n_{C_2H_4}\)

\(\Rightarrow V_{C_2H_4}=0,025\cdot22,4=0,56\left(l\right)\) \(\Rightarrow V_{CH_4}=2,8\left(l\right)\)

nhh = 5.6/22.4 = 0.25(mol) 

nAg2C2 = nC2H2 = 24/240 = 0.1 (mol) 

nBr2 = 0.3 (mol) 

=> nC2H4 = 0.3 - 0.1*2 = 0.1 (mol) 

nCH4 = 0.25 - 0.1 - 0.1 = 0.05 (mol) 

mCH4 = 0.05*16 = 0.8 (g) 

mC2H2 = 0.1*26 = 2.6 (g) 

mC2H4 = 0.1*28 = 2.8 (g)

mhh = 0.8 + 2.6 + 2.8 = 6.2 (g)  

%CH4 = 0.8/6.2 * 100% = 12.9%

%C2H4 = 2.8/ 6.2 * 100% = 45.16%

%C2H2 = 41.94%

\(a,n_{hhkhí\left(C_2H_4,C_2H_2\right)}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\\ n_{Br_2}=\dfrac{80}{160}=0,5\left(mol\right)\\ Gọi\left\{{}\begin{matrix}n_{C_2H_4}=a\left(mol\right)\\n_{C_2H_2}=b\left(mol\right)\end{matrix}\right.\\ PTHH:C_2H_4+Br_2\rightarrow C_2H_4Br_2\\ Mol:a\rightarrow a\\ C_2H_2+2Br_2\rightarrow C_2H_2Br_4\\ Mol:b\rightarrow2b\\ Hệ.pt\left\{{}\begin{matrix}a+b=0,3\\a+2b=0,5\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}a=0,1\left(mol\right)\\b=0,2\left(mol\right)\end{matrix}\right.\\ \%V_{C_2H_4}=\dfrac{0,1}{0,3}=33,33\%\\ \%V_{C_2H_2}=100\%-33,335=66,67\%\)

\(b,PTHH:\\ C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\\ Mol:0,1\rightarrow0,3\rightarrow0,2\\ 2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\\ Mol:0,2\rightarrow0,25\rightarrow0,4\\ n_{CO_2}=0,2+0,4=0,6\left(mol\right)\\ PTHH:Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\\ Mol:0,6\rightarrow0,6\rightarrow0,6\\ m_{CaCO_3}=0,6.100=60\left(g\right)\)