Anh bổ sung câu c)

\(C_{MddNa_2SO_4}=\dfrac{0,25}{0,09879+0,5}=0,4175\left(M\right)\)

Ta có: \(n_{Na_2O}=\dfrac{3,1}{62}=0,05\left(mol\right)\)

PTHH: Na₂O + H₂O ---> 2NaOH (1)

a. Theo PT₍₁₎: \(n_{NaOH}=2.n_{Na_2O}=2.0,05=0,1\left(mol\right)\)

=> \(C_{M_{NaOH}}=\dfrac{0,1}{2}=0,05M\)

b. PTHH: 2NaOH + H₂SO₄ ---> Na₂SO₄ + 2H₂O

Theo PT: \(n_{H_2SO_4}=\dfrac{1}{2}.n_{NaOH}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)

=> \(m_{H_2SO_4}=0,05.98=4,9\left(g\right)\)

Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{4,9}{m_{dd_{H_2SO_4}}}.100\%=20\%\)

=> \(m_{dd_{H_2SO_4}}=24,5\left(g\right)\)

\(n_{K_2O}=\dfrac{23.5}{94}=0.25\left(mol\right)\)

\(K_2O+H_2O\rightarrow2KOH\)

\(0.25...................0.5\)

\(C_{M_{KOH}}=\dfrac{0.5}{0.5}=1\left(M\right)\)

\(2KOH+H_2SO_4\rightarrow K_2SO_4+H_2O\)

\(0.5............0.25............0.25\)

\(m_{dd_{H_2SO_4}}=\dfrac{0.25\cdot98}{20\%}=122.5\left(g\right)\)

\(V_{dd_{H_2SO_4}}=\dfrac{122.5}{1.14}=107.5\left(ml\right)=0.1075\left(l\right)\)

\(C_{M_{K_2SO_4}}=\dfrac{0.25}{0.1075+0.5}=0.4\left(M\right)\)

nK2O = 23,5 : 94 = 0,25 (mol)
Vdd = 500ml = 0,5l

PT K2O + H2O ==> 2KOH
TPT 1 1 2 (mol)
TĐB: 0,25 --> 0,5 (mol)

a) C_{M KOH} = 0,5 : 0,5 = 1(M)

b) PT: H2SO4 + 2KOH ==> K2SO4 + 2H2O
TPT: 1 2 1 2 (mol)

a.

\(n_{K_2O}=\dfrac{m}{M}=\dfrac{23,5}{94}=0,25\left(mol\right)\\ PT:\\ K_2O+H_2O\rightarrow2KOH\)

Theo pt: \(n_{KOH}=2n_{K_2O}=0,5\left(mol\right)\)

\(\Rightarrow C_{M\left(KOH\right)}=\dfrac{n}{V}=\dfrac{0,5}{0,5}=1\left(M\right)\)

b.

\(PT:\\ 2KOH+H_2SO_4\rightarrow K_2SO_4+2H_2O\)(2)

Theo pt, \(n_{H_2SO_4}=\dfrac{1}{2}n_{KOH}=0,25\left(mol\right)\)

\(\Rightarrow V_{ddH_2SO_4}=\dfrac{m_{dd}}{D}=\dfrac{n.M:C\%}{D}=\dfrac{0,25.98:20\%}{1,14}=\)107,46(ml)

c.

dd spư có chất tan là K₂SO₄

Theo pt (2), \(n_{K_2SO_4}=\dfrac{1}{2}n_{KOH}=0,25\left(mol\right)\)

=> C_M = \(\dfrac{n}{V}=\dfrac{0,25}{0,107}=2,336\left(M\right)\)

\(n_{Na_2O}=\dfrac{15,5}{62}=0,25\left(mol\right)\\ PTHH:Na_2O+H_2O\rightarrow2NaOH\\ n_{NaOH}=2.0,25=0,5\left(mol\right)\\ a,C_{MddNaOH}=\dfrac{0,5}{0,5}=1\left(M\right)\\ b,2NaOH+H_2SO_4\rightarrow Na_2SO_4+2H_2O\\ n_{H_2SO_4}=n_{Na_2SO_4}=\dfrac{0,5}{2}=0,25\left(mol\right)\\ m_{H_2SO_4}=0,25.98=24,5\left(g\right)\\ m_{ddH_2SO_4}=\dfrac{24,5.100}{20}=122,5\left(g\right)\\ V_{ddH_2SO_4}=\dfrac{122,5}{1,14}\approx107,456\left(ml\right)\\ c,V_{ddsau}=V_{ddNaOH}+V_{ddH_2SO_4}\approx0,5+0,107456=0,607456\left(l\right)\\C_{MddNa_2SO_4}\approx\dfrac{ 0,25}{0,607456}\approx0,411552\left(M\right)\)

n_{CaO = \(\dfrac{m}{M}=\dfrac{0.28}{40}=0,007\left(mol\right)\)}

PTHH : CaO + H₂O ---> Ca(OH)₂ 

            0,007                   0,007

\(C_M=\dfrac{n}{V}=\dfrac{0,007}{0,25}=0,028\left(M\right)\)

\(m_{Ca\left(OH\right)_2}=n.M=0,007.74=0,518\left(g\right)\)

a, PT: \(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

b, Ta có: \(n_{Fe}=\dfrac{19,6}{56}=0,35\left(mol\right)\)

Theo PT: \(n_{H_2}=n_{Fe}=0,35\left(mol\right)\Rightarrow V_{H_2}=0,35.22,4=7,84\left(l\right)\)

c, \(n_{H_2SO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow C_{M_{H_2SO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)

d, \(n_{FeSO_4}=n_{Fe}=0,35\left(mol\right)\Rightarrow m_{FeSO_4}=0,35.152=53,2\left(g\right)\)

e, \(C_{M_{FeSO_4}}=\dfrac{0,35}{0,2}=1,75\left(M\right)\)

d, \(n_{H_2SO_4}=0,25.1,6=0,4\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{n_{Fe}}{1}< \dfrac{n_{H_2SO_4}}{1}\), ta được H₂SO₄ dư.

Theo PT: \(n_{H_2SO_4\left(pư\right)}=n_{Fe}=0,35\left(mol\right)\)

\(\Rightarrow n_{H_2SO_4\left(dư\right)}=0,4-0,35=0,05\left(mol\right)\)

\(\Rightarrow m_{H_2SO_4\left(dư\right)}=0,05.98=4,9\left(g\right)\)

\(a) m_{dd} = \dfrac{6}{15\%} = 40(gam)\\ b) V_{dd} = \dfrac{m_{dd}}{D} = \dfrac{40}{1,15} = 34,78(ml)\\ c)n_{CuSO_4} = \dfrac{6}{160} = 0,0375(mol)\\ C_{M_{CuSO_4}} = \dfrac{0,0375}{0,03478}=1,078M\)

1)

$n_{Na_2O} = \dfrac{6,2}{62} = 0,1(mol)$
$Na_2O + H_2O \to 2NaOH$
$n_{NaOH} = 2n_{Na_2O} = 0,2(mol)$
$m_{dd} = 6,2 + 193,8 = 200(gam) \Rightarrow C\%_{NaOH} = \dfrac{0,2.40}{200}.100\% = 4\%$

2) 

$n_{K_2O} = \dfrac{23,5}{94} = 0,25(mol)$
$K_2O + H_2O \to 2KOH$
$n_{KOH} = 2n_{K_2O} = 0,5(mol) \Rightarrow C_{M_{KOH}} = \dfrac{0,5}{0,5} = 1M$

3) $n_{Na_2O} = \dfrac{12,4}{62} = 0,2(mol)$
$Na_2O + H_2O \to 2NaOH$
$n_{NaOH} = 2n_{Na_2O} = 0,4(mol)$
$C_{M_{NaOH}} = \dfrac{0,4}{0,5} =0,8M$

4)

$Na_2SO_3 + 2HCl \to 2NaCl +S O_2 + H_2O$
Theo PTHH : 

$n_{SO_2} = n_{Na_2SO_3} = \dfrac{12,6}{126} = 0,1(mol)$
$V_{SO_2} = 0,1.22,4 = 2,24(lít)$

5) $n_{CaO} = \dfrac{5,6}{56} = 0,1(mol)$

$CaO + 2HCl \to CaCl_2 + H_2O$

Theo PTHH : 

$n_{HCl} = 2n_{CaO} = 0,2(mol) \Rightarrow m_{dd\ HCl} = \dfrac{0,2.36,5}{14,6\%} = 50(gam)$

Bài 1 : 

\(n_{Na2O}=\dfrac{6,2}{62}=0,1\left(mol\right)\)

Pt : \(Na_2O+H_2O\rightarrow2NaOH|\)

           1          1              2

          0,1                      0,2

\(n_{NaOH}=\dfrac{0,1.2}{1}=0,2\left(mol\right)\)

⇒ \(m_{NaOH}=0,2.40=8\left(g\right)\)

\(m_{ddspu}=6,2+193,8=200\left(g\right)\)

\(C_{ddNaOH}=\dfrac{8.100}{200}=4\)⁰/₀

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