a)

$BaCl_2 + H_2SO_4 \to BaSO_4 + 2HCl$
$n_{BaCl_2} = 0,1 < n_{H_2SO_4} = 0,2$ nên $H_2SO_4$ dư

$n_{BaSO_4} = n_{BaCl_2} = 0,1(mol)$
$m_{BaSO_4} = 0,1.233 = 23,3(gam)$

b)

A gồm :

$HCl : 0,1.2 = 0,2(mol)$
$H_2SO_4\ dư : 0,2 - 0,1 = 0,1(mol)$
$V_{dd} = 0,1 + 0,1= 0,2(lít)$

$C_{M_{HCl}} = \dfrac{0,2}{0,2} = 1M$
$C_{M_{H_2SO_4}} = \dfrac{0,1}{0,2} = 0,5M$

c)

$2NaOH + H_2SO_4 \to Na_2SO_4 + 2H_2O$
$n_{NaOH} = 2n_{H_2SO_4\ dư} = 0,2(mol)$
$m_{dd\ NaOH} = \dfrac{0,2.40}{15\%} = 53,33(gam)$

a)nHCl= 0,1 , nNaOh=0,4 khi phân li ra ta thu được các ion; H+, Cl- Na+, OH-    Vdung dịch sau = 0,1+0,4=0,5(l)

nH+=nCl-=0,1 [H+]=[Cl-]=0,1/0,5=0,2 (M)

nNa+=nOH-=0,4 [Na+]=[OH-]=0,4/0,5=0,8

b)nH+=0,1 nOH-=0,4 --> OH- dư --> nOHdư=0,4-0,1=0,3 --> [OHdư ]=0,3/0,5=0,6 --> pOh=0,23--> ph=14-0,23=13,77

Có \(m_M=m_{Na}+m_{Cl}+m_{SO_4}=1,38+m_{Cl}+m_{SO_4}=3,76\)

\(\Rightarrow m_{Cl}+m_{SO_4}=2,38\)

\(\Rightarrow35,5n_{HCl}+96n_{H_2SO_4}=2,38\)

Lại có : \(n_O=n_{NaOH}=0,06\left(mol\right)\)

BtH : \(n_H=2n_{H_2O}=2n_O=n_{H\left(NaOH\right)}+n_{H\left(HCl\right)}+2n_{H\left(H_2SO_4\right)}\)

\(\Rightarrow n_{HCl}+2n_{H_2SO_4}=0,06\)

\(\Rightarrow n_{HCl}=0,04\left(mol\right)\)

\(\Rightarrow C_{MHCl}=1M\)

a) \(m_{ddAl_2\left(SO_4\right)_3}=200\cdot1,2=240\left(g\right)\)

    \(\Rightarrow m_{Al_2\left(SO_4\right)_3}=\dfrac{240\cdot28,5}{100}=68,4\left(g\right)\)

    \(\Rightarrow n_{Al_2\left(SO_4\right)_3}=0,2mol\)

    \(\Rightarrow\left\{{}\begin{matrix}n_{Al^{3+}}=2n_{Al_2\left(SO_4\right)_3}=0,4mol\\n_{SO^{2-}_4}=0,6mol\end{matrix}\right.\)

b) \(n_{HCl}=0,1\cdot3=0,3mol\) \(\Rightarrow n_{Cl^-}=0,3mol\)

    \(n_{HNO_3}=0,1\cdot1=0,1mol\) \(\Rightarrow n_{NO^-_3}=0,1mol\)

    \(\Sigma n_{H^+}=n_{HCl}+n_{HNO_3}=0,3+0,1=0,4mol\)

\(n_{NaOH}=0.25\cdot2=0.5\left(mol\right)\)

\(n_{H_2SO_4}=0.25\cdot1=0.25\left(mol\right)\)

\(2NaOH+H_2SO_4\rightarrow Na_2SO_4+H_2O\)

\(0.5..............0.25................0.25\)

\(\left[Na^+\right]=\dfrac{0.25\cdot2}{0.25+0.25}=1\left(M\right)\)

\(\left[SO_4^{2-}\right]=\dfrac{0.25}{0.25+0.25}=0.5\left(M\right)\)

\(n_{Ba\left(OH\right)_2}=0,3.0,1=0,03\left(mol\right)\\ n_{HCl}=0,2.0,15=0,03\left(mol\right)\\ Ba\left(OH\right)_2+2HCl\rightarrow BaCl_2+2H_2O\\ Vì:\dfrac{n_{Ba\left(OH\right)_2\left(đề\right)}}{n_{Ba\left(OH\right)_2\left(PTHH\right)}}=\dfrac{0,03}{1}>\dfrac{n_{HCl\left(đề\right)}}{n_{HCl\left(PTHH\right)}}=\dfrac{0,03}{2}\\ \Rightarrow Ba\left(OH\right)_2dư\\ n_{Ba\left(OH\right)_2\left(p.ứ\right)}=\dfrac{n_{HCl}}{2}=\dfrac{0,03}{2}=0,015\\ n_{Ba\left(OH\right)_2\left(dư\right)}=0,03-0,015=0,015\left(mol\right)\\ \left[OH^-\right]=2.\left[Ba\left(OH\right)_2\left(dư\right)\right]=\dfrac{0,015}{0,3+0,2}=0,03\left(M\right)\\ \Rightarrow pH=14+log\left[OH^-\right]=14+log\left[0,03\right]\approx12,477\)

Câu 3 : 

\(pH=-log\left[H^+\right]=-log\left(0.1\right)=1\)

Câu 4 : 

Chứa các ion : H⁺ , Cl^-

Câu 5 : 

\(n_{NaOH}=n_{HCl}=0.02\cdot0.1=0.002\left(mol\right)\)

\(\Rightarrow x=\dfrac{0.002}{0.01}=0.2\left(M\right)\)

Câu 1 : 

Bảo toàn điện tích : 

\(n_{SO_4^{2-}}=\dfrac{0.2\cdot2+0.1-0.05}{2}=0.225\left(mol\right)\)

\(m_{Muối}=0.2\cdot64+0.1\cdot39+0.05\cdot35.5+0.225\cdot96=40.075\left(g\right)\)

Câu 2 : 

\(\left[Na^+\right]=\dfrac{0.15\cdot0.5\cdot2+0.05\cdot1}{0.15+0.05}=1\left(M\right)\)

Câu 6 : 

\(pH=14+log\left[OH^-\right]=12\)

\(\Rightarrow\left[OH^-\right]=0.01\)

\(n_{NaOH}=n_{OH}=0.01\cdot2=0.02\left(mol\right)\)

\(\Rightarrow m_{NaOH\left(bđ\right)}=0.02\cdot40=0.8\left(g\right)\)

Câu 7 : 

\(n_{KOH}=0.25\cdot0.03=0.0075\left(mol\right)\)

\(n_{HCl}=0.25\cdot0.01=0.0025\left(mol\right)\)

\(\Rightarrow n_{KOH\left(dư\right)}=0.0075-0.0025=0.005\left(mol\right)\)

\(\left[OH^-\right]=\dfrac{0.005}{0.25+0.25}=0.01\)

\(pH=14+log\left[OH^-\right]=14+log\left(0.01\right)=12\)

Chọn C.

Đáp án C

n_MgSO4= 0,1 mol; n_Al2(SO4)3= 0,1 mol; V_dd= 0,5 lít

C_MgSO4=0,2M; C_MAl2(SO4)3= 0,2M

MgSO₄ → Mg²⁺+ SO₄^2-

0,2M                       0,2M

Al₂(SO₄)₃→ 2Al³⁺+ 3SO₄^2-

0,2M                        0,6M

[SO₄^2-] = 0,8M