Đáp án A

.100 => m_HCl = 43,78 (g)

n_HCl = 1,2 (mol)

Gọi n_Zn = a, n_ZnO = b

Zn + 2HCl → ZnCl₂ + H₂

0,4       0,8   ←            0,4 (mol)

ZnO + 2HCl → ZnCl₂ + H₂O

0,2  ←   0,4                               (mol)

.100%

.100% = 61,61%

%m_ZnO = 100% -61,6% = 38,4%

Giải thích: 

Zn + 2HCl -> ZnCl₂ + H₂

ZnO + 2HCl -> ZnCl₂ + H₂O

n_H2 = n_Zn = 0,4 mol

n_HCl = 1,2 mol = 2n_Zn + 2n_ZnO => n_ZnO = 0,2 mol

=> %m_ZnO = 38,4%

Đáp án B

nH2 = 6,72/22,4 = 0,3 (mol)

PTHH: 2Al + 6HCl -> 2AlCl3 + 3H2

nAl = 0,3 : 3 . 2 = 0,2 (mol)

nHCl (Al) = 0,3 . 2 = 0,6 (mol)

mAl = 0,2 . 27 = 5,4 (g)

%mAl = 5,4/25,65 = 20,05%

%mZnO = 100% - 20,05% = 79,95%

mZnO = 25,65 - 5,4 = 20,25 (g)

nZnO = 20,25/81 = 0,25 (mol)

PTHH: ZnO + 2HCl -> ZnCl2 + H2O

nHCl (ZnO) = 0,25 . 2 = 0,5 (mol)

nHCl (đã dùng) = 0,6 + 0,5 = 1,1 (mol)

CMddHCl = 1,1/0,1008 = 10,9M

C% = (10,9 . 36,5)/(10 . 1,19) = 33,43%

Đặt: \(n_{Zn}=a\left(mol\right);n_{ZnO}=b\left(mol\right)\left(a,b>0\right)\)

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

\(a.Zn+2HCl\rightarrow ZnCl_2+H_2\\ ZnO+2HCl\rightarrow ZnCl_2+H_2O\\ \Rightarrow\left\{{}\begin{matrix}65a+81b=14,6\\a=0,1\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\\ b.m_{Zn}=0,1.65=6,5\left(g\right)\\ m_{ZnO}=0,1.81=8,1\left(g\right)\\ d.m_{ddHCl}=\dfrac{\left(0,1+0,1\right).2.36,5.100}{7,3}=200\left(g\right)\)

a)\(n_{H_2}=\dfrac{3,36}{22,4}=0,15mol\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

0,15    0,3                        0,15

\(m_{Zn}=0,15\cdot65=9,75\left(g\right)\)

\(\%m_{Zn}=\dfrac{9,75}{17,85}\cdot100\%=54,62\%\)

\(\%m_{ZnO}=100\%-54,62\%=45,38\%\)

b)\(m_{ZnO}=17,85-9,75=8,1\left(g\right)\Rightarrow n_{ZnO}=\dfrac{8,1}{81}=0,1mol\)

  \(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)

  0,1         0,2

  \(\Rightarrow\Sigma n_{HCl}=0,3+0,2=0,5mol\)

  \(\Rightarrow V=\dfrac{0,5}{1}=0,5l=500ml\)

Tiếp bài của creeper nhé:

c. Ta có: \(n_{ZnO}=\dfrac{4,86}{81}=0,06\left(mol\right)\)

Theo PT₍₁₎: \(n_{HCl}=2.n_{ZnO}=2.0,06=0,12\left(mol\right)\)

Theo PT₍₂₎: \(n_{HCl}=2.n_{Zn}=2.0,1=0,2\left(mol\right)\)

=> \(n_{HCl}=0,12+0,2=0,32\left(mol\right)\)

=> \(m_{HCl}=0,32.36,5=11,68\left(g\right)\)

Ta có: \(C_{\%_{HCl}}=\dfrac{11,68}{m_{dd_{HCl}}}.100\%=12\%\)

=> \(m_{dd_{HCl}}=\dfrac{292}{3}\left(g\right)\)

Theo đề, ta có: 

\(D=\dfrac{\dfrac{292}{3}}{V_{dd_{HCl}}}=1,2\)(g/ml)

=> \(V_{dd_{HCl}}=81,1\left(ml\right)\)

a) Gọi n Zn = a(mol) ; n ZnO =  b(mol)

=> 65a + 81b = 14,6(1)

$Zn + 2HCl \to ZnCl_2 + H_2$
$ZnO + 2HCl \to ZnCl_2 + H_2O$

n ZnCl2 = a + b = 27,2/136 = 0,2(2)

Từ (1)(2) suy ra : a = b = 0,1

%m Zn = 0,1.65/14,6  .100% = 44,52%
%m ZnO = 100% -44,52% = 55,45%

b)

n HCl = 2n Zn + 2n ZnO = 0,4(mol)

m dd HCl = 0,4.36,5/7,3% = 200(gam)

Zn+2HCl->ZnCl2+H2

ZnO+2HCl->ZnCl2+H2O

nH2=0.2(mol)->nZn=0.2(mol).mZn=13(g)

mZnO=21.1-13=8.1(g)

nZnO=0.1(mol)

Tổng nHCl cần dùng:0.2*2+0.1*2=0.6(mol)

mHCl=21.9(g)

C%ddHCl=21.9:200*100=10.95%

n muối=0.2+.1=0.3(mol)

m muối=40.8(g)