\(2KMnO_4\underrightarrow{to}K_2MnO_4+MnO_2+O_2\\ 3Fe+2O_2\underrightarrow{to}Fe_3O_4\\ n_{Fe_3O_4}=\dfrac{69,6}{232}=0,3\left(mol\right)\\ \Rightarrow n_{O_2}=2.0,3=0,6\left(mol\right)\\ n_{KMnO_4}=2.n_{O_2}=2.0,6=1,2\left(mol\right)\\ m=m_{KMnO_4}=158.1,2=189,6\left(g\right)\\ V=V_{O_2\left(đktc\right)}=0,6.22,4=13,44\left(l\right)\)

PTHH: \(2KMnO_4\xrightarrow[]{t^o}K_2MnO_4+MnO_2+O_2\)

\(n_{KMnO_4}=\dfrac{m_{KMnO_4}}{M_{KMnO_4}}=\dfrac{15,8}{158}=0,1\left(mol\right)\)

a. Theo PTHH: \(n_{O_2}=\dfrac{1}{2}n_{KMnO_4}=\dfrac{1}{2}0,1=0,05\left(mol\right)\)

\(\Rightarrow V_{O_2}=n_{O_2}.22,4=0,05.22,4=1,12\left(l\right)\)

b. PTHH: \(3Fe+2O_2\xrightarrow[]{t^o}Fe_3O_4\)

\(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)

Ta có: \(\dfrac{1}{n_{O_2}}=\dfrac{1}{0,05}\)

\(\dfrac{1}{n_{Fe}}=\dfrac{1}{0,1}\)

\(\Rightarrow\dfrac{1}{n_{O_2}}>\dfrac{1}{n_{Fe}}\)

Vậy Fe dư

Theo PTHH: \(n_{Fe_3O_4}=\dfrac{0,1.1}{3}=\dfrac{1}{30}\left(mol\right)\)

\(\Rightarrow m_{Fe_3O_4}=n_{Fe_3O_4}.M_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,73g\)

Chọn đáp án C

a) \(n_{O_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\)

PTHH: 2KMnO₄ --t^o--> K₂MnO₄ + MnO₂ + O₂

                 1<-----------------------------0,5

=> \(m_{KMnO_4}=1.158=158\left(g\right)\)

b) \(n_{Fe_2O_3}=\dfrac{80}{160}=0,5\left(mol\right)\)

PTHH: Fe₂O₃ + 3H₂ --t^o--> 2Fe + 3H₂O

              0,5--->1,5

=> \(V_{H_2}=1,5.22,4=33,6\left(l\right)\)

c) \(n_{CuO}=\dfrac{8}{80}=0,1\left(mol\right)\)

\(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)

PTHH: CuO + H₂ --t^o--> Cu + H₂O

Xét tỉ lệ: \(\dfrac{0,1}{1}>\dfrac{0,05}{1}\) => CuO dư, H₂ hết

PTHH: CuO + H₂ --t^o--> Cu + H₂O

            0,05<-0,05---->0,05-->0,05

=> \(n_{Cu\left(dư\right)}=0,1-0,05=0,05\left(mol\right)\)

m_Cu = 0,05.64 = 3,2 (g)

V_H2O = 0,05.22,4 = 1,12 (l)

a)\(n_{O_2}=\dfrac{11,2}{22,4}=0,5mol\)

   \(2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)

    1                                                   0,5

   \(M_{KMnO_4}=1\cdot158=158g\)

b)\(n_{Fe_2O_3}=\dfrac{80}{160}=0,5mol\)

   \(Fe_2O_3+3H_2\rightarrow2Fe+3H_2O\)

   0,5          1,5

   \(V_{H_2}=1,15\cdot22,4=25,76l\)

nKMnO4 = 15.8/158 = 0.1 (mol) 

2KMnO4 -to-> K2MnO4 + MnO2 + O2 

0.1__________________________0.05 

nNa = 1.38/23 = 0.06 (mol) 

4Na +  O2 -to-> 2Na2O 

0.06__0.015 

mO2 (dư) = ( 0.025 - 0.015) * 32 = 0.32(g)

\(n_{O_2}=\dfrac{1}{2}\cdot n_{KMnO_4}1=\dfrac{1}{2}\cdot0.1=0.05\left(mol\right)\)

\(n_{H_2}=\dfrac{1.792}{22.4}=0.08\left(mol\right)\)

\(\Rightarrow n_{M\left(dư\right)}=\dfrac{0.08\cdot2}{n}=\dfrac{0.16}{n}\left(mol\right)\)

\(n_{M\left(pư\right)}=\dfrac{0.05\cdot4}{n}=\dfrac{0.2}{n}\left(mol\right)\)

\(m_M=\left(\dfrac{0.16}{n}+\dfrac{0.2}{n}\right)\cdot M=11.7\left(g\right)\)

\(\Leftrightarrow0.36M=11.7n\)

\(\Leftrightarrow M=32.5n\)

\(BL:n=2\Rightarrow M=65\)

\(M:Zn\)

\(\)

\(PTHH:2KMnO_4\underrightarrow{t^o}K_2MnO_4+MnO_2+O_2\)

\(\Rightarrow n_{O_2}=0,05\left(mol\right)\)

Gọi hóa trị của M là n

Bảo toàn e: \(\Rightarrow n_M=0,2+0,16=\dfrac{0,36}{n}\left(mol\right)\)

\(\Rightarrow M_M=\dfrac{11,7n}{0,36}=32,5n\)

Biện luận: 

\(n=2\rightarrow M=65\left(Zn\right)\)

Chọn đáp án D

a) Gọi số mol KMnO₄, KClO₃ là a, b (mol)

=> \(\left\{{}\begin{matrix}n_K=a+b\left(mol\right)\\n_{Mn}=a\left(mol\right)\\n_{Cl}=b\left(mol\right)\\n_O=4a+3b\left(mol\right)\end{matrix}\right.\)

Có \(n_O=\dfrac{9}{14}\Sigma_n\)

=> \(4a+3b=\dfrac{9}{14}\left(a+b+a+b+4a+3b\right)\)

=> \(\dfrac{1}{7}a-\dfrac{3}{14}b=0\) (1)

PTHH: 2KMnO₄ --t^o--> K₂MnO₄ + MnO₂ + O₂

                 a------------------------------->0,5a

             2KClO₃ --t^o--> 2KCl + 3O₂

                 b------------------>1,5b

=> \(0,5a+1,5b=\dfrac{10,08}{22,4}=0,45\) (2)

(1)(2) => a = 0,3 (mol); b = 0,2 (mol)

=> m = 0,3.158 + 0,2.122,5 = 71,9 (g)

b) \(\left\{{}\begin{matrix}\%m_{KMnO_4}=\dfrac{0,3.158}{71,9}.100\%=65,925\%\\\%m_{KClO_3}=\dfrac{0,2.122,5}{71,9}.100\%=34,075\%\end{matrix}\right.\)

Câu 1/

\(2C\left(\dfrac{m}{12}\right)+O_2\left(\dfrac{m}{24}\right)\rightarrow2CO_2\left(\dfrac{m}{12}\right)\)

\(CO_2\left(\dfrac{m}{12}\right)+Ca\left(OH\right)_2\rightarrow CaCO_3\left(\dfrac{m}{12}\right)+H_2O\)

Nếu như O₂ thì tỷ khối của hỗn hợp so với O₂ phải là: \(\dfrac{44}{32}=1,375>1,25\) vậy trong hỗn hợp khí phải có O₂

\(n_C=\dfrac{m}{12}\left(mol\right)\)

\(n_{O_2}=\dfrac{V}{22,4}\left(mol\right)\)

\(\Rightarrow n_{O_2\left(dư\right)}=\dfrac{V}{22,4}-\dfrac{m}{12}\left(mol\right)\)

\(\Rightarrow\dfrac{44.\dfrac{m}{12}+32.\left(\dfrac{V}{22,4}-\dfrac{m}{24}\right)}{\dfrac{m}{12}+\dfrac{V}{22,4}-\dfrac{m}{24}}=1,25.32=40\)

\(\Leftrightarrow15V-28m=0\left(1\right)\)

Ta lại có: \(n_{CaCO_3}=\dfrac{6}{100}=0,06\left(mol\right)\)

\(\Rightarrow\dfrac{m}{12}=0,06\Leftrightarrow m=0,72\left(2\right)\)

Từ (1) và (2) ta có hệ: \(\left\{{}\begin{matrix}15V-28m=0\\m=0,72\end{matrix}\right.\)

\(\Leftrightarrow\left\{{}\begin{matrix}m=0,72\left(g\right)\\V=1,344\left(l\right)\end{matrix}\right.\)

Đáp án D

Na₂CO₃ bền với nhiệt nên không bị nhiệt phân.

 %mCaCO₃

%mCaCO₃ =  Chọn D.