pthh: Zn+HCl→ZnCl₂+H₂ (1)

         ZnO+HCl→ZnCl₂+H₂O (2)

theo bài ra số mol của H₂=0,2 (mol)

theo pt1 ta có nZn=nH₂=0,2 (mol)

⇒ mZn=0,2 .65=13 (g)→mZnO=21,1-13=8,1 (g) →nZnO=0,1 (mol)

%Zn=13.100%/21,1=61,61%

%ZnO=38,39%

Theo pt 1 nHCl=2nZn=0,4(mol) (3)

Theo pt2 nHCl=2nZnO=0,4 (mol) (4)

Từ 3,4 ⇒nHCl=0,8 (mol)

V HCl=0,4 (lít)=400ml

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1mol\\ a)Zn+2HCl\rightarrow ZnCl_2+H_2\)

0,1             0,2          0,1         0,1

\(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)

\(b)m_{Zn}=0,1.65=6,5g\\ m_{ZnO}=14,6-6,5=8,1g\\ c)n_{ZnO}=\dfrac{8,1}{81}=0,1mol\\ ZnO+2HCl\rightarrow ZnCl_2+H_2O\)

0,1            0,2

\(m_{ddHCl}=\dfrac{\left(0,2+0,2\right)36,5}{14,6}\cdot100=100g\)

Zn+2HCl->ZnCl2+H2

ZnO+2HCl->ZnCl2+H2O

nH2=0.2(mol)->nZn=0.2(mol).mZn=13(g)

mZnO=21.1-13=8.1(g)

nZnO=0.1(mol)

Tổng nHCl cần dùng:0.2*2+0.1*2=0.6(mol)

mHCl=21.9(g)

C%ddHCl=21.9:200*100=10.95%

n muối=0.2+.1=0.3(mol)

m muối=40.8(g)

a)\(n_{H_2}=\dfrac{3,36}{22,4}=0,15mol\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

0,15    0,3                        0,15

\(m_{Zn}=0,15\cdot65=9,75\left(g\right)\)

\(\%m_{Zn}=\dfrac{9,75}{17,85}\cdot100\%=54,62\%\)

\(\%m_{ZnO}=100\%-54,62\%=45,38\%\)

b)\(m_{ZnO}=17,85-9,75=8,1\left(g\right)\Rightarrow n_{ZnO}=\dfrac{8,1}{81}=0,1mol\)

  \(ZnO+2HCl\rightarrow ZnCl_2+H_2O\)

  0,1         0,2

  \(\Rightarrow\Sigma n_{HCl}=0,3+0,2=0,5mol\)

  \(\Rightarrow V=\dfrac{0,5}{1}=0,5l=500ml\)

Zn  +  2HCl →  ZnCl₂  +  H₂

ZnO  +  HCl →  ZnCl₂  +  H₂O

nH₂ = 4,48/22,4 = 0,2 mol

=> nZn = nH₂ = 0,2 mol

<=> mZn = 0,2.65= 13 gam 

<=> %mZn = \(\dfrac{13}{21,1}.100\%\) = 61,6% , %mZnO = 100 - 61,6 = 38,4%.

b. nZnO = \(\dfrac{21,1-13}{81}\) = 0,1 mol

=> nZnCl₂ = nZn + nZnO = 0,3 mol

<=> mZnCl₂ = 0,3.81 = 24,3 gam.

gọi a=nZn; b=nZnO

ta có 65a+81b= 21,1 (1)

nH2=4,48/22,4=0,2mol

Zn+2HCl->ZnCl2+H2

0,2                            0,2

ZnO+2HCl-> ZnCl2+H2O

b                    b

ta có 

nZn=a= 0,2 mol

từ (1) => b= 0,1 mol

mZn=0,2.65=13(g)

mZnO= 0,1.81=8,1g

%mZn=13.100%/21,1=61,61%

%mZnO=38,39%

mZnCl2=135.(0,2+0,1)=40,5g

Bài 1:

Ta có: \(n_{HCl}=0,08.1=0,08\left(mol\right)\)

BTNT H và O, có: \(n_{H_2O}=\dfrac{1}{2}n_{HCl}=0,04\left(mol\right)\)

⇒ n_{O (trong oxit)} = n_H2O = 0,04 (mol)

Có: m_hh  = m_Fe + m_O

⇒ m_Fe = 2,32 - 0,04.16 = 1,68 (g)

Bài 2:

Ta có: \(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

BTNT H, có: \(n_{HCl}=2n_{H_2}=0,4\left(mol\right)\)

\(\Rightarrow V_{ddHCl}=\dfrac{0,4}{0,5}=0,8\left(l\right)\)

Bạn tham khảo nhé!

$a\big)$

$Zn+2CH_3COOH\to (CH_3COO)_2Zn+H_2$

$ZnO+2CH_3COOH\to (CH_2COO)_2Zn+H_2O$

Theo PT: $n_{Zn}=n_{H_2}=\frac{4,48}{22,4}=0,2(mol)$

$\to \%m_{Zn}=\frac{0,2.65}{21,1}.100\%\approx 61,61\%$

$\to \%m_{ZnO}=100-61,61=38,39\%$

$b\big)$

$n_{ZnO}=\frac{21,1-0,2.65}{81}=0,1(mol)$

Theo PT: $\sum n_{CH_3COOH}=2n_{Zn}+2n_{ZnO}=0,6(mol)$

$\to C_{M_{CH_3COOH}}=\dfrac{0,6}{\frac{200}{1000}}=3M$

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\)

\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)

 0,2                                                                0,2     ( mol )

\(m_{Zn}=0,2.65=13g\)

\(\%m_{Zn}=\dfrac{13}{21,1}.100=61,61\%\)

\(\%m_{ZnO}=100\%-61,61\%=38,39\%\)

\(Zn+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2\)

0,2               0,4                                                  ( mol )

\(n_{ZnO}=\dfrac{21,1-13}{81}=0,1mol\)

\(ZnO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Zn+H_2O\)

 0,1              0,2                                                        ( mol )

\(C_{M\left(CH_3COOH\right)}=\dfrac{0,4+0,2}{0,2}=3M\)

`a)`

`Zn+2HCl->ZnCl_2+H_2`

`ZnO+2HCl->ZnCl_2+H_2O`

`b)`

Theo PT: `n_{Zn}=n_{H_2}={2,24}/{22,4}=0,1(mol)`

`->m_{Zn}=0,1.65=6,5(g)`

`->m_{ZnO}=14,6-6,5=8,1(g)`

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