Fe + CuSO4 → FeSO4 + Cu.

nFe = nCuSO4 = 0,232 mol.

mFe = 0,232 x 56 = 12,992g.

\(a.n_{CuSO_4}=n_{CuSO_4.5H_2O}=\dfrac{58}{250}=0,232\left(mol\right)\\ \Rightarrow CM_{CuSO_4}=\dfrac{0,232}{0,5}=0,464M\\ b.Fe+CuSO_4\rightarrow FeSO_4+Cu\\ 50mlddAcó0,0232molCuSO_4\\ n_{Fe}=n_{CuSO_4}=0,0232\left(mol\right)\\ \Rightarrow m_{Fe}=0,0232.56=1,2992\left(g\right)\)

Phải hòa tan \(\dfrac{80.11,1}{100}=8,88g\) muối này vào 80g nước để được dd bão hòa ở nhiệt độ trên

Ta có: \(n_{Fe_2O_3}=\dfrac{9,6}{160}=0,06\left(mol\right)\)

a. PTHH: Fe₂O₃ + 3H₂SO₄ ---> Fe₂(SO₄)₃ + 3H₂O (1)

Theo PT₍₁₎: \(n_{H_2SO_4}=3.n_{Fe_2O_3}=3.0,06=0,18\left(mol\right)\)

=> \(m_{H_2SO_4}=0,18.98=17,64\left(g\right)\)

Ta có: \(C_{\%_{H_2SO_4}}=\dfrac{17,64}{m_{dd_{H_2SO_4}}}.100\%=9,8\%\)

=> \(m_{dd_{H_2SO_4}}=180\left(g\right)\)

b. Ta có: \(m_{dd_{Fe_2\left(SO_4\right)_3}}=9,6+180=189,6\left(g\right)\)

Theo PT₍₁₎: \(n_{Fe_2\left(SO_4\right)_3}=n_{Fe_2O_3}=0,06\left(mol\right)\)

=> \(m_{Fe_2\left(SO_4\right)_3}=0,06.400=24\left(g\right)\)

=> \(C_{\%_{Fe_2\left(SO_4\right)_3}}=\dfrac{24}{189,6}.100\%=12,66\%\)

c. PTHH: Fe₂(SO₄)₃ + 3BaCl₂ ---> 3BaSO₄↓ + 2FeCl₃ (2)

Theo PT₍₂₎: \(n_{BaSO_4}=3.n_{Fe_2\left(SO_4\right)_3}=3.0,06=0,18\left(mol\right)\)

=> \(m_{BaSO_4}=0,18.233=41,94\left(g\right)\)

Theo PT₍₂₎: \(n_{BaCl_2}=n_{BaSO_4}=0,18\left(mol\right)\)

=> \(m_{BaCl_2}=0,18.208=37,44\left(g\right)\)

Ta có: \(C_{\%_{BaCl_2}}=\dfrac{37,44}{m_{dd_{BaCl_2}}}.100\%=10,4\%\)

=> \(m_{dd_{BaCl_2}}=360\left(g\right)\)

a, \(Na_2O+H_2O\rightarrow2NaOH\)

Ta có: \(n_{Na_2O}=\dfrac{3,1}{62}=0,05\left(mol\right)\)

Theo PT: \(n_{NaOH}=2n_{Na_2O}=0,1\left(mol\right)\)

m _{dd sau pư} = 3,1 + 50 = 53,1 (g)

\(\Rightarrow C\%_{NaOH}=\dfrac{0,1.40}{53,1}.100\%\approx7,53\%\)

b, \(2Na+2H_2O\rightarrow2NaOH+H_2\)

Ta có: \(n_{Na}=\dfrac{4,6}{23}=0,2\left(mol\right)\)

Theo PT: \(\left\{{}\begin{matrix}n_{NaOH}=n_{Na}=0,2\left(mol\right)\\n_{H_2}=\dfrac{1}{2}n_{Na}=0,1\left(mol\right)\end{matrix}\right.\)

Ta có: m _{dd sau pư} = 4,6 + 95,6 - 0,1.2 = 100 (g)

\(\Rightarrow C\%_{NaOH}=\dfrac{0,2.40}{100}.100\%=8\%\)

\(n_{Fe2O3}=\dfrac{16}{160}=0,1\left(mol\right)\)

Pt : \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O|\)

           1            6               2             3

        0,1           0,6           0,2

a) \(n_{HCl}=\dfrac{0,1.6}{1}=0,6\left(mol\right)\)

\(m_{HCl}=0,6.36,5=21,9\left(g\right)\)

\(m_{ddHCl}=\dfrac{21,9.100}{7,3}=300\left(g\right)\)

b) \(n_{FeCl3}=\dfrac{0,6.2}{6}=0,2\left(mol\right)\)

⇒ \(m_{FeCl3}=0,2.162,5=32,5\left(g\right)\)

\(m_{ddspu}=16+300=316\left(g\right)\)

\(C_{FeCl3}=\dfrac{32,5.100}{316}=10,28\)⁰/₀

$n_{Fe}=\frac{19,6}{56}=0,35(mol)$

$Fe+H_2SO_4\to FeSO_4+H_2$

Theo PT: $n_{H_2SO_4}=n_{FeSO_4}=n_{H_2}=0,35(mol)$

$\to m_{H_2SO_4}=0,35.98=34,3(g)$

$m_{FeSO_4}=0,35.152=53,2(g)$

$m_{H_2}=0,35.2=0,7(g)$

\(n_{H_2SO_4}=0.5\cdot1=0.5\left(mol\right)\)

\(Fe+H_2SO_4\rightarrow FeSO_4+H_2\)

\(0.5......0.5.............0.5\)

\(m_{Fe}=0.5\cdot56=28\left(g\right)\)

\(C_{M_{FeSO_4}}=\dfrac{0.5}{0.5}=1\left(M\right)\)

1

\(a)m_{H_2O}=250-5=245g\\b )C_{\%NaCl}=\dfrac{5}{250}\cdot100=2\%\)

\(2\\ m_{ddCuSO_4}=\dfrac{15.100}{5}=300g\\ m_{H_2O}=300-15=285g\)

Câu 1:

a, Ta có: m _dd = m _{chất tan} + m_H2O ⇒ m_H2O = 250 - 5 = 245 (g)

b, \(C\%_{NaCl}=\dfrac{5}{250}.100\%=2\%\)

Câu 2:

Ta có: \(C\%_{CuSO_4}=\dfrac{15}{m_{ddCuSO_4}}.100\%=5\%\)

\(\Rightarrow m_{ddCuSO_4}=300\left(g\right)\)

⇒ m_H2O = 300 - 15 = 285 (g)