câu 1

Feo + 2HCl----->FeCl2 +H2

x-----------------x

ZnO + 2HCl--------->ZnCl2+ H2

y--------------------------y

\(\left\{{}\begin{matrix}72x+81y=67,95\\127x+136y=114,7\end{matrix}\right.\)

=>\(\left\{{}\begin{matrix}x=0,1\\y=o,75\end{matrix}\right.\)

%FeO=\(\frac{0,1.72}{67,95}\).100=10,6

%ZnO=89,4

b/ nHCl=0,1.2+0,75.2=1,7

mHcl=1,7.36,5=62,05

mddHcl=62,05.100/3,65=1700

mH2=1,7

mdd=1700+67,95-1,7=1766,25

C%Fecl2=0,1.127/1766,25.100=0,72

C%ZnCl2=0,75.136/1766,25.100=5,77

a) \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)

PTHH: Mg + H₂SO₄ --> MgSO₄ + H₂

           0,1---->0,1------->0,1---->0,1

=> \(m_{dd.H_2SO_4}=\dfrac{0,1.98}{4,9\%}=200\left(g\right)\)

b) m_{dd sau pư} = 2,4 + 200 - 0,1.2 = 202,2 (g)

m_MgSO4 = 0,1.120 = 12 (g)

\(C\%_{MgSO_4}=\dfrac{12}{202,2}.100\%=5,9\%\)

c) 

\(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)

PTHH: CuO + H₂ --t^o--> Cu + H₂O

Xét tỉ lệ: \(\dfrac{0,25}{1}>\dfrac{0,1}{1}\) => Hiệu suất tính theo H₂

\(n_{Cu}=\dfrac{3,2}{64}=0,05\left(mol\right)\)

PTHH: CuO + H₂ --t^o--> Cu + H₂O

                      0,05<-----0,05

=> \(H=\dfrac{0,05}{0,1}.100\%=50\%\)

a, \(n_{Mg}=\dfrac{2,4}{24}=0,1\left(mol\right)\)

PTHH: Mg + H₂SO₄ ---> MgSO₄ + H₂

           0,1--->0,1---------->0,1-------->0,1

\(m_{dd\left(H_2SO_4\right)}=\dfrac{0,1.98}{4,9\%}=200\left(g\right)\)

b, \(m_{dd\left(sau.pư\right)}=2,4+200-0,2.2=202,2\left(g\right)\)

\(\rightarrow C\%_{MgSO_4}=\dfrac{0,1.120}{202,2}.100\%=5,93\%\)

c, \(n_{CuO}=\dfrac{20}{80}=0,25\left(mol\right)\)

PTHH: CuO + H₂ --t^o--> Cu + H₂O

LTL: 0,25 > 0,1 => CuO dư

\(n_{Cu}=\dfrac{3,2}{64}=0,05\left(mol\right)\)

Theo pt: \(n_{H_2}=n_{Cu}=0,05\left(mol\right)\)

=> \(H=\dfrac{0,05}{0,1}.100\%=50\%\)

Gọi oxit kim loại cần tìm là \(AO\).

\(n_{H_2SO_4}=C_M\cdot V=0,2\cdot0,4=0,08\left(mol\right)\)

\(pthh:AO+H_2SO_4\rightarrow ASO_4+H_2\left(1\right)\)

Theo \(pthh\left(1\right):n_{AO}=n_{H_2SO_4}=0,08\left(mol\right)\)

\(\Rightarrow M_{AO}=\dfrac{m}{n}=\dfrac{4,48}{0,08}=56\left(g\right)\\ \Rightarrow M_A+16=56\\ \Rightarrow M_A=40\left(g\right)\)

\(\Rightarrow\) A là kim loại \(Ca\left(Caxi\right)\)

\(\Rightarrow CTHH:CaO\)

Sai đề không bạn? :33

Gọi CTHH oxit kim loại là \(RO\)

Giả sử có 1mol oxit pứ

\(RO+H_2SO_4\rightarrow RSO_4+H_2O\)

\(1-\rightarrow1---\rightarrow1\)

\(m_{ddH_2SO_4}=\dfrac{1.98}{4,9}\cdot100=2000\left(g\right)\\ m_{ddRSO_4}=1\left(R+16\right)+2000=2016+R\left(g\right)\\ C_{\%RSO_4}=\dfrac{1\left(R+96\right)}{2016+R}\cdot100=5,88\%\\ \Rightarrow R\approx24\left(g/mol\right)\)

Vậy R là Mg

a)

$MCl_2 + H_2SO_4 \to MSO_4 + 2HCl$
$n_{MCl_2}= n_{MSO_4}$

$\Rightarrow \dfrac{31,2}{M + 71} = \dfrac{34,95}{M + 96}$
$\Rightarrow M = 137(Bari)$

b)

$n_{H_2SO_4} = n_{BaSO_4} = \dfrac{34,95}{233} = 0,15(mol)$
$m_{dd\ H_2SO_4} = \dfrac{0,15.98}{20\%} = 73,5(gam)$
c)

$n_{HCl} = 2n_{BaSO_4} = 0,3(mol)$
$m_{dd}=  31,2 + 73,5 - 34,95 = 69,75(gam)$
$C\%_{HCl} = \dfrac{0,3.36,5}{69,75}.100\% = 15,7\%$

Sửa 5,78 thành 5,88%

Gọi kim loại là R $\Rightarrow$ Oxit là RO

Gỉa sử nRO=1 mol

$RO+{}^{}S{}^{}\to RS{}^{}+{}^{}O$

Ta có: nRO=nH2SO4=nRSO4=1(mol)nRO=nH2SO4=nRSO4=1(mol)

⇒mH2SO4=198=98(g)⇒mH2SO4=198=98(g)

mddH2SO4=984,9%=2000(g)mddH2SO4=984,9%=2000(g)

BTKL: m dung dịch sau phản ứng=mRO + m dd H2SO4

$=1\left(R+15\right)+200=R+2016($

\(n_{H_2SO_4}=0,2.2=0,4\left(mol\right)\)

Fe + H2SO4 → FeSO4 + H2 

2Al + 3H2SO4 → Al2(SO4)3 + 3H2

Gọi x,y lần lượt là số mol Fe, Al

\(\left\{{}\begin{matrix}56x+27y=11\\x+\dfrac{3}{2}y=0,4\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\)

=>\(\%m_{Fe}=\dfrac{0,1.56}{11}.100=50,91\%\)

=> %m _Al = 100 - 50,91 =49,09 %

b)Theo PT:  \(n_{H_2}=n_{H_2SO_4}=0,4\left(mol\right)\)

=> \(V_{H_2}=0,4.22,4=8,96\left(l\right)\)

c) \(CM_{FeSO_4}=\dfrac{0,1}{0,2}=0,5M\)

\(CM_{Al_2\left(SO_4\right)_3}=\dfrac{\dfrac{0,2}{2}}{0,2}=0,5M\)