a)

PTHH :

C2H4 + Br2 - > C2H4Br2

b) m( bình tăng ) = mC2H4 = 2,8(g) => nC2H4 = 0,1(mol)

nCH4 = nhh - nC2H4 = 0,15 - 0,1 = 0,05(mol)

=> mCH4 = 0,05.16 = 0,8(g)

c) Theo PTHH ta có : nBr2(pư)=nC2H4 = 0,1 (mol)

=> mBr2(pư) = 0,1.0 = 8(g)

C2H4: 1,7% và CH4:88,3% 

\(PTHH:C_2H_4+Br_2\rightarrow C_2H_4Br_2\\ n_{CH_4}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ \%m_{CH_4}=\dfrac{0,1.16}{3}.100\%=53,33\%\\ \%m_{C_2H_4}=100\%-53,33\%=46,67\%\)

\(V_{khí.thoát.ra}=V_{CH_4}=2,24l\)

\(n_{CH_4}=\dfrac{2,24}{22,4}=0,1mol\)

\(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

\(m_{CH_4}=0,1.16=1,6g\)

\(\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{1,6}{3}.100=53,33\%\\\%m_{C_2H_4}=100\%-53,33\%=46,67\%\end{matrix}\right.\)

a)\(m_{tăng}=m_{Br_2}=m_{C_2H_2}=0,78g\Rightarrow n_{C_2H_2}=0,03mol\)

\(n_{hh}=\dfrac{11,2}{22,4}=0,5mol\)

\(\Rightarrow n_{CH_4}=0,5-0,03=0,47mol\)

b)\(C_2H_2+2Br_2\rightarrow C_2H_2Br_4\)

    0,03                    0,03

\(m_{C_2H_2Br_4}=0,03\cdot266=7,98g\)

c)\(\%V_{C_2H_2}=\dfrac{0,03}{0,5}\cdot100\%=6\%\)

\(\%V_{CH_4}=100\%-6\%=94\%\)

\(a,n_{hh\left(CH_4,C_2H_4,C_2H_2\right)}=\dfrac{8,96}{22,4}=0,4\left(mol\right)\\ n_{CH_4}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\\ n_{hh\left(C_2H_4,C_2H_2\right)}=0,4-0,1=0,3\left(mol\right)\)

Gọi \(\left\{{}\begin{matrix}n_{C_2H_4}=a\left(mol\right)\\n_{C_2H_2}=b\left(mol\right)\end{matrix}\right.\)

=> \(\left\{{}\begin{matrix}a+b=0,3\\28a+26b=8,1\end{matrix}\right.\Leftrightarrow a=b=0,15\left(mol\right)\)

PTHH:

\(CH\equiv CH+2Br-Br\rightarrow CHBr_2-CHBr_2\)

\(CH_2=CH_2+Br-Br\rightarrow CH_2Br-CH_2Br\)

\(b,\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,1}{0,4}.100\%=25\%\\\%V_{C_2H_4}=\%V_{C_2H_2}=\dfrac{0,15}{0,4}.100\%=37,5\%\end{matrix}\right.\)

c, PTHH:

\(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\\ C_2H_2+\dfrac{5}{2}O_2\underrightarrow{t^o}2CO_2+H_2O\\ C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\\ Ba\left(OH\right)_2+CO_2\rightarrow BaCO_3\downarrow+H_2O\\ \rightarrow n_{BaCO_3}=n_{CO_2}=0,1+0,15.0,15.2=0,7\left(mol\right)\\ m_{BaCO_3}=0,7.197=137,9\left(g\right)\)

Ta có: m _{dd Br2 tăng} = m_C2H4 = 2,8 (g)

\(\Rightarrow n_{C_2H_4}=\dfrac{2,8}{28}=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{C_2H_4}=\dfrac{0,1.22,4}{3,36}.100\%\approx66,67\%\\\%V_{CH_4}\approx33,33\%\end{matrix}\right.\)

Có: \(n_{CH_4}=\dfrac{3,36}{22,4}-0,1=0,05\left(mol\right)\)

⇒ m _hh = m_CH4 + m_C2H4 = 0,05.16 + 0,1.28 = 3,6 (g)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,05.16}{3,6}.100\%\approx22,22\%\\\%m_{C_2H_4}\approx77,78\%\end{matrix}\right.\)

a, Ta có: \(n_{CH_4}+n_{C_2H_4}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\left(1\right)\)

\(16n_{CH_4}+28n_{C_2H_4}=3\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,1\left(mol\right)\\n_{C_2H_4}=0,05\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,1.16}{3}.100\%\approx53,33\%\\\%m_{C_2H_4}\approx46,67\%\end{matrix}\right.\)

- Ở cùng điều kiện nhiệt độ và áp suất, % số mol cũng là %V.

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,1}{0,15}.100\%\approx66,67\%\\\%V_{C_2H_4}\approx33,33\%\end{matrix}\right.\)

b, PT: \(C_2H_4+Br_2\rightarrow C_2H_4Br_2\)

Có: m _tăng = m_C2H4 = 0,05.28 = 1,4 (g)

a) \(n_{hh}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

Gọi \(\left\{{}\begin{matrix}n_{CH_4}=a\left(mol\right)\\n_{C_2H_4}=b\left(mol\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}a+b=0,15\\16a+28b=3\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,05\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CH_4}=\dfrac{0,1}{0,15}.100\%=66,67\%\\\%V_{C_2H_4}=100\%-66,67\%=33,33\%\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{CH_4}=\dfrac{0,1.16}{3}.100\%=53,33\%\\\%m_{C_2H_4}=100\%-53,33\%=46,67\%\end{matrix}\right.\)

b) \(m=m_{C_2H_4}=0,05.28=1,4\left(g\right)\)