\(n_{HCl}=0,2.0,2=0,04\left(mol\right)\)

Để trung hòa thì:

\(n_{NaOH}=n_{HCl}\)

\(\Leftrightarrow0,1.V_{NaOH}=0,04\)

\(\Leftrightarrow V_{NaOH}=0,4\left(l\right)=400\left(ml\right)\)

PTHH: \(HCl+NaOH\rightarrow NaCl+H_2O\)

\(\Rightarrow n_{NaCl}=n_{HCl}=0,04\left(mol\right)\)

\(V_{dd}=0,2+0,4=0,6\left(l\right)\)

\(\Rightarrow C_{M\left(NaCl\right)}=\dfrac{0,04}{0,6}=0,67M\)

\(n_{HCl}=0.2\cdot0.1=0.02\left(mol\right)\)

\(\Rightarrow n_{OH^-}=0.02\cdot2=0.04\left(mol\right)\)

BTĐT : 

\(b=0.04+0.01-0.01\cdot2=0.03\left(mol\right)\)

\(m_{Cr}=0.01\cdot137+0.01\cdot62+0.04\cdot17+0.03\cdot23=3.36\left(g\right)\)

 

Theo ĐLBT điện tích thì: 0,01.2+ b = 0,01+a

H⁺           +     OH^-   → H2O

nOH^-= nH⁺= 0,04 mol = a => b = 0,03 mol

Khối lượng chất rắn thu được khi cô cạn dung dịch X là:

0,01.137+ 0,01.62+ 17.0,04+ 23.0,03 = 3,36 gam

ta có khi cho A tác dụng với $N{a}_{2}C{O}_3$
$Ba(OH{)}_2+N{a}_{2}C{O}_3-->BaC{O}_3+2NaOH$
...0.001......................................0.001...............mol
$NaOH+HCl-->NaCl+H_{2}O$
$Ba(OH{)}_2+2HCl-->BaC{l}_2+2H_{2}O$
....0.001............0.002................................mol
${}^{}HCl=0.1\ast 0.06=0.006mol$
=> ${}^{}NaOH=0.006-0.002=0.004mol$
=> CM từng chất =......  

\(n_{NaOH}=0.1\cdot0.1=0.01\left(mol\right)\)

\(n_{KOH}=0.1\cdot0.1=0.01\left(mol\right)\)

\(V=0.1+0.1=0.2\left(l\right)\)

\(\left[Na^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)

\(\left[K^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)

\(\left[OH^-\right]=\dfrac{0.01+0.01}{0.2}=0.1\left(M\right)\)

\(b.\)

\(pH=14+log\left[OH^-\right]=14+log\left(0.1\right)=13\)

\(c.\)

\(H^++OH^-\rightarrow H_2O\)

\(0.02........0.02\)

\(V_{dd_{H_2SO_4}}=\dfrac{0.02}{1}=0.02\left(l\right)\)

\(a.\)

\(n_{NaOH}=0.1\cdot0.1=0.01\left(mol\right)\)

\(n_{KOH}=0.1\cdot0.1=0.01\left(mol\right)\)

\(V=0.1+0.1=0.2\left(l\right)\)

\(\left[Na^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)

\(\left[K^+\right]=\dfrac{0.01}{0.2}=0.05\left(M\right)\)

\(\left[OH^+\right]=\dfrac{0.01+0.01}{0.2}=0.1\left(M\right)\)

\(b.\)

\(pH=14+log\left(0.1\right)=13\)

\(c.\)

\(H^++OH^-\rightarrow H_2O\)

\(0.02.......0.02\)

\(V_{H_2SO_4}=\dfrac{0.02}{1}=0.02\left(l\right)\)

a) Ta có: \(n_{NaOH}=0,1\cdot0,1=n_{KOH}=0,01\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{OH^-}=0,02\left(mol\right)\\n_{Na^+}=n_{K^+}=0,01\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\left[OH^-\right]=\dfrac{0,02}{0,2}=0,1\left(M\right)\\\left[Na^+\right]=\left[K^+\right]=\dfrac{0,01}{0,2}=0,05\left(M\right)\end{matrix}\right.\)

b) Ta có: \(pH=14+log\left[OH^-\right]=13\)

c) PT ion: \(OH^-+H^+\rightarrow H_2O\)

Theo PT ion: \(n_{H^+}=n_{OH^-}=0,02\left(mol\right)\)

\(\Rightarrow n_{H_2SO_4}=0,01\left(mol\right)\) \(\Rightarrow V_{ddH_2SO_4}=\dfrac{0,01}{1}=0,01\left(l\right)=10\left(ml\right)\)

 

a)

Gọi thể tích hai bazo là V

Suy ra : 

n NaOH = 0,1V ; n Ba(OH)2 = 0,15V

n HCl = 0,2.0,2 = 0,04(mol) ; n H2SO4 = 0,2.0,1 = 0,02(mol)

Bản chất của phản ứng là H trong axit tác dụng với OH trong bazo tạo thành nước : 

$H + OH \to H_2O$

n H = n HCl + 2n H2SO4 = 0,08(mol)

n OH = n NaOH + 2n Ba(OH)2 = 0,4V

Theo PTHH :

n H = n OH <=> 0,08 = 0,4V <=> V = 0,2(lít)

b) Dung dịch sau pư có : 

Na+ : 0,02

Ba2+ : 

Cl- : 0,04

Bảo toàn điện tích => n Ba2+ = 0,01(mol)

=> n BaSO4 = n Ba(OH)2 - n Ba2+ = 0,03 - 0,01 = 0,02

m BaSO4 = 0,02.233 = 4,66 gam

 

 

 

So mol H⁺ = 0,4V_A. Số mol OH^- = 0,05

=> pH = 7 nên pư vừa đủ => 0,4V_A = 0,05 => V_A = 0,125 lít = 125 ml

\(pH=2\Rightarrow\left[H^+_{dư}\right]=10^{-2}\Rightarrow n_{H^+}=10^{-2}\left(V+0,4\right)\)

\(n_{H^+}=2.0,0375.0,4+0,0125.0,4=0,035\left(mol\right)\)

\(n_{OH^-}=0,3V\left(mol\right)\)

\(\Rightarrow0,035+0,3V=10^{-2}\left(V+0,4\right)\)

\(\Rightarrow V=33,1\left(l\right)\)

\(\Leftrightarrow V=\)