\(n_{Zn}=\dfrac{6.5}{65}=0.1\left(mol\right)\)

\(n_{HCl}=\dfrac{100\cdot14.6\%}{36.5}=0.4\left(mol\right)\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(1........2\)

\(0.1......0.4\)

\(LTL:\dfrac{0.1}{1}< \dfrac{0.4}{2}\Rightarrow HCldư\)

\(V_{H_2}=0.1\cdot22.4=2.24\left(l\right)\)

\(m_{\text{dung dịch sau phản ứng}}=6.5+100-0.1\cdot2=106.3\left(g\right)\)

\(C\%ZnCl_2=\dfrac{0.1\cdot136}{106.3}\cdot100\%=12.79\%\)

\(C\%HCl\left(dư\right)=\dfrac{\left(0.4-0.2\right)\cdot36.5}{106.3}\cdot100\%=6.87\%\%\)

n Zn= 19,5/65=0,3 (mol).

PTPƯ: Zn(0.3) +   HCl(0.6) ---->  ZnCl2(0.3) + H2(0,3)

mHCl=0,6.36.5=21.9(g)

a) C%HCl= 21.9/300.100%=7,3%

b) VH2=0,3.22,4=6,72(lít)

c) mH2=0,3.2=0,6(g)

mZnCl2=0,3.136=40,8(g)

mddZnCl2 =(19,5+300)-0,6=318,9(g)

C%=mZnCl2/mddZnCl2.100= 40,8/318,9.100=12,793%

\(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\\ m_{HCl}=\dfrac{100.18,25}{100}=18,25\left(g\right)\\ n_{HCl}=\dfrac{18,25}{36,5}=0,5\\ pthh:Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)  
            0,125                            0,125 (mol ) 
\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(l\right)\\ \)   
\(C\%=\dfrac{8,125}{8,125+18,25}.100\%=30,8\%\)
 

Bài 18:

Ta có: \(n_{Zn}=\dfrac{8,125}{65}=0,125\left(mol\right)\)

\(m_{HCl}=100.18,25\%=18,25\left(g\right)\Rightarrow n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)

a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

b, Xét tỉ lệ: \(\dfrac{0,125}{1}< \dfrac{0,5}{2}\), ta được HCl dư.

Theo PT: \(n_{H_2}=n_{Zn}=0,125\left(mol\right)\)

\(\Rightarrow V_{H_2}=0,125.22,4=2,8\left(g\right)\)

\(m_{H_2}=0,125.2=0,25\left(g\right)\)

c, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,125\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Zn}=0,25\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow n_{HCl\left(dư\right)}=0,25\left(mol\right)\)

Có: m _{dd sau pư} = 8,125 + 100 - 0,25 = 107,875 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,125.136}{107,875}.100\%\approx15,76\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,25.36,5}{107,875}.100\%\approx8,46\%\end{matrix}\right.\)

Bạn tham khảo nhé!

`a)PTHH:`

`Zn + 2HCl -> ZnCl_2 + H_2↑`

`0,125`  `0,25`    `0,125`    `0,125`      `(mol)`

`b)n_[Zn] = [ 8,125 ] / 65 = 0,125 (mol)`

`n_[HCl] = [ [ 18,25 ] / 100 . 100 ] / [ 36,5 ] = 0,5 (mol)`

Ta có: `[ 0,125 ] / 1 < [ 0,5 ] / 2`

    `-> Zn` hết, `HCl` dư

 `=> V_[H_2] = 0,125 . 22,4 = 2,8 (l)`

 `=> m_[H_2] = 0,125 . 2 = 0,25 (g)`

`c)m_\text{dd sau p/ứ} = 8,125 + 100 - 0,25 = 107,875 (g)`

`=> C%_[ZnCl_2] = [ 0,125 . 136 ] / [ 107,875 ] . 100 ~~ 15,76%`

`=> C%_[HCl(dư)] = [ ( 0,5 - 0,25 ) . 36,5 ] / [ 107,875 ] . 100 ~~ 8,46%`

\(n_{Zn}=\dfrac{19,5}{65}=0,3\left(mol\right)\)

\(m_{HCl}=\dfrac{150.18,25}{100}=27,375\left(g\right)\)

\(n_{HCl}=\dfrac{27,375}{36,5}=0,75\left(mol\right)\)

PTHH :

                \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)

trc p/u :   0,3       0,75        

p/u:          0,3     0,6           0,3        0,3 

sau p/u :  0         0,15         0,3       0,3 

---> Sau p/ư HCl dư 

\(a,V_{H_2}=0,3.22,4=6,72\left(l\right)\)

\(b,m_{ddHCl}=0,6.36,5=21,9\left(g\right)\)

\(c,m_{ZnCl_2}=0,3.136=40,8\left(g\right)\)

\(m_{ddZnCl_2}=19,5+150-\left(0,3.2\right)=168,9\left(g\right)\)

\(C\%=\dfrac{40,8}{168,9}.100\%\approx24,16\%\)

\(a)n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ 2Al+6HCl\xrightarrow[]{}2AlCl_3+3H_2\\ n_{H_2}=\dfrac{3}{2}n_{Al}=\dfrac{3}{2}\cdot0,4=0,6\left(mol\right)\\ V_{H_2}=0,6.22,4=13,44\left(l\right)\\ b)n_{HCl}=3n_{Al}=3.0,4=1,2\left(mol\right)\\ m_{HCl}=1,2.36,5=43,8\left(g\right)\\ m_{dd_{HCl}}=\dfrac{43,8}{10,95\%}\cdot100\%=400\left(g\right)\\ c)n_{AlCl_3}=n_{Al}=0,4mol\\ m_{AlCl_3}=0,4.133,5=53,4\left(g\right)\\ m_{H_2}=0,6.2=1,2\left(g\right)\\ m_{dd_{AlCl_3}}=10,8+400-1,2=409,6\left(g\right)\\ C_{\%AlCl_3}=\dfrac{53,4}{409,6}\cdot100\%\approx13\%\)

`n_[Al]=[2,7]/27=0,1(mol)`

`2Al + 6HCl -> 2AlCl_3 + 3H_2 \uparrow`

`0,1`    `0,3`              `0,1`      `0,15`           `(mol)`

`a)V_[H_2]=0,15.22,4=3,36(l)`

`b)V_[dd HCl]=[0,3]/2=0,15(l)`

`=>C_[M_[AlCl_3]]=[0,1]/[0,15]~~0,67(M)`

\(n_{Al}=\dfrac{2,7}{27}=0,1\left(mol\right)\\ pthh:2Al+6HCl\rightarrow2AlCl_3+3H_2\) 
          0,1        0,3            0,1            0,15
\(V_{H_2}=0,15.22,4=3,36\left(l\right)\\ V_{HCl}=\dfrac{0,3}{2}=0,15\left(l\right)\\ C_{M\left(AlCl_3\right)}=\dfrac{0,1}{0,15}=\dfrac{2}{3}M\)

1////          nAl=0,4mol   

2Al     +      6HCl -----> 2AlCl3 + 3H2

0,4mol      1,2mol         0,4mol    0,6 mol

a/ V_H2=0,6.22,4=13,44 l

b/ V=1,2/2=0,6 l

C_AlCl3=0,4/0,6=2/3 M

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