PTHH: \(C_2H_5OH+3O_2\xrightarrow[]{t^o}2CO_2+3H_2O_{ }\)

           \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3\downarrow+H_2O\)

a) Ta có: \(n_{CaCO_3}=\dfrac{160}{100}=1,6\left(mol\right)=n_{CO_2}\) \(\Rightarrow n_{O_2}=2,4\left(mol\right)\)

\(\Rightarrow V_{kk}=\dfrac{2,4\cdot22,4}{20\%}=268,8\left(l\right)\)

b) Theo PTHH: \(n_{C_2H_5OH}=\dfrac{1}{2}n_{CO_2}=0,8\left(mol\right)\)

\(\Rightarrow a=C\%_{C_2H_5OH}=\dfrac{0,8\cdot46}{50\cdot0,8}\cdot100\%=92\%=92^o\)

nCaCO3 = 4,5/100 = 0,045 (mol)

PTHH: 

CO2 + Ca(OH)2 -> CaCO3 + H2O

0,045 <--- 0,045 <--- 0,045

2C2H2 + 5O2 -> (t°) 4CO2 + 2H2O

0,0225 <--- 0,05625 <--- 0,045

VC2H2 = 0,0225 . 22,4 = 0,504 (l) = 504 (ml)

PTHH: CaC2 + 2H2O -> C2H2 + Ca(OH)2

nC2H2 (LT) = 0,504 : 80% = 0,63 (mol)

nCaC2 = 0,63 (mol)

mCaC2 = 0,63 . 64 = 40,32 (g)

\(n_{CaCO_3}=\dfrac{100,2}{100}=1,002\left(mol\right)\)

PTHH: Ca(OH)₂ + CO₂ ---> CaCO₃ + H₂O

                             1,002 <---- 1,002

            C₂H₅OH + 3O₂ --t^o--> 2CO₂ + 3H₂O

             0,501 <-------------------- 1,002

\(\rightarrow m_{C_2H_5OH}=0,501.46=23,046\left(g\right)\\ \rightarrow V_{C_2H_5OH}=\dfrac{23,046}{0,8}=28,8075\left(ml\right)\)

=> Độ rượu là: \(\dfrac{29,8075}{30}=96,025^o\)

Câu 1.

\(V_{C_2H_5OH}=\dfrac{90.90}{100}=81\left(ml\right)\)

\(m_{C_2H_5OH}=81.0,8=64,8g\)

\(n_{C_2H_5OH}=\dfrac{64,8}{46}=1,4mol\)

\(2C_2H_5OH+2Na\rightarrow2C_2H_5ONa+H_2\)

    1,4                                                   0,7        ( mol )

\(V_{H_2}=0,7.22,4=15,68l\)

Câu 2.

\(n_{CaCO_3}=\dfrac{100}{100}=1mol\)

\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)

                        1            1                      ( mol )

\(C_2H_5OH+3O_2\rightarrow\left(t^o\right)2CO_2+3H_2O\)

       0,5          1,5             1                          ( mol )

\(V_{kk}=\left(1,5.22,4\right).5=168l\)           

\(m_{C_2H_5OH}=0,5.46=23g\)  

\(V_{C_2H_5OH}=\dfrac{23}{0,8}=28,75ml\)

Độ rượu = \(\dfrac{28,75}{30}.100=95,83^o\)

\(M_X=\dfrac{1.5}{\dfrac{1.775}{71}}=60\left(g\text{/}mol\right)\)

\(n_X=\dfrac{2.25}{60}=0.0375\left(mol\right)\)

CT : \(C_xH_yO_z\)

\(n_{CaCO_3}=n_{CO_2}=\dfrac{11.25}{100}=0.1125\left(mol\right)\)

\(\Rightarrow n_C=0.1125\left(mol\right)\)

\(m_{bt}=m_{CO_2}+m_{H_2O}=7.65\left(g\right)\)

\(\Rightarrow n_{H_2O}=\dfrac{7.65-0.1125\cdot44}{18}=0.15\left(mol\right)\)

\(\Rightarrow n_H=0.15\cdot2=0.3\left(mol\right)\)

Ta có : 

\(x=\dfrac{n_C}{n_X}=\dfrac{0.1125}{0.0375}=3\)

\(y=\dfrac{n_H}{n_X}=\dfrac{0.3}{0.0375}=8\)

\(M=12\cdot3+8+16z=60\left(g\text{/}mol\right)\)

\(\Rightarrow z=1\)

\(CT:C_3H_8O\)

Ta có: $n_{CaCO_3}=0,835(mol)$

Bảo toàn C ta có: $n_{C_2H_5OH}=0,4175(mol)$

$\Rightarrow m_{C_2H_5OH}=19,205(g)\Rightarrow V_{C_2H_5OH}=24(ml)$

$\Rightarrow S=8^o$

a) PTHH: C2H6O + 3 O2 -to-> 2CO2 + 3 H2O

b) nC2H6O=0,1(mol) => nCO2=2.0,1=0,2(mol)

PHHH: CO2 + Ca(OH)2 -> CaCO3 + H2O

nCaCO3=nCO2=0,2(mol)

=>m(kết tủa)=mCaCO3=0,2.100=20(g)

nC2H5OH = 4.6/46 = 0.1 (mol) 

C2H5OH + 3O2 -to-> 2CO2 + 3H2O 

0.1.................................0.2

Ca(OH)2 + CO2 => CaCO3 + H2O 

.....................0.2............0.2

mCaCO3 = 0.2 * 100 = 20 (g) 

A tác dụng với NaHCO₃ cho khí CO2 → A: axit CH₃COOH

BTKL: m + m_O2 = m_CO2 + m_H2O => m = 1,8

=> n_CH3COOH = 0,03

CH₃COOH + C₂H₅OH → CH₃COOC₂H₅ + H₂O

0,03                 0,02                 0,0125

=> H = 62,5%

Ta có: \(n_{H_2O}=\dfrac{14,4}{18}=0,8\left(mol\right)\)

\(n_{CO_2}=n_{CaCO_3}=\dfrac{60}{100}=0,6\left(mol\right)\)

⇒ n_H2O > n_CO2 → A là ankan.

⇒ n_A = n_H2O - n_CO2 = 0,2 (mol)

CTPT của A là C_nH_2n+2

\(\Rightarrow n=\dfrac{n_{CO_2}}{n_A}=3\)

Vậy: CTPT của A là C₃H₈.