\(n_{CuSO_4}=\dfrac{200.16\%}{160}=0,2\left(mol\right)\)

PTHH :

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2\downarrow+Na_2SO_4\)

0,2              0,4                  0,2               0,2 

\(m_{NaOH}=0,4.40=16\left(g\right)\)

\(m_{ddNaOH}=\dfrac{16.100}{10}=160\left(g\right)\)

\(c,m_{Na_2SO_4}=0,2.142=28,4\left(g\right)\)

\(m_{ddNa_2SO_4}=200+160-\left(0,2.98\right)=340,4\left(g\right)\)

\(C\%_{Na_2SO_4}=\dfrac{28,4}{240,4}.100\%\approx8,34\%\)

\(d,PTHH:\)

\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)

0,2               0,2 

\(m_{CuO}=0,2.80=16\left(g\right)\)

a, \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

b, \(m_{CuSO_4}=200.16\%=32\left(g\right)\Rightarrow n_{CuSO_4}=\dfrac{32}{160}=0,2\left(mol\right)\)

\(n_{NaOH}=2n_{CuSO_4}=0,4\left(mol\right)\Rightarrow m_{ddNaOH}=\dfrac{0,4.40}{10\%}=160\left(g\right)\)

c, \(n_{Cu\left(OH\right)_2}=n_{Na_2SO_4}=n_{CuSO_4}=0,2\left(mol\right)\)

\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{0,2.142}{200+160-0,2.98}.100\%\approx8,34\%\)

d, \(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)

\(n_{CuO}=n_{Cu\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)

câu 1

cho 2dd trên td vs NaOH dư

có tủa => CuSO4

CuSO4 + 2NaOH => Na2SO4 + Cu(OH)2

ko hiện tượng => Na2SO4

câu 2

nNaOH = 0,75

MgCl2 + 2NaOH => 2NaCl + Mg(OH)2

0,375<---- 0,75--------> 0,75---> 0,375

=> mcr = 0,375. 58 = 21,75 (g)

CM MgCl2 = 0,375/0,5 = 0,75M

a, \(MgO+H_2SO_4\rightarrow MgSO_4+H_2O\)

b, Ta có: \(m_{H_2SO_4}=200.9,8\%=19,6\left(g\right)\)

\(\Rightarrow n_{H_2SO_4}=\dfrac{19,6}{98}=0,2\left(mol\right)\)

Theo PT: \(n_{MgO}=n_{MgSO_4}=n_{H_2SO_4}=0,2\left(mol\right)\)

\(\Rightarrow m_{MgO}=0,2.40=8\left(g\right)\)

c, Ta có: m _{dd sau pư} = 8 + 200 = 208 (g)

\(\Rightarrow C\%_{MgSO_4}=\dfrac{0,2.120}{208}.100\%\approx11,54\%\)

a, \(MgCl_2+2NaOH\rightarrow Mg\left(OH\right)_2+2NaCl\)

\(Mg\left(OH\right)_2\underrightarrow{t^o}MgO+H_2O\)

b, \(n_{MgCl_2}=0,2.0,25=0,05\left(mol\right)\)

 Theo PT: \(n_{MgO}=n_{Mg\left(OH\right)_2}=n_{MgCl_2}=0,05\left(mol\right)\)

\(\Rightarrow m_{MgO}=0,05.40=2\left(g\right)\)

c, \(n_{NaOH}=2n_{MgCl_2}=0,1\left(mol\right)\)

\(\Rightarrow m_{ddNaOH}=\dfrac{0,1.40}{15\%}=\dfrac{80}{3}\left(g\right)\)

\(n_{CuSO_4}=\dfrac{15,2}{160}=0,095mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

0,095          0,19              0,095            0,095

\(m_{rắn}=m_{Cu\left(OH\right)_2}=0,095.98=9,31g\\ V_{ddNaOH}=\dfrac{0,19}{2}=0,095l\\ b)C_{M_{Na_2SO_4}}=\dfrac{0,095}{0,04+0,095}\approx0,7M\\ c)Cu\left(OH\right)_2\xrightarrow[t^0]{}CuO+H_2O\)

0,095                 0,095

\(m_{rắn}=m_{CuO}=0,095.80=7,6g\)

Gọi: \(\left\{{}\begin{matrix}n_{FeCl_3}=x\left(mol\right)\\n_{MgCl_2}=y\left(mol\right)\end{matrix}\right.\)

PT: \(FeCl_3+3KOH\rightarrow Fe\left(OH\right)_{3\downarrow}+3KCl\)

______x_________3x_________x (mol)

\(MgCl_2+2KOH\rightarrow Mg\left(OH\right)_{2\downarrow}+2KCl\)

____y_________2y_________y (mol)

Ta có: \(n_{KOH}=0,2.2,5=0,5\left(mol\right)\)

⇒ 3x + 2y = 0,5 (1)

m _{kết tủa} = 16,5 ⇒ 107x + 58y = 16,5 (2)

Từ (1) và (2) ⇒ x = y = 0,1 (mol)

\(\Rightarrow C_{M_{FeCl_3}}=C_{M_{MgCl_2}}=\dfrac{0,1}{0,5}=0,2\left(M\right)\)

\(FeCl_3+3KOH\rightarrow Fe\left(OH\right)_3\downarrow+3KCl\\ MgCl_2+2KOH\rightarrow Mg\left(OH\right)_2\downarrow+2KCl\)

\(n_{KOH}=0,2\cdot2,5=0,5\left(mol\right)\)

Đặt n_FeCl₃ trong 500ml X là a mol, n_MgCl₂ trong 500ml X là b mol

\(\Rightarrow\left\{{}\begin{matrix}3a+2b=0,5\\107a+58b=16,5\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}a=0,1\\b=0,1\end{matrix}\right.\)

\(\Rightarrow C_MFeCl_3=\dfrac{0,1}{0,5}=0,2\left(M\right)\\ C_MMgCl_2=\dfrac{0,1}{0,5}=0,2\left(M\right)\)

MgCl2+2NaOH->Mg(OH)2+2NaCl

0,5-------1-------------0,5

Mg(OH)2-to>MgO+H2O

0,5----------------0,5

m Mgcl2=47,5g

=>n Mgcl2=0,5 mol

=>m NaOH=1.40=40g

=>m ddNaOH=500g

=>m MgO=0,5.40=20g

MgCl₂ (0,5 mol) + 2NaOH (1 mol) \(\rightarrow\) Mg(OH)₂\(\downarrow\) (0,5 mol) + 2NaCl.

a) Khối lượng dung dịch NaOH cần dùng:

m=1.40.100:8=500 (g).

b) Mg(OH)₂ (0,5 mol) \(\underrightarrow{t^o}\) MgO (0,5 mol) + H₂O.

Khối lượng chất rắn MgO thu được là:

x=0,5.40=20 (g).

\(n_{Fe_2O_3}=\dfrac{16}{160}=0,1\left(mol\right)\)

PT: \(Fe_2O_3+6HCl\rightarrow2FeCl_3+3H_2O\)

a, \(n_{HCl}=6n_{Fe_2O_3}=0,6\left(mol\right)\)

\(\Rightarrow C\%_{HCl}=\dfrac{0,6.36,5}{500}.100\%=4,38\%\)

b, \(n_{FeCl_3}=2n_{Fe_2O_3}=0,2\left(mol\right)\)

PT: \(FeCl_3+3KOH\rightarrow3KCl+Fe\left(OH\right)_{3\downarrow}\)

______0,2_______0,6______________0,2 (mol)

\(\Rightarrow C_{M_{KOH}}=\dfrac{0,6}{0,2}=3\left(M\right)\)

\(m_{Fe\left(OH\right)_3}=0,2.107=21,4\left(g\right)\)

\(n_{MgCl_2}=0,15.0,2=0,03(mol)\\ PTHH:MgCl_2+2NaOH\to Mg(OH)_2\downarrow +2NaCl\\ a,n_{Mg(OH)_2}=n_{MgCl_2}=0,03(mol)\\ \Rightarrow m_{\downarrow}=m_{Mg(OH)_2}=0,03.58=1,74(g)\\ b,n_{NaOH}=2n_{MgCl_2}=0,06(mol)\\ \Rightarrow C_{M_{NaOH}}=\dfrac{0,06}{0,3}=0,2M\\ c,PTHH:Mg(OH)_2\xrightarrow{t^o}MgO+H_2O\\ \Rightarrow n_{MgO}=n_{Mg(OH)_2}=0,03(mol)\\ \Rightarrow m_{A}=m_{MgO}=0,03.40=1,2(g)\)