nCO2 = 0,448 / 22,4 = 0,02 (mol)

2CH3COOH + CaCO3 -> (CH3COO)2Ca + CO2 + H2O

0,04 0,02 0,02

mCH3COOH = 0,04 * 60 = 2,4 (gam)

-> C%CH3COOH = 2,4 / 40 * 100% = 6%

mCaCO3 = 0,02 * 100 = 2 (gam)

nKOH = 0,5.0,3 = 0,15 mol 

CH3COOH + KOH → CH3COOK + H2O

   0,15            0,15         0,15                   mol

a) C_{M CH3COOH} = 0,15/0,2 =0,75M

b) Thể tích của dung dịch thu được sau phản ứng: 500 ml

C_{M CH3COOK} = 0,15/0,5 = 0,3M

c) Phản ứng lên men giấm

C2H5OH + O2 → CH3COOH + H2O

0,15                          0,15

→ mC2H5OH = 0,15.46 = 6,9 gam

\(n_{KOH}=0,5\cdot0,3=0,15mol\)

\(CH_3COOH+KOH\rightarrow CH_3COOK+H_2O\)

0,15                     0,15          0,15            0,15

a)\(C_{M_{CH_3COOH}}=\dfrac{0,15}{0,2}=0,75M\)

b)\(C_{M_{CH_3COOK}}=\dfrac{0,15}{0,2+0,3}=0,3M\)

\(a,n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)

PTHH: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)

                        0,1<----------------0,05-------------->0,05

\(\rightarrow V_{H_2}=0,05.22,4=1,12\left(l\right)\\ b,C\%_{CH_3COOH}=\dfrac{0,1.60}{100}.100\%=6\%\)

\(c,n_{C_2H_5OH}=\dfrac{6,9}{46}=0,15\left(mol\right)\)

PTHH: \(CH_3COOH+C_2H_5OH\xrightarrow[H_2SO_{4\left(đặc\right)}]{t^o}CH_3COOC_2H_5+H_2O\)

bđ          0,1                 0,15

pư          0,1                 0,1

spư         0                     0,05                          0,1

\(\rightarrow m_{este}=0,1.80\%.88=7,04\left(g\right)\)

nCO2= 0.15 mol

CH3COOH + NaHCO3 --> CH3COONa + CO2 + H2O

0.15_________0.15_________0.15______0.15

VddCH3COOH= 0.15/0.5=0.3 l

mCH3COONa = 12.3g

C%NaHCO3= 12.6/300*100%=4.2%

Zn+2CH3COOH->(CH3COO)2Zn+H2

0,125----0,25------------------------------0,125

n Zn=8,125\65=0,125 mol

=>VH2=0,125.22,4=2,8l

=>Cm=0,25\0,5=0,5M

2CH3COOH + Zn -- > (CH3COOH)2Zn + H2

nH2 = 2,24 / 22,4 = 0,1 (mol)

=> nCH3COOH = 0,2 (mol)

mZn = 0,1. 65 = 6,5 (g)

mH2 = 0,1.2 = 0,2 (g)

mdd  = 300 + 6,5 - 0,2 = 306,3 (g)

mCH3COOH = 0,2 . 60 = 12 (g)

=> C%CH3COOH = ( 12.100 ) / 306,3 = 4%

m(CH3COO)2Zn = 0,1 . 183 = 18,3 (g)

=> (18,3.100) / 306,3 = 6%

a, \(n_{CH_3COOH}=0,2.1=0,2\left(mol\right)\)

PT: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\)

Theo PT: \(n_{Mg}=n_{H_2}=\dfrac{1}{2}n_{CH_3COOH}=0,1\left(mol\right)\)

\(\Rightarrow m=m_{Mg}=0,1.24=2,4\left(g\right)\)

\(V=V_{H_2}=0,1.22,4=2,24\left(l\right)\)

b, \(C_2H_5OH+O_2\underrightarrow{^{mengiam}}CH_3COOH+H_2O\)

Theo PT: \(n_{C_2H_5OH}=n_{CH_3COOH}=0,2\left(mol\right)\)

\(\Rightarrow m_{C_2H_5OH}=0,2.46=9,2\left(g\right)\)

\(\Rightarrow V_{ddC_2H_5OH}=\dfrac{9,2}{0,8}=11,5\left(ml\right)\)

Rượu etylic \(C_2H_5OH\)

Axit axetic \(CH_3COOH\)

\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1mol\)

\(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+H_2O+CO_2\uparrow\)

      0,2                  0,1                 0,2                  0,1         0,1

\(\%m_{CH_3COOH}=\dfrac{0,2\cdot60}{39,6}\cdot100\%=30,3\%\)      

\(\%m_{C_2H_5OH}=100\%-30,3\%=69,7\%\)

a)

\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

PTHH: 2CH₃COOH + Na₂CO₃ --> 2CH₃COONa + CO₂ + H₂O

                 0,2<----------0,1<-------------0,2<-------0,1

=> \(m_{CH_3COOH}=0,2.60=12\left(g\right)\)

\(\%m_{CH_3COOH}=\dfrac{12}{39,6}.100\%=30,3\%\)

\(\%m_{C_2H_5OH}=\dfrac{39,6-12}{39,6}.100\%=69,7\%\)

b) dd sau pư chứa \(\left\{{}\begin{matrix}CH_3COONa:0,2\left(mol\right)\\C_2H_5OH:\dfrac{39,6-12}{46}=0,6\left(mol\right)\end{matrix}\right.\)

\(V_{dd}=\dfrac{0,1}{2}=0,05\left(l\right)\)

=> \(\left\{{}\begin{matrix}C_{M\left(CH_3COONa\right)}=\dfrac{0,2}{0,05}=4M\\C_{M\left(C_2H_5OH\right)}=\dfrac{0,6}{0,05}=12M\end{matrix}\right.\)

a) Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

b) \(n_{CH_3COOH}=\dfrac{25.6\%}{60}=0,025\left(mol\right)\)

PTHH: Na₂CO₃ + 2CH₃COOH --> 2CH₃COONa + CO₂ + H₂O

              0,0125<-----0,025------------>0,025------>0,0125

=> \(m_{Na_2CO_3}=0,0125.106=1,325\left(g\right)\)

c) \(m_{dd.sau.pư}=1,325+25-0,0125.44=25,775\left(g\right)\)

\(C\%_{dd.CH_3COONa}=\dfrac{0,025.82}{25,775}.100\%=7,95\%\)

m CH3COOH=1,5g=>n=0,025 mol

2CH3COOH+Na2CO3->2CH3COONa+H2O+CO2

0,025--------------0,0125----------0,025

=>m Na2CO3=0,0125.106=1,325g

=>mdd=25g

c) 

C% =\(\dfrac{0,025.82}{25+25}100=4,1\%\)